Design and Synthesis of Copper-Cobalt Catalysts for the Selective Conversion of Synthesis Gas to Ethanol and Higher Alcohols

Prieto, Gonzalo; Beijer, Steven; Smith, Miranda L.; He, Ming; Au, Yuen; Wang, Zi; Bruce, David A.; de Jong, Krijn P.; Spivey, James J.; de Jongh, Petra E.

doi:10.1002/anie.201402680

Title: Design and Synthesis of Copper-Cobalt Catalysts for the Selective Conversion of Synthesis Gas to Ethanol and Higher Alcohols

Journal Article · Wed May 14 00:00:00 EDT 2014 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201402680· OSTI ID:1384257

Prieto, Gonzalo; Beijer, Steven; Smith, Miranda L.; He, Ming; Au, Yuen; Wang, Zi; Bruce, David A.; de Jong, Krijn P.; Spivey, James J.; de Jongh, Petra E.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Atomic-Level Catalyst Design (CALCD)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001058

OSTI ID:: 1384257

Journal Information:: Angewandte Chemie (International Edition), Vol. 53, Issue 25; Related Information: CALCD partners with Louisiana State University (lead); Clemson University; University of Florida; Georgia Institute of Technology; Grambling State University; Oak Ridge National Laboratory; Ohio State University; Pennsylvania State; Texas A&M University; Vienna University of Technology, Austria; University of Utrecht, Netherlands; ISSN 1433-7851

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (27)

Activity and Selectivity Trends in Synthesis Gas Conversion to Higher Alcohols Medford, Andrew J.; Lausche, Adam C.; Abild-Pedersen, Frank Topics in Catalysis, Vol. 57, Issue 1-4 https://doi.org/10.1007/s11244-013-0169-0	journal	October 2013
Long-Chain Terminal Alcohols through Catalytic CO Hydrogenation Xiang, Yizhi; Chitry, Véronique; Liddicoat, Peter Journal of the American Chemical Society, Vol. 135, Issue 19 https://doi.org/10.1021/ja402512r	journal	May 2013
Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates Román-Leshkov, Yuriy; Barrett, Christopher J.; Liu, Zhen Y. Nature, Vol. 447, Issue 7147, p. 982-985 https://doi.org/10.1038/nature05923	journal	June 2007
Photocatalytic Conversion of Carbon Dioxide with Water into Methane: Platinum and Copper(I) Oxide Co-catalysts with a Core-Shell Structure Zhai, Qingge; Xie, Shunji; Fan, Wenqing Angewandte Chemie International Edition, Vol. 52, Issue 22 https://doi.org/10.1002/anie.201301473	journal	April 2013
Platinum–cobalt bimetallic nanoparticles in hollow carbon nanospheres for hydrogenolysis of 5-hydroxymethylfurfural Wang, Guang-Hui; Hilgert, Jakob; Richter, Felix Herrmann Nature Materials, Vol. 13, Issue 3 https://doi.org/10.1038/nmat3872	journal	February 2014
Mechanism of Ethanol Synthesis from Syngas on Rh(111) Choi, YongMan; Liu, Ping Journal of the American Chemical Society, Vol. 131, Issue 36 https://doi.org/10.1021/ja903013x	journal	September 2009
Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene Studt, F.; Abild-Pedersen, F.; Bligaard, T. Science, Vol. 320, Issue 5881 https://doi.org/10.1126/science.1156660	journal	June 2008
Cobalt Particle Size Effects in the Fischer−Tropsch Reaction Studied with Carbon Nanofiber Supported Catalysts Bezemer, G. Leendert; Bitter, Johannes H.; Kuipers, Herman P. C. E. Journal of the American Chemical Society, Vol. 128, Issue 12 https://doi.org/10.1021/ja058282w	journal	March 2006
Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles Pan, Xiulian; Fan, Zhongli; Chen, Wei Nature Materials, Vol. 6, Issue 7 https://doi.org/10.1038/nmat1916	journal	May 2007
Advances in the Development of Novel Cobalt Fischer−Tropsch Catalysts for Synthesis of Long-Chain Hydrocarbons and Clean Fuels Khodakov, Andrei Y.; Chu, Wei; Fongarland, Pascal Chemical Reviews, Vol. 107, Issue 5 https://doi.org/10.1021/cr050972v	journal	May 2007
Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins Torres Galvis, H. M.; Bitter, J. H.; Khare, C. B. Science, Vol. 335, Issue 6070, p. 835-838 https://doi.org/10.1126/science.1215614	journal	February 2012
Synthesis of higher alcohols from syngas - recently patented catalysts and tentative ideas on the mechanism Xiaoding, Xu; Doesburg, E. B. M.; Scholten, J. J. F. Catalysis Today, Vol. 2, Issue 1 https://doi.org/10.1016/0920-5861(87)80002-0	journal	December 1987
Palladium and Gold-Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide Edwards, Jennifer K.; Hutchings, Graham J. Angewandte Chemie International Edition, Vol. 47, Issue 48 https://doi.org/10.1002/anie.200802818	journal	September 2008
A Review of Recent Literature to Search for an Efficient Catalytic Process for the Conversion of Syngas to Ethanol Subramani, Velu; Gangwal, Santosh K. Energy & Fuels, Vol. 22, Issue 2 https://doi.org/10.1021/ef700411x	journal	March 2008
Al13Fe4 as a low-cost alternative for palladium in heterogeneous hydrogenation Armbrüster, M.; Kovnir, K.; Friedrich, M. Nature Materials, Vol. 11, Issue 8 https://doi.org/10.1038/nmat3347	journal	June 2012
About the nature of the Co-Cu interaction in Co-based catalysts for higher alcohols synthesis Bailliard-Letournel, R. M.; Gomez Cobo, A. J.; Mirodatos, C. Catalysis Letters, Vol. 2, Issue 3 https://doi.org/10.1007/BF00775064	journal	January 1989
C1-C6 alcohols from synthesis gas on copper-cobalt catalysts Courty, Philippe; Durand, Daniel; Freund, Edouard Journal of Molecular Catalysis, Vol. 17, Issue 2-3 https://doi.org/10.1016/0304-5102(82)85035-9	journal	November 1982
Designing bimetallic catalysts for a green and sustainable future Sankar, Meenakshisundaram; Dimitratos, Nikolaos; Miedziak, Peter J. Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35296f	journal	January 2012
Photocatalytic Conversion of Carbon Dioxide with Water into Methane: Platinum and Copper(I) Oxide Co-catalysts with a Core-Shell Structure Zhai, Qingge; Xie, Shunji; Fan, Wenqing Angewandte Chemie, Vol. 125, Issue 22 https://doi.org/10.1002/ange.201301473	journal	April 2013
New insights into the role of the electronic properties of oxide promoters in Rh-catalyzed selective synthesis of oxygenates from synthesis gas Prieto, Gonzalo; Concepción, Patricia; Martínez, Agustín Journal of Catalysis, Vol. 280, Issue 2 https://doi.org/10.1016/j.jcat.2011.03.025	journal	June 2011
Structure and catalytic performance of alumina-supported copper–cobalt catalysts for carbon monoxide hydrogenation Wang, Jingjuan; Chernavskii, Petr A.; Khodakov, Andrei Y. Journal of Catalysis, Vol. 286 https://doi.org/10.1016/j.jcat.2011.10.012	journal	February 2012
Heterogeneous Catalytic Conversion of Dry Syngas to Ethanol and Higher Alcohols on Cu-Based Catalysts Gupta, Mayank; Smith, Miranda L.; Spivey, James J. ACS Catalysis, Vol. 1, Issue 6 https://doi.org/10.1021/cs2001048	journal	May 2011
Nanoalloys: From Theory to Applications of Alloy Clusters and Nanoparticles Ferrando, Riccardo; Jellinek, Julius; Johnston, Roy L. Chemical Reviews, Vol. 108, Issue 3, p. 845-910 https://doi.org/10.1021/cr040090g	journal	March 2008
Using first principles to predict bimetallic catalysts for the ammonia decomposition reaction Hansgen, Danielle A.; Vlachos, Dionisios G.; Chen, Jingguang G. Nature Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/nchem.626	journal	April 2010
Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas Spivey, James J.; Egbebi, Adefemi Chemical Society Reviews, Vol. 36, Issue 9 https://doi.org/10.1039/b414039g	journal	January 2007
Bimetallic Au–Pd catalysts for selective hydrogenation of butadiene: Influence of the preparation method on catalytic properties Kolli, Nadia El; Delannoy, Laurent; Louis, Catherine Journal of Catalysis, Vol. 297 https://doi.org/10.1016/j.jcat.2012.09.022	journal	January 2013
Palladium‐ und Gold‐Palladium‐Katalysatoren für die Direktsynthese von Wasserstoffperoxid Edwards, Jennifer K.; Hutchings, Graham J. Angewandte Chemie, Vol. 120, Issue 48 https://doi.org/10.1002/ange.200802818	journal	November 2008

Similar Records

Design and synthesis of copper-cobalt catalysts for the selective conversion of synthesis gas to ethanol and higher alcohols

Journal Article · Wed May 14 00:00:00 EDT 2014 · Angew. Chem. Int. Ed. · OSTI ID:1384257

Prieto, G.; Beijer, S.; Smith, Miranda L.; +7 more

Effect of ZrO₂, Al₂O₃ and La₂O₃ on cobalt–copper catalysts for higher alcohols synthesis

Journal Article · Sat Sep 26 00:00:00 EDT 2015 · Applied Catalysis. A, General · OSTI ID:1384257

Wang, Zi; Spivey, James J.

Heterogeneous Catalytic Conversion of Dry Syngas to Ethanol and Higher Alcohols on Cu-Based Catalysts

Journal Article · Tue May 10 00:00:00 EDT 2011 · ACS Catalysis · OSTI ID:1384257

Gupta, Mayank; Smith, Miranda L.; Spivey, James J.

Related Subjects

catalysis (heterogeneous)
hydrogen and fuel cells
charge transport
carbon capture
carbon sequestration
materials and chemistry by design
synthesis (novel materials)

Title: Design and Synthesis of Copper-Cobalt Catalysts for the Selective Conversion of Synthesis Gas to Ethanol and Higher Alcohols

Citation Formats

References (27)

Similar Records

Related Subjects