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Title: Three-Dimensional Microstructural Imaging of Sulfur Poisoning-Induced Degradation in a Ni-YSZ Anode of Solid Oxide Fuel Cells

Authors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Heterogeneous Functional Materials Center (HeteroFoaM)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1383947
DOE Contract Number:  
SC0001061
Resource Type:
Journal Article
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 4; Journal Issue: 1; Related Information: HeteroFoaM partners with University of South Carolina (lead); University of California, Santa Barbara; University of Connecticut; Georgia Institute of Technology; Princeton University; Rochester Institute of Technology; Savannah River National Laboratory; University of South Carolina; University of Utah; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
catalysis (heterogeneous), energy storage (including batteries and capacitors), hydrogen and fuel cells, mechanical behavior, charge transport, membrane, carbon sequestration, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Harris, William M., Lombardo, Jeffrey J., Nelson, George J., Lai, Barry, Wang, Steve, Vila-Comamala, Joan, Liu, Mingfei, Liu, Meilin, and Chiu, Wilson K. S. Three-Dimensional Microstructural Imaging of Sulfur Poisoning-Induced Degradation in a Ni-YSZ Anode of Solid Oxide Fuel Cells. United States: N. p., 2014. Web. doi:10.1038/srep05246.
Harris, William M., Lombardo, Jeffrey J., Nelson, George J., Lai, Barry, Wang, Steve, Vila-Comamala, Joan, Liu, Mingfei, Liu, Meilin, & Chiu, Wilson K. S. Three-Dimensional Microstructural Imaging of Sulfur Poisoning-Induced Degradation in a Ni-YSZ Anode of Solid Oxide Fuel Cells. United States. doi:10.1038/srep05246.
Harris, William M., Lombardo, Jeffrey J., Nelson, George J., Lai, Barry, Wang, Steve, Vila-Comamala, Joan, Liu, Mingfei, Liu, Meilin, and Chiu, Wilson K. S. Tue . "Three-Dimensional Microstructural Imaging of Sulfur Poisoning-Induced Degradation in a Ni-YSZ Anode of Solid Oxide Fuel Cells". United States. doi:10.1038/srep05246.
@article{osti_1383947,
title = {Three-Dimensional Microstructural Imaging of Sulfur Poisoning-Induced Degradation in a Ni-YSZ Anode of Solid Oxide Fuel Cells},
author = {Harris, William M. and Lombardo, Jeffrey J. and Nelson, George J. and Lai, Barry and Wang, Steve and Vila-Comamala, Joan and Liu, Mingfei and Liu, Meilin and Chiu, Wilson K. S.},
abstractNote = {},
doi = {10.1038/srep05246},
journal = {Scientific Reports},
issn = {2045-2322},
number = 1,
volume = 4,
place = {United States},
year = {2014},
month = {6}
}

Works referenced in this record:

Sulfur Poisoning and Regeneration of Ni-Based Anodes in Solid Oxide Fuel Cells
journal, January 2007

  • Zha, Shaowu; Cheng, Zhe; Liu, Meilin
  • Journal of The Electrochemical Society, Vol. 154, Issue 2
  • DOI: 10.1149/1.2404779

Three-Dimensional Reconstruction of Porous LSCF Cathodes
journal, January 2007

  • Gostovic, D.; Smith, J. R.; Kundinger, D. P.
  • Electrochemical and Solid-State Letters, Vol. 10, Issue 12
  • DOI: 10.1149/1.2794672

Zone-doubled Fresnel zone plates for high-resolution hard X-ray full-field transmission microscopy
journal, July 2012

  • Vila-Comamala, Joan; Pan, Yongsheng; Lombardo, Jeffrey J.
  • Journal of Synchrotron Radiation, Vol. 19, Issue 5
  • DOI: 10.1107/S0909049512029640

Double Perovskites as Anode Materials for Solid-Oxide Fuel Cells
journal, April 2006


In-situ observation of nickel oxidation using synchrotron based full-field transmission X-ray microscopy
journal, February 2013

  • Kiss, Andrew M.; Harris, William M.; Wang, Steve
  • Applied Physics Letters, Vol. 102, Issue 5
  • DOI: 10.1063/1.4789991

Nondestructive Nanoscale 3D Elemental Mapping and Analysis of a Solid Oxide Fuel Cell Anode
journal, January 2010

  • Grew, Kyle N.; Chu, Yong S.; Yi, Jaemock
  • Journal of The Electrochemical Society, Vol. 157, Issue 6
  • DOI: 10.1149/1.3355957

Promotion of water-mediated carbon removal by nanostructured barium oxide/nickel interfaces in solid oxide fuel cells
journal, June 2011

  • Yang, Lei; Choi, YongMan; Qin, Wentao
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1359

Microstructural analysis of a solid oxide fuel cell anode using focused ion beam techniques coupled with electrochemical simulation
journal, August 2010


Nondestructive volumetric 3-D chemical mapping of nickel-sulfur compounds at the nanoscale
journal, January 2012

  • Harris, William M.; Nelson, George J.; Kiss, Andrew M.
  • Nanoscale, Vol. 4, Issue 5
  • DOI: 10.1039/c2nr11690a

Sulfur Poisoning on SOFC Ni Anodes: Thermodynamic Analyses within Local Equilibrium Anode Reaction Model
journal, January 2010

  • Kishimoto, Haruo; Horita, Teruhisa; Yamaji, Katsuhiko
  • Journal of The Electrochemical Society, Vol. 157, Issue 6
  • DOI: 10.1149/1.3362896

Using Synchrotron X-Ray Nano-CT to Characterize SOFC Electrode Microstructures in Three-Dimensions at Operating Temperature
journal, January 2011

  • Shearing, P. R.; Bradley, R. S.; Gelb, J.
  • Electrochemical and Solid-State Letters, Vol. 14, Issue 10
  • DOI: 10.1149/1.3615824

Mechanism for SOFC anode degradation from hydrogen sulfide exposure
journal, July 2008


H[sub 2]S Poisoning of Solid Oxide Fuel Cells
journal, January 2006

  • Sasaki, K.; Susuki, K.; Iyoshi, A.
  • Journal of The Electrochemical Society, Vol. 153, Issue 11
  • DOI: 10.1149/1.2336075

Focused ion beam preparation of samples for X-ray nanotomography
journal, July 2012

  • Lombardo, Jeffrey J.; Ristau, Roger A.; Harris, William M.
  • Journal of Synchrotron Radiation, Vol. 19, Issue 5
  • DOI: 10.1107/S0909049512027252

Three-dimensional microstructural imaging methods for energy materials
journal, January 2013

  • Cocco, Alex P.; Nelson, George J.; Harris, William M.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 39
  • DOI: 10.1039/c3cp52356j

Three-dimensional reconstruction and analysis of an entire solid oxide fuel cell by full-field transmission X-ray microscopy
journal, July 2013


Comparison of SOFC cathode microstructure quantified using X-ray nanotomography and focused ion beam–scanning electron microscopy
journal, June 2011

  • Nelson, George J.; Harris, William M.; Lombardo, Jeffrey J.
  • Electrochemistry Communications, Vol. 13, Issue 6
  • DOI: 10.1016/j.elecom.2011.03.016

Sr2Fe4/3Mo2/3O6 as anodes for solid oxide fuel cells
journal, December 2010