Beyond PCBM: Understanding the Photovoltaic Performance of Blends of Indene-C 60 Multiadducts with Poly(3-hexylthiophene)

Nardes, Alexandre M.; Ferguson, Andrew J.; Whitaker, James B.; Larson, Bryon W.; Larsen, Ross E.; Maturová, Klára; Graf, Peter A.; Boltalina, Olga V.; Strauss, Steven H.; Kopidakis, Nikos

doi:10.1002/adfm.201200336

Title: Beyond PCBM: Understanding the Photovoltaic Performance of Blends of Indene-C ₆₀ Multiadducts with Poly(3-hexylthiophene)

Journal Article · Mon Jun 11 00:00:00 EDT 2012 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.201200336· OSTI ID:1381399

Nardes, Alexandre M.; Ferguson, Andrew J.; Whitaker, James B.; Larson, Bryon W.; Larsen, Ross E.; Maturová, Klára; Graf, Peter A.; Boltalina, Olga V.; Strauss, Steven H.; Kopidakis, Nikos

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Molecularly Engineered Energy Materials (MEEM)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001342

OSTI ID:: 1381399

Journal Information:: Advanced Functional Materials, Vol. 22, Issue 19; Related Information: MEEM partners with University of California, Los Angeles (lead); University of California, Berkeley; Eastern Washington University; University of Kansas; National Renewable Energy Laboratory; ISSN 1616-301X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (50)

Absence of Postnanosecond Charge Carrier Relaxation in Poly(3-hexylthiophene)/Fullerene Blends Savenije, Tom J.; Murthy, D. H. K.; Gunz, Matthias The Journal of Physical Chemistry Letters, Vol. 2, Issue 12 https://doi.org/10.1021/jz200569h	journal	May 2011
Charge Carrier Formation in Polythiophene/Fullerene Blend Films Studied by Transient Absorption Spectroscopy Ohkita, Hideo; Cook, Steffan; Astuti, Yeni Journal of the American Chemical Society, Vol. 130, Issue 10 https://doi.org/10.1021/ja076568q	journal	March 2008
High Photovoltaic Performance of a Low-Bandgap Polymer Mühlbacher, D.; Scharber, M.; Morana, M. Advanced Materials, Vol. 18, Issue 21 https://doi.org/10.1002/adma.200600160	journal	November 2006
Infrared photocurrent spectral response from plastic solar cell with low-band-gap polyfluorene and fullerene derivative Wang, Xiangjun; Perzon, Erik; Delgado, Juan Luis Applied Physics Letters, Vol. 85, Issue 21 https://doi.org/10.1063/1.1825070	journal	November 2004
Increasing the Open Circuit Voltage of Bulk-Heterojunction Solar Cells by Raising the LUMO Level of the Acceptor Kooistra, Floris B.; Knol, Joop; Kastenberg, Fredrik Organic Letters, Vol. 9, Issue 4 https://doi.org/10.1021/ol062666p	journal	February 2007
Dark Carriers, Trapping, and Activation Control of Carrier Recombination in Neat P3HT and P3HT:PCBM Blends Ferguson, Andrew J.; Kopidakis, Nikos; Shaheen, Sean E. The Journal of Physical Chemistry C, Vol. 115, Issue 46 https://doi.org/10.1021/jp208014v	journal	October 2011
Electrodeless time-resolved microwave conductivity study of charge-carrier photogeneration in regioregular poly(3-hexylthiophene) thin films Dicker, Gerald; de Haas, Matthijs P.; Siebbeles, Laurens D. A. Physical Review B, Vol. 70, Issue 4 https://doi.org/10.1103/PhysRevB.70.045203	journal	July 2004
Prolonging Charge Separation in P3HT−SWNT Composites Using Highly Enriched Semiconducting Nanotubes Holt, Josh M.; Ferguson, Andrew J.; Kopidakis, Nikos Nano Letters, Vol. 10, Issue 11 https://doi.org/10.1021/nl102753z	journal	November 2010
Temperature-Independent Charge Carrier Photogeneration in P3HT−PCBM Blends with Different Morphology Grzegorczyk, Wojciech J.; Savenije, Tom J.; Dykstra, Tieneke E. The Journal of Physical Chemistry C, Vol. 114, Issue 11 https://doi.org/10.1021/jp9119364	journal	March 2010
Synthesis and photovoltaic properties of biindene-C70 monoadduct as acceptor in polymer solar cells He, Youjun; Chen, Hsiang-Yu; Zhao, Guangjin Solar Energy Materials and Solar Cells, Vol. 95, Issue 7 https://doi.org/10.1016/j.solmat.2011.01.045	journal	July 2011
Effect of multiple adduct fullerenes on charge generation and transport in photovoltaic blends with poly(3-hexylthiophene-2,5-diyl) Faist, Mark A.; Keivanidis, Panagiotis E.; Foster, Samuel Journal of Polymer Science Part B: Polymer Physics, Vol. 49, Issue 1 https://doi.org/10.1002/polb.22125	journal	September 2010
Recombination and loss analysis in polythiophene based bulk heterojunction photodetectors Schilinsky, Pavel; Waldauf, Christoph; Brabec, Christoph J. Applied Physics Letters, Vol. 81, Issue 20 https://doi.org/10.1063/1.1521244	journal	November 2002
Polymer solar cells with enhanced open-circuit voltage and efficiency Chen, Hsiang-Yu; Hou, Jianhui; Zhang, Shaoqing Nature Photonics, Vol. 3, Issue 11, p. 649-653 https://doi.org/10.1038/nphoton.2009.192	journal	November 2009
Polymer Solar Cells Based on a Low-Bandgap Fluorene Copolymer and a Fullerene Derivative with Photocurrent Extended to 850 nm Zhang, F.; Perzon, E.; Wang, X. Advanced Functional Materials, Vol. 15, Issue 5 https://doi.org/10.1002/adfm.200400416	journal	April 2005
Biindene-C60 adducts for the application as acceptor in polymer solar cells with higher open-circuit-voltage He, Youjun; Chen, Hsiang-Yu; Zhao, Guangjin Solar Energy Materials and Solar Cells, Vol. 95, Issue 3 https://doi.org/10.1016/j.solmat.2010.11.016	journal	March 2011
Indene−C 60 Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells He, Youjun; Chen, Hsiang-Yu; Hou, Jianhui Journal of the American Chemical Society, Vol. 132, Issue 15 https://doi.org/10.1021/ja101780s	journal	April 2010
A Low-Bandgap Poly(2,7-Carbazole) Derivative for Use in High-Performance Solar Cells Blouin, N.; Michaud, A.; Leclerc, M. Advanced Materials, Vol. 19, Issue 17, p. 2295-2300 https://doi.org/10.1002/adma.200602496	journal	September 2007
Design Rules for Donors in Bulk-Heterojunction Solar Cells—Towards 10 % Energy-Conversion Efficiency Scharber, M. C.; Mühlbacher, D.; Koppe, M. Advanced Materials, Vol. 18, Issue 6, p. 789-794 https://doi.org/10.1002/adma.200501717	journal	March 2006
The Disperse Charge-Carrier Kinetics in Regioregular Poly(3-hexylthiophene) Dicker, Gerald; de Haas, Matthijs P.; Warman, John M. The Journal of Physical Chemistry B, Vol. 108, Issue 46 https://doi.org/10.1021/jp046853l	journal	November 2004
High Efficiency Organic Photovoltaics Incorporating a New Family of Soluble Fullerene Derivatives Backer, Scott A.; Sivula, Kevin; Kavulak, David F. Chemistry of Materials, Vol. 19, Issue 12 https://doi.org/10.1021/cm070893v	journal	June 2007
Soluble Chlorofullerenes C 60 Cl 2,4,6,8,10 . Synthesis, Purification, Compositional Analysis, Stability, and Experimental/Theoretical Structure Elucidation, Including the X-ray Structure of C 1 -C 60 Cl 10 Kuvychko, Igor V.; Streletskii, Alexey V.; Shustova, Natalia B. Journal of the American Chemical Society, Vol. 132, Issue 18 https://doi.org/10.1021/ja1005256	journal	May 2010
Solar cell efficiency tables (version 30) Green, Martin A.; Emery, Keith; Hisikawa, Yoshihiro Progress in Photovoltaics: Research and Applications, Vol. 15, Issue 5 https://doi.org/10.1002/pip.781	journal	January 2007
Fullerene Bisadducts for Enhanced Open-Circuit Voltages and Efficiencies in Polymer Solar Cells Lenes, Martijn; Wetzelaer, Gert-Jan A. H.; Kooistra, Floris B. Advanced Materials, Vol. 20, Issue 11, p. 2116-2119 https://doi.org/10.1002/adma.200702438	journal	June 2008
Exciton Diffusion Measurements in Poly(3-hexylthiophene) Shaw, Paul E.; Ruseckas, Arvydas; Samuel, Ifor D. W. Advanced Materials, Vol. 20, Issue 18, p. 3516-3520 https://doi.org/10.1002/adma.200800982	journal	July 2008
The Locus of Free Charge-Carrier Generation in Solution-Cast Zn1–xMgxO/Poly(3-hexylthiophene) Bilayers for Photovoltaic Applications Piris, J.; Kopidakis, N.; Olson, D. C. Advanced Functional Materials, Vol. 17, Issue 18 https://doi.org/10.1002/adfm.200700305	journal	December 2007
Contactless Determination of the Photoconductivity Action Spectrum, Exciton Diffusion Length, and Charge Separation Efficiency in Polythiophene-Sensitized TiO ₂ Bilayers Kroeze, Jessica E.; Savenije, Tom J.; Vermeulen, Martien J. W. The Journal of Physical Chemistry B, Vol. 107, Issue 31 https://doi.org/10.1021/jp0217738	journal	August 2003
Nanomorphology and Charge Generation in Bulk Heterojunctions Based on Low-Bandgap Dithiophene Polymers with Different Bridging Atoms Morana, Mauro; Azimi, Hamed; Dennler, Gilles Advanced Functional Materials, Vol. 20, Issue 7 https://doi.org/10.1002/adfm.200900931	journal	March 2010
Electron Trapping in Higher Adduct Fullerene-Based Solar Cells Lenes, Martijn; Shelton, Steve W.; Sieval, Alex B. Advanced Functional Materials, Vol. 19, Issue 18 https://doi.org/10.1002/adfm.200900459	journal	September 2009
Solar cell efficiency tables (Version 38) Green, Martin A.; Emery, Keith; Hishikawa, Yoshihiro Progress in Photovoltaics: Research and Applications, Vol. 19, Issue 5 https://doi.org/10.1002/pip.1150	journal	July 2011
Development of New Semiconducting Polymers for High Performance Solar Cells Liang, Yongye; Wu, Yue; Feng, Danqin Journal of the American Chemical Society, Vol. 131, Issue 1 https://doi.org/10.1021/ja808373p	journal	January 2009
New Architecture for High-Efficiency Polymer Photovoltaic Cells Using Solution-Based Titanium Oxide as an Optical Spacer Kim, J. Y.; Kim, S. H.; Lee, H.-H. Advanced Materials, Vol. 18, Issue 5, p. 572-576 https://doi.org/10.1002/adma.200501825	journal	March 2006
Identifying a Threshold Impurity Level for Organic Solar Cells: Enhanced First-Order Recombination Via Well-Defined PC84BM Traps in Organic Bulk Heterojunction Solar Cells Cowan, Sarah R.; Leong, Wei Lin; Banerji, Natalie Advanced Functional Materials, Vol. 21, Issue 16 https://doi.org/10.1002/adfm.201100514	journal	June 2011
Indene−C₆₀ Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells He, Youjun; Chen, Hsiang-Yu; Hou, Jianhui Journal of the American Chemical Society, Vol. 132, Issue 4, p. 1377-1382 https://doi.org/10.1021/ja908602j	journal	February 2010
A numerical study of mobility in thin films of fullerene derivatives MacKenzie, Roderick C. I.; Frost, Jarvist M.; Nelson, Jenny The Journal of Chemical Physics, Vol. 132, Issue 6 https://doi.org/10.1063/1.3315872	journal	February 2010
Continuous Flow Synthesis of Fullerene Derivatives Seyler, Helga; Wong, Wallace W. H.; Jones, David J. The Journal of Organic Chemistry, Vol. 76, Issue 9 https://doi.org/10.1021/jo2001879	journal	May 2011
Fullerene Chemistry in Three Dimensions: Isolation of Seven Regioisomeric Bisadducts and Chiral Trisadducts of C60 and Di(ethoxycarbonyl)methylene Hirsch, Andreas; Lamparth, Iris; Karfunkel, Heinrich R. Angewandte Chemie International Edition in English, Vol. 33, Issue 4 https://doi.org/10.1002/anie.199404371	journal	March 1994
Diphenylmethanofullerenes: New and Efficient Acceptors in Bulk-Heterojunction Solar Cells Riedel, I.; von Hauff, E.; Parisi, J. Advanced Functional Materials, Vol. 15, Issue 12 https://doi.org/10.1002/adfm.200500097	journal	December 2005
On the analysis of fluorescence decay kinetics by the method of least-squares Grinvald, Amiram; Steinberg, Izchak Z. Analytical Biochemistry, Vol. 59, Issue 2 https://doi.org/10.1016/0003-2697(74)90312-1	journal	June 1974
The Yield and Mobility of Charge Carriers in Smooth and Nanoporous TiO 2 Films Savenije, T. J.; de Haas, M. P.; Warman, J. M. Zeitschrift für Physikalische Chemie, Vol. 212, Issue Part_2 https://doi.org/10.1524/zpch.1999.212.Part_2.201	journal	January 1999
Endohedral fullerenes for organic photovoltaic devices Ross, Russel B.; Cardona, Claudia M.; Guldi, Dirk M. Nature Materials, Vol. 8, Issue 3 https://doi.org/10.1038/nmat2379	journal	February 2009
Polymer solar cells with novel fullerene-based acceptor Riedel, I.; Martin, N.; Giacalone, F. Thin Solid Films, Vol. 451-452 https://doi.org/10.1016/j.tsf.2003.10.088	journal	March 2004
Origin of the Open Circuit Voltage of Plastic Solar Cells Brabec, C. J.; Cravino, A.; Meissner, D. Advanced Functional Materials, Vol. 11, Issue 5 https://doi.org/10.1002/1616-3028(200110)11:5<374::AID-ADFM374>3.0.CO;2-W	journal	October 2001
Excitonic Solar Cells Gregg, Brian A. The Journal of Physical Chemistry B, Vol. 107, Issue 20 https://doi.org/10.1021/jp022507x	journal	May 2003
New route for [60]fullerene functionalisation in [4+2] cycloaddition reaction using indene Puplovskis, Austris; Kacens, Janis; Neilands, Ojars Tetrahedron Letters, Vol. 38, Issue 2 https://doi.org/10.1016/S0040-4039(96)02293-9	journal	January 1997
Signature of exciton annihilation in the photoconductance of regioregular poly(3-hexylthiophene) Dicker, Gerald; de Haas, Matthijs P.; Siebbeles, Laurens D. A. Physical Review B, Vol. 71, Issue 15 https://doi.org/10.1103/PhysRevB.71.155204	journal	April 2005
Photogeneration and Ultrafast Dynamics of Excitons and Charges in P3HT/PCBM Blends Piris, Jorge; Dykstra, Tieneke E.; Bakulin, Artem A. The Journal of Physical Chemistry C, Vol. 113, Issue 32 https://doi.org/10.1021/jp904229q	journal	July 2009
Photoluminescence studies of chain interactions in electroluminescent polymers Magnani, L.; Rumbles, G.; Samuel, I. D. W. Synthetic Metals, Vol. 84, Issue 1-3 https://doi.org/10.1016/S0379-6779(96)04202-6	journal	January 1997
Quenching of Excitons by Holes in Poly(3-hexylthiophene) Films Ferguson, Andrew J.; Kopidakis, Nikos; Shaheen, Sean E. The Journal of Physical Chemistry C, Vol. 112, Issue 26 https://doi.org/10.1021/jp7113412	journal	May 2008
Energetic Disorder in Higher Fullerene Adducts: A Quantum Chemical and Voltammetric Study Frost, Jarvist Moore; Faist, Mark Anton; Nelson, Jenny Advanced Materials, Vol. 22, Issue 43 https://doi.org/10.1002/adma.201002189	journal	September 2010
Functionalized Methanofullerenes Used as n-Type Materials in Bulk-Heterojunction Polymer Solar Cells and in Field-Effect Transistors Yang, Changduk; Kim, Jin Young; Cho, Shinuk Journal of the American Chemical Society, Vol. 130, Issue 20 https://doi.org/10.1021/ja710621j	journal	May 2008

Similar Records

Beyond PCBM: Understanding the Photovoltaic Performance of Blends of Indene-C60 Multiadducts with Poly(3-Hexylthiophene)

Journal Article · Wed Oct 10 00:00:00 EDT 2012 · Advanced Functional Materials · OSTI ID:1381399

Nardes, Alexandre M.; Ferguson, Andrew J.; Whitaker, James B.; +7 more

Variations in the optical properties of poly(3-hexylthiophene)/C{sub 60} blends and poly(3-hexylthiophene)/sol-gel composites

Conference · Sun Sep 01 00:00:00 EDT 1996 · OSTI ID:1381399

Wang, Hsing-Lin; Grigorva, M; Mattes, B R; +2 more

Effect of Miscibility and Percolation on Electron Transport in Amorphous Poly(3-Hexylthiophene)/Phenyl-C₆₁-Butyric Acid Methyl Ester Blends

Journal Article · Wed Jan 11 00:00:00 EST 2012 · Physical Review Letters · OSTI ID:1381399

Vakhshouri, Kiarash; Kozub, Derek R.; Wang, Chenchen; +2 more

Related Subjects

solar (photovoltaic)
energy storage (including batteries and capacitors)
charge transport
membrane
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)

Title: Beyond PCBM: Understanding the Photovoltaic Performance of Blends of Indene-C 60 Multiadducts with Poly(3-hexylthiophene)

Citation Formats

References (50)

Similar Records

Related Subjects

Title: Beyond PCBM: Understanding the Photovoltaic Performance of Blends of Indene-C ₆₀ Multiadducts with Poly(3-hexylthiophene)