Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H red State?

Wang, Wenguang; Rauchfuss, Thomas B.; Moore, Curtis E.; Rheingold, Arnold L.; De Gioia, Luca; Zampella, Giuseppe

doi:10.1002/chem.201303351

Title: Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H _red State?

Journal Article · Tue Oct 15 00:00:00 EDT 2013 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201303351· OSTI ID:1383080

Wang, Wenguang; Rauchfuss, Thomas B.; Moore, Curtis E.; Rheingold, Arnold L.; De Gioia, Luca; Zampella, Giuseppe

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001059

OSTI ID:: 1383080

Journal Information:: Chemistry - A European Journal, Vol. 19, Issue 46; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; ISSN 0947-6539

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

References (20)

Redox and Structural Properties of Mixed-Valence Models for the Active Site of the [FeFe]-Hydrogenase: Progress and Challenges Justice, Aaron K.; De Gioia, Luca; Nilges, Mark J. Inorganic Chemistry, Vol. 47, Issue 16 https://doi.org/10.1021/ic8007552	journal	August 2008
Chelate Control of Diiron(I) Dithiolates Relevant to the [Fe−Fe]- Hydrogenase Active Site Justice, Aaron K.; Zampella, Giuseppe; De Gioia, Luca Inorganic Chemistry, Vol. 46, Issue 5 https://doi.org/10.1021/ic0618706	journal	March 2007
Evidence for the Formation of Terminal Hydrides by Protonation of an Asymmetric Iron Hydrogenase Active Site Mimic Ezzaher, Salah; Capon, Jean-François; Gloaguen, Frédéric Inorganic Chemistry, Vol. 46, Issue 9 https://doi.org/10.1021/ic0703124	journal	April 2007
A Mixed-Valent, Fe(II)Fe(I), Diiron Complex Reproduces the Unique Rotated State of the [FeFe]Hydrogenase Active Site Liu, Tianbiao; Darensbourg, Marcetta Y. Journal of the American Chemical Society, Vol. 129, Issue 22 https://doi.org/10.1021/ja071851a	journal	June 2007
Hydrogen Bonding in Organometallic Crystals. 6. ^† X−H---M Hydrogen Bonds and M---(H−X) Pseudo-Agostic Bonds Braga, Dario; Grepioni, Fabrizia; Tedesco, Emilio Organometallics, Vol. 16, Issue 9 https://doi.org/10.1021/om9608364	journal	April 1997
The effect of bridgehead steric bulk on the ground state and intramolecular exchange processes of (μ-SCH2CR2CH2S)[Fe(CO)3][Fe(CO)2L] complexes Singleton, Michael L.; Jenkins, Roxanne M.; Klemashevich, Cory L. Comptes Rendus Chimie, Vol. 11, Issue 8 https://doi.org/10.1016/j.crci.2008.01.018	journal	August 2008
Activation and Inactivation of Hydrogenase Function and the Catalytic Cycle: Spectroelectrochemical Studies De Lacey, Antonio L.; Fernández, Víctor M.; Rousset, Marc Chemical Reviews, Vol. 107, Issue 10 https://doi.org/10.1021/cr0501947	journal	October 2007
Structural and Spectroscopic Features of Mixed Valent Fe ^II Fe ^I Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase Hsieh, Chung-Hung; Erdem, Özlen F.; Harman, Scott D. Journal of the American Chemical Society, Vol. 134, Issue 31 https://doi.org/10.1021/ja304866r	journal	July 2012
Low-Coordinate Iron(II) Amido Complexes of β-Diketiminates: Synthesis, Structure, and Reactivity Eckert, Nathan A.; Smith, Jeremy M.; Lachicotte, Rene J. Inorganic Chemistry, Vol. 43, Issue 10 https://doi.org/10.1021/ic035483x	journal	May 2004
Coordination Sphere Flexibility of Active-Site Models for Fe-Only Hydrogenase: Studies in Intra- and Intermolecular Diatomic Ligand Exchange Lyon, Erica J.; Georgakaki, Irene P.; Reibenspies, Joseph H. Journal of the American Chemical Society, Vol. 123, Issue 14 https://doi.org/10.1021/ja003147z	journal	April 2001
De Novo Design of Synthetic Di-Iron(I) Complexes as Structural Models of the Reduced Form of Iron−Iron Hydrogenase Tye, Jesse W.; Darensbourg, Marcetta Y.; Hall, Michael B. Inorganic Chemistry, Vol. 45, Issue 4 https://doi.org/10.1021/ic051231f	journal	February 2006
Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the [FeFe]-Hydrogenase Active Site Olsen, Matthew T.; Bruschi, Maurizio; De Gioia, Luca Journal of the American Chemical Society, Vol. 130, Issue 36 https://doi.org/10.1021/ja802268p	journal	August 2008
Mixed-valence [FeIFeII] hydrogenase active site model complexes stabilized by a bidentate carborane bis-phosphine ligand Karnahl, Michael; Tschierlei, Stefanie; Erdem, Özlen F. Dalton Transactions, Vol. 41, Issue 40 https://doi.org/10.1039/c2dt31192e	journal	January 2012
Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases ^† Tard, Cédric; Pickett, Christopher J. Chemical Reviews, Vol. 109, Issue 6 https://doi.org/10.1021/cr800542q	journal	June 2009
Spectroelectrochemical Characterization of the Active Site of the [FeFe] Hydrogenase HydA1 from Chlamydomonas reinhardtii Silakov, Alexey; Kamp, Christina; Reijerse, Eduard Biochemistry, Vol. 48, Issue 33 https://doi.org/10.1021/bi9009105	journal	August 2009
Mild Redox Complementation Enables H ₂ Activation by [FeFe]-Hydrogenase Models Camara, James M.; Rauchfuss, Thomas B. Journal of the American Chemical Society, Vol. 133, Issue 21 https://doi.org/10.1021/ja201731q	journal	June 2011
Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models Singleton, Michael L.; Bhuvanesh, Nattamai; Reibenspies, Joseph H. Angewandte Chemie, Vol. 120, Issue 49 https://doi.org/10.1002/ange.200803939	journal	November 2008
Unsaturated, Mixed-Valence Diiron Dithiolate Model for the Hox State of the [FeFe] Hydrogenase Justice, Aaron K.; Rauchfuss, Thomas B.; Wilson, Scott R. Angewandte Chemie International Edition, Vol. 46, Issue 32 https://doi.org/10.1002/anie.200702224	journal	August 2007
Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate Carroll, Maria E.; Barton, Bryan E.; Rauchfuss, Thomas B. Journal of the American Chemical Society, Vol. 134, Issue 45 https://doi.org/10.1021/ja309216v	journal	November 2012
Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models Singleton, Michael L.; Bhuvanesh, Nattamai; Reibenspies, Joseph H. Angewandte Chemie International Edition, Vol. 47, Issue 49 https://doi.org/10.1002/anie.200803939	journal	November 2008

Similar Records

Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H-red State?

Journal Article · Tue Oct 15 00:00:00 EDT 2013 · Chemistry - A European Journal · OSTI ID:1383080

Wang, W. G.; Rauchfuss, Thomas B.; Moore, C. E.; +3 more

New Reactions of Terminal Hydrides on a Diiron Dithiolate

Journal Article · Wed Apr 16 00:00:00 EDT 2014 · Journal of the American Chemical Society · OSTI ID:1383080

Wang, Wenguang; Rauchfuss, Thomas B.; Zhu, Lingyang; +1 more

New Reactions of Terminal Hydrides on a Diiron Dithiolate

Journal Article · Wed Apr 02 00:00:00 EDT 2014 · Journal of the American Chemical Society · OSTI ID:1383080

Wang, Wenguang; Rauchfuss, Thomas B.; Zhu, Lingyang; +1 more

Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
solar (photovoltaic)
solar (fuels)
photosynthesis (natural and artificial)
bio-inspired
hydrogen and fuel cells
electrodes - solar
defects
charge transport
spin dynamics
membrane
materials and chemistry by design
optics
synthesis (novel materials)
synthesis (self-assembly)

Title: Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H red State?

Citation Formats

References (20)

Similar Records

Related Subjects

Title: Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H _red State?