Artificial hydrogenases
journal
June 2010
Helix−Loop−Helix Peptides as Scaffolds for the Construction of Bridged Metal Assemblies in Proteins: The Spectroscopic A-Cluster Structure in Carbon Monoxide Dehydrogenase
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October 2001
Insights into [FeFe]-Hydrogenase Structure, Mechanism, and Maturation
journal
August 2011
A nickel–manganese catalyst as a biomimic of the active site of NiFe hydrogenases: a combined electrocatalytical and DFT mechanistic study
journal
January 2011
Activation and Inactivation of Hydrogenase Function and the Catalytic Cycle: Spectroelectrochemical Studies
journal
October 2007
Occurrence, Classification, and Biological Function of Hydrogenases: An Overview
journal
October 2007
Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase
journal
October 2011
Iron-sulfur clusters: ever-expanding roles
journal
April 2006
Structural basis for a [4Fe-3S] cluster in the oxygen-tolerant membrane-bound [NiFe]-hydrogenase
journal
October 2011
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+
journal
August 2008
A Density Functional Theory Study on the Active Center of Fe-Only Hydrogenase: Characterization and Electronic Structure of the Redox States
journal
May 2002
A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production
journal
August 2011
Acidic ionic liquid/water solution as both medium and proton source for electrocatalytic H2 evolution by [Ni(P2N2)2]2+ complexes
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June 2012
Alteration of the oxygen-dependent reactivity of de novo Due Ferri proteins
journal
September 2012
Investigating and Exploiting the Electrocatalytic Properties of Hydrogenases
journal
October 2007
Synthesis and characterization of de novo designed peptides modelling the binding sites of [4Fe–4S] clusters in photosystem I
journal
August 2009
A third type of hydrogenase catalyzing H2 activation
journal
January 2007
[Fe4S4]- and [Fe3S4]-cluster formation in synthetic peptides
journal
November 2011
Ferrocenoyl peptides with sulfur-containing side chains: synthesis, solid state and solution structures
journal
December 2004
Visible Light-Driven Hydrogen Production from Aqueous Protons Catalyzed by Molecular Cobaloxime Catalysts
journal
June 2009
Relation between anaerobic inactivation and oxygen tolerance in a large series of NiFe hydrogenase mutants
journal
November 2012
Improving the efficiency of water splitting in dye-sensitized solar cells by using a biomimetic electron transfer mediator
journal
April 2012
Effect of Iron-Sulfur Cluster Environment in Modulating the Thermodynamic Properties and Biological Function of Ferredoxin from Pyrococcus furiosus †
journal
May 1998
Synthetic and Structural Studies on [Fe 2 (SR) 2 (CN) x (CO) 6 - x ] x - as Active Site Models for Fe-Only Hydrogenases
journal
December 2001
An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen
journal
February 2013
Structure and Function of [Fe]-Hydrogenase and its Iron-Guanylylpyridinol (FeGP) Cofactor
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December 2010
Reaction of Fe3(CO)12 with octreotide—chemical, electrochemical and biological investigations
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January 2010
The evolution of Photosystem II: insights into the past and future
journal
May 2010
Reversible Electrocatalytic Production and Oxidation of Hydrogen at Low Overpotentials by a Functional Hydrogenase Mimic
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February 2012
Photo-catalytic oxidation of a di-nuclear manganese centre in an engineered bacterioferritin ‘reaction centre’
journal
September 2009
Cobalt and nickel diimine-dioxime complexes as molecular electrocatalysts for hydrogen evolution with low overvoltages
journal
November 2009
Functional models for the oxygen-evolving complex of photosystem II
journal
February 2008
Structure, function and biosynthesis of O2-tolerant hydrogenases
journal
January 2013
Classification and phylogeny of hydrogenases
journal
August 2001
Construction of Heterometallic Clusters in a Small Peptide Scaffold as [NiFe]-Hydrogenase Models: Development of a Synthetic Methodology
journal
August 2012
Importance of the Protein Framework for Catalytic Activity of [FeFe]-Hydrogenases
journal
November 2011
The Role of a Dipeptide Outer-Coordination Sphere on H 2 -Production Catalysts: Influence on Catalytic Rates and Electron Transfer
journal
December 2012
A Ferrocene-Peptide Conjugate as a Hydrogenase Model System
journal
October 2008
Electrocatalytic Water Oxidation with a Copper(II) Polypeptide Complex
journal
January 2013
Incorporating Peptides in the Outer-Coordination Sphere of Bioinspired Electrocatalysts for Hydrogen Production
journal
May 2011
Catalytic hydrogen production by a Ni–Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step
journal
January 2013
Catalysis by a De Novo Zinc-Mediated Protein Interface: Implications for Natural Enzyme Evolution and Rational Enzyme Engineering
journal
April 2012
Realizing artificial photosynthesis
journal
January 2012
Computational redesign of a mononuclear zinc metalloenzyme for organophosphate hydrolysis
journal
February 2012
Designing artificial enzymes by intuition and computation
journal
December 2009
Hydrogenase sophistication
journal
January 1999
Electron transfer and hydrogen generation from a molecular dyad: platinum(ii) alkynyl complex anchored to [FeFe] hydrogenase subsite mimic
journal
January 2012
Proton Delivery and Removal in [Ni(P R 2 N R ′ 2 ) 2 ] 2+ Hydrogen Production and Oxidation Catalysts
journal
November 2012
A Functional [NiFe]Hydrogenase Mimic That Catalyzes Electron and Hydride Transfer from H2
journal
February 2013
Density functional study of the catalytic cycle of nickel–iron [NiFe] hydrogenases and the involvement of high-spin nickel(II)
journal
March 2006
Structure/Function Relationships of [NiFe]- and [FeFe]-Hydrogenases
journal
October 2007
Efficient water oxidation at carbon nanotube–polyoxometalate electrocatalytic interfaces
journal
August 2010
Artificial [FeFe]-Hydrogenase: On Resin Modification of an Amino Acid to Anchor a Hexacarbonyldiiron Cluster in a Peptide Framework
journal
November 2010
De novo design of a non-natural fold for an iron–sulfur protein: Alpha-helical coiled-coil with a four-iron four-sulfur cluster binding site in its central core
journal
March 2010
Photocatalytic hydrogen evolution by a diiron hydrogenase model based on a peptide fragment of cytochrome c556 with an attached diiron carbonyl cluster and an attached ruthenium photosensitizer
journal
March 2012
Solar Fuels via Artificial Photosynthesis
journal
December 2009
Functionally Relevant Interplay between the Fe 4 S 4 Cluster and CN − Ligands in the Active Site of [FeFe]-Hydrogenases
journal
April 2010
De Novo Design and Structural Characterization of Proteins and Metalloproteins
journal
June 1999
Oxygen-tolerant hydrogenases in hydrogen-based technologies
journal
June 2011
Sulfonated Diiron Complexes as Water-Soluble Models of the [Fe–Fe]-Hydrogenase Enzyme Active Site
journal
June 2011
Empirical and computational design of iron-sulfur cluster proteins
journal
August 2012
An artificial di-iron oxo-protein with phenol oxidase activity
journal
November 2009
Emerging Paradigms for Complex Iron-Sulfur Cofactor Assembly and Insertion
journal
July 2012
Architecture of the Photosynthetic Oxygen-Evolving Center
journal
March 2004
A hydrogenase model system based on the sequence of cytochrome c: photochemical hydrogen evolution in aqueous media
journal
January 2011
The rational design and construction of a cuboidal iron-sulfur protein
journal
June 1997
Characterization of the Fundamental Protein Ligand Requirements of [4Fe-4S] 2+/+ Clusters with Sixteen Amino Acid Maquettes
journal
October 1998
The structure and mechanism of iron-hydrogenases
journal
November 1990
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals
journal
March 2010
Negatively Charged Residues and Hydrogen Bonds Tune the Ligand Histidine p K a Values of Rieske Iron−Sulfur Proteins †
journal
October 2004
Novel, Oxygen-Insensitive Group 5 [NiFe]-Hydrogenase in Ralstonia eutropha
journal
June 2013
A novel FeS cluster in Fe-only hydrogenases
journal
March 2000
Principles for designing ideal protein structures
journal
November 2012
Moving Protons with Pendant Amines: Proton Mobility in a Nickel Catalyst for Oxidation of Hydrogen
journal
September 2011
Merging the old with the new
journal
December 2011
Biological water oxidation: Lessons from Nature
journal
August 2012
The design and synthesis of artificial photosynthetic antennas, reaction centres and membranes
journal
October 2002
Kinetics and mechanism of the substitution reactions of bis(mercaptotricarbonyliron) complexes
journal
November 1973
Ferredoxin and ferredoxin-heme maquettes
journal
December 1996
Synthetic Hydrogenases: Incorporation of an Iron Carbonyl Thiolate into a Designed Peptide
journal
December 2007
Modelling NiFe hydrogenases: nickel-based electrocatalysts for hydrogen production
journal
January 2008
Iron-Sulfur Clusters: Nature's Modular, Multipurpose Structures
journal
August 1997
Evolution of an [FeFe] hydrogenase with decreased oxygen sensitivity
journal
February 2012
Catalytic Hydrogen Oxidation: Dawn of a New Iron Age
journal
May 2013
Hydrogen Oxidation and Production Using Nickel-Based Molecular Catalysts with Positioned Proton Relays
journal
January 2006
Dithiomethylether as a Ligand in the Hydrogenase H-Cluster
journal
April 2008
Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase
journal
November 1999
Activation Process of [NiFe] Hydrogenase Elucidated by High-Resolution X-Ray Analyses: Conversion of the Ready to the Unready State
journal
November 2005
From Hydrogenases to Noble Metal-Free Catalytic Nanomaterials for H2 Production and Uptake
journal
December 2009
Structural informatics, modeling, and design with an open-source Molecular Software Library (MSL)
journal
May 2012
A low-spin iron with CN and CO as intrinsic ligands forms the core of the active site in [Fe]-hydrogenases
journal
December 1998
Biological activition of hydrogen
journal
January 1997
The organometallic active site of [Fe]hydrogenase: Models and entatic states
journal
March 2003
Engineering oxidoreductases: maquette proteins designed from scratch
journal
May 2012
Atomic Resolution Structures of Rieske Iron-Sulfur Protein: Role of Hydrogen Bonds in Tuning the Redox Potential of Iron-Sulfur Clusters
journal
January 2007
Where Water Is Oxidized to Dioxygen: Structure of the Photosynthetic Mn4Ca Cluster
journal
November 2006
Harnessing natures ability to control metal ion coordination geometry using de novo designed peptides
journal
January 2009
Intermediates in the Catalytic Cycle of [NiFe] Hydrogenase: Functional Spectroscopy of the Active Site
journal
April 2010
Design of membrane proteins: toward functional systems
journal
December 2009
A Basis Set of de Novo Coiled-Coil Peptide Oligomers for Rational Protein Design and Synthetic Biology
journal
May 2012
Determination of Nonligand Amino Acids Critical to [4Fe-4S] 2+/+ Assembly in Ferredoxin Maquettes †
journal
August 1999
Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases †
journal
June 2009
Design and engineering of an O2 transport protein
journal
March 2009
A di-iron dithiolate possessing structural elements of the carbonyl/cyanide sub-site of the H-centre of Fe-only hydrogenase
journal
January 1999
Towards complete cofactor arrangement in the 3.0 Å resolution structure of photosystem II
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December 2005
Theoretical and Computational Protein Design
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May 2011
Shaping the beating heart of artificial photosynthesis: oxygenic metal oxide nano-clusters
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January 2012
A modular, energy-based approach to the development of nickel containing molecular electrocatalysts for hydrogen production and oxidation
journal
August 2013
A Cyclodextrin Host/Guest Approach to a Hydrogenase Active Site Biomimetic Cavity
Singleton, Michael L.; Reibenspies, Joseph H.; Darensbourg, Marcetta Y.
Journal of the American Chemical Society, Vol. 132, Issue 26
https://doi.org/10.1021/ja103774j
journal
July 2010
Computational Design of Peptides That Target Transmembrane Helices
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March 2007
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å
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April 2011
Fundamentals of H 2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H 2 Production and Storage
journal
October 2007
X-ray Crystal Structure of the Fe-Only Hydrogenase (CpI) from Clostridium pasteurianum to 1.8 Angstrom Resolution
journal
December 1998
Infrared-Detectable Group Senses Changes in Charge Density on the Nickel Center in Hydrogenase from Chromatium vinosum
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April 1995
Mechanism of electrocatalytic hydrogen production by a di-iron model of iron–iron hydrogenase: A density functional theory study of proton dissociation constants and electrode reduction potentials
journal
January 2010
Desulfovibrio desulfuricans iron hydrogenase: the structure shows unusual coordination to an active site Fe binuclear center
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January 1999
Modulation of function in a minimalist heme-binding membrane protein
journal
February 2012
The environment of Fe4S4 clusters in ferredoxins and high-potential iron proteins. New information from x-ray crystallography and resonance Raman spectroscopy
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March 1991
Thiolate Bridged Nickel–Iron Complexes Containing both Iron(0) and Iron(II) Carbonyls
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November 1996
Calcium Manganese(III) Oxides (CaMn 2 O 4 ⋅ x H 2 O) as Biomimetic Oxygen-Evolving Catalysts
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March 2010
Computational protein design: structure, function and combinatorial diversity
journal
June 2007
Structural and Spectroscopic Features of Mixed Valent Fe II Fe I Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase
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July 2012
A Highly Efficient Photocatalytic System for Hydrogen Production by a Robust Hydrogenase Mimic in an Aqueous Solution
journal
March 2011
Investigating the Role of the Outer-Coordination Sphere in [Ni(P Ph 2 N Ph-R 2 ) 2 ] 2+ Hydrogenase Mimics
journal
June 2012
Probing Variable Axial Ligation in Nickel Superoxide Dismutase Utilizing Metallopeptide-Based Models: Insight into the Superoxide Disproportionation Mechanism
journal
November 2007
Understanding and Tuning the Catalytic Bias of Hydrogenase
journal
May 2012
[FeFe] hydrogenases and their evolution: a genomic perspective
journal
March 2007
The Outer-Coordination Sphere: Incorporating Amino Acids and Peptides as Ligands for Homogeneous Catalysts to Mimic Enzyme Function
journal
October 2012
A double life: cytosolic aconitase as a regulatory RNA binding protein.
journal
January 1993
Cobalt complexes as artificial hydrogenases for the reductive side of water splitting
journal
August 2013
Phosphine Coordination to a Cobalt Diimine–Dioxime Catalyst Increases Stability during Light-Driven H 2 Production
journal
January 2012
Protein engineering of cytochrome b562 for quinone binding and light-induced electron transfer
journal
December 2004
The crystal structure of an oxygen-tolerant hydrogenase uncovers a novel iron-sulphur centre
journal
October 2011
A Cobalt–Dithiolene Complex for the Photocatalytic and Electrocatalytic Reduction of Protons
journal
October 2011
Chelate Control of Diiron(I) Dithiolates Relevant to the [Fe−Fe]- Hydrogenase Active Site
journal
March 2007
Reflections on small molecule manganese models that seek to mimic photosynthetic water oxidation chemistry
journal
February 2008
Photo-induced hydrogen production in a helical peptide incorporating a [FeFe] hydrogenase active site mimic
journal
January 2012
Oxygen Evolution Catalysis by a Dimanganese Complex and Its Relation to Photosynthetic Water Oxidation
journal
March 2008
Binding of Exogenously Added Carbon Monoxide at the Active Site of the Iron-Only Hydrogenase (CpI) from Clostridium pasteurianum † , ‡
journal
October 1999
Crystal structure of the nickel–iron hydrogenase from Desulfovibrio gigas
journal
February 1995
Hydrogenases: Hydrogen-Activating Enzymes
journal
March 2002
Hydrolytic catalysis and structural stabilization in a designed metalloprotein
journal
November 2011
Directing protonation in [FeFe] hydrogenase active site models by modifications in their second coordination sphere
journal
January 2010
Crystallographic and FTIR Spectroscopic Evidence of Changes in Fe Coordination Upon Reduction of the Active Site of the Fe-Only Hydrogenase from Desulfovibrio d esulfuricans
journal
February 2001
Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions
journal
June 2012
A Model of the [FeFe] Hydrogenase Active Site with a Biologically Relevant Azadithiolate Bridge: A Spectroscopic and Theoretical Investigation
journal
January 2011
A Cell-Free Microtiter Plate Screen for Improved [FeFe] Hydrogenases
journal
May 2010
First Generation Analogues of the Binuclear Site in the Fe-Only Hydrogenases: Fe 2 (μ-SR) 2 (CO) 4 (CN) 2 2 -
journal
October 1999
Impact of Ligand Exchange in Hydrogen Production from Cobaloxime-Containing Photocatalytic Systems
journal
November 2011
[NiFe] hydrogenases: A common active site for hydrogen metabolism under diverse conditions
journal
August 2013