Ultrafast excited state dynamics of spirilloxanthin in solution and bound to core antenna complexes: Identification of the S* and T 1 states

Kosumi, Daisuke; Maruta, Satoshi; Horibe, Tomoko; Nagaoka, Yuya; Fujii, Ritsuko; Sugisaki, Mitsuru; Cogdell, Richard J.; Hashimoto, Hideki

doi:10.1063/1.4737129

Title: Ultrafast excited state dynamics of spirilloxanthin in solution and bound to core antenna complexes: Identification of the S* and T ₁ states

Journal Article · Tue Aug 14 00:00:00 EDT 2012 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4737129· OSTI ID:1384912

Kosumi, Daisuke; Maruta, Satoshi; Horibe, Tomoko; Nagaoka, Yuya; Fujii, Ritsuko; Sugisaki, Mitsuru; Cogdell, Richard J.; Hashimoto, Hideki

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Photosynthetic Antenna Research Center (PARC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001035

OSTI ID:: 1384912

Journal Information:: Journal of Chemical Physics, Vol. 137, Issue 6; Related Information: PARC partners with Washington University in St. Louis (lead); University of California, Riverside; University of Glasgow, UK; Los Alamos National Laboratory; University of New Mexico; New Mexico Corsortium; North Carolina State University; Northwestern University; Oak Ridge National Laboratory; University of Pennsylvania; Sandia National Laboratories; University of Sheffield, UK; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)

Country of Publication:: United States

Language:: English

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The <mml:math altimg="si13.gif" display="inline" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd"><mml:mrow><mml:mn>1</mml:mn><mml:msubsup><mml:mrow><mml:mi mathvariant="normal">B</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant="normal">u</mml:mi></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msubsup><mml:mo>→</mml:mo><mml:mn>3</mml:mn><mml:msubsup><mml:mrow><mml:mi mathvariant="normal">A</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant="normal">g</mml:mi></mml:mrow><mml:mrow><mml:mo>-</mml:mo></mml:mrow></mml:msubsup><mml:mo>→</mml:mo><mml:mn>1</mml:mn><mml:msubsup><mml:mrow><mml:mi mathvariant="normal">B</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant="normal">u</mml:mi></mml:mrow><mml:mrow><mml:mo>-</mml:mo></mml:mrow></mml:msubsup><mml:mo>→</mml:mo><mml:mn>2</mml:mn><mml:msubsup><mml:mrow><mml:mi mathvariant="normal">A</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant="normal">g</mml:mi></mml:mrow><mml:mrow><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math> internal conversion in carotenoids following the energy-gap law identified by 5fs spectroscopy Ikuta, Mitsuhiro; Yabushita, Atsushi; Rondonuwu, Ferdy S. Chemical Physics Letters, Vol. 422, Issue 1-3 https://doi.org/10.1016/j.cplett.2006.02.042	journal	April 2006
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Carotenoid Photoprotection in Artificial Photosynthetic Antennas Kloz, Miroslav; Pillai, Smitha; Kodis, Gerdenis Journal of the American Chemical Society, Vol. 133, Issue 18 https://doi.org/10.1021/ja1103553	journal	May 2011
Magnetic Field Dependence of Ultrafast Intersystem-Crossing: A Triplet Mechanism on the Picosecond Time Scale? Musewald, Christian; Gilch, Peter; Hartwich, Gerhard Journal of the American Chemical Society, Vol. 121, Issue 38 https://doi.org/10.1021/ja9842520	journal	September 1999

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Title: Ultrafast excited state dynamics of spirilloxanthin in solution and bound to core antenna complexes: Identification of the S* and T 1 states

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Title: Ultrafast excited state dynamics of spirilloxanthin in solution and bound to core antenna complexes: Identification of the S* and T ₁ states