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Insights into capacity loss mechanisms of all-solid-state Li-ion batteries with Al anodes

Journal Article · · Journal of Materials Chemistry. A
DOI:https://doi.org/10.1039/C4TA03716B· OSTI ID:1384683
 [1];  [2];  [3];  [3];  [4];  [5];  [6]
  1. Department of Materials Science and Engineering; Institute for Research in Electronics and Applied Physics; College Park, USA; Center for Nanoscale Science and Technology; NIST
  2. Center for Nanoscale Science and Technology; NIST; Gaithersburg, USA; Maryland NanoCenter; University of Maryland
  3. Material Measurement Laboratory; NIST; Gaithersburg, USA
  4. Sandia National Laboratories; Livermore, USA
  5. Center for Nanoscale Science and Technology; NIST; Gaithersburg, USA
  6. Center for Nanoscale Science and Technology; NIST; Gaithersburg, USA; Sandia National Laboratories; Livermore, USA

The dynamic degradation of Al anodes in solid-state batteries is quantitatively measured by combining real-time scanning electron microscopy with electrochemical cycling.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)
Sponsoring Organization:
USDOE SC Office of Basic Energy Sciences (SC-22)
DOE Contract Number:
SC0001160
OSTI ID:
1384683
Journal Information:
Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 48 Vol. 2; ISSN JMCAET; ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (21)

In Situ Transmission Electron Microscopy Observation of Pulverization of Aluminum Nanowires and Evolution of the Thin Surface Al 2 O 3 Layers during Lithiation–Delithiation Cycles journal October 2011
Thermodynamic assessment of the Al–Li system journal October 2007
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries journal May 2012
Size Effects in the Electrochemical Alloying and Cycling of Electrodeposited Aluminum with Lithium journal January 2012
Al-based anode materials for Li-ion batteries journal June 2003
A review of the electrochemical performance of alloy anodes for lithium-ion batteries journal January 2011
Diffusion of Lithium in Bulk Amorphous Silicon: A Theoretical Study journal October 2012
Building better batteries journal February 2008
Research on Advanced Materials for Li-ion Batteries journal December 2009
Li-ion microbatteries generated by a laser direct-write method journal February 2004
Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells journal January 2007
Evolution of nanoporosity in dealloying journal March 2001
In situ atomic-scale imaging of electrochemical lithiation in silicon journal October 2012
Mechanical-energy influences to electrochemical phenomena in lithium-ion batteries journal January 2011
In Situ TEM Experiments of Electrochemical Lithiation and Delithiation of Individual Nanostructures journal May 2012
A new phase in the system lithium–aluminum: Characterization of orthorhombic Li2Al journal November 2010
High-Performance All-Solid-State Cells Fabricated With Silicon Electrodes journal March 2012
H adsorption and the formation of alane oligomers on Al(111) journal September 1999
Analysis of tracer and nuclear magnetic resonance measurements of self-diffusion in aluminium journal December 1971
Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries journal December 2011
Issues and challenges facing rechargeable lithium batteries journal November 2001

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