Sr2Fe1.5Mo0.5O6-δ as a regenerative anode for solid oxide fuel cells
Sr2Fe1.5Mo0.5O6-δ (SFM) was prepared using a microwave-assisted combustion synthesis method. Rietveld refinement of powder X-ray diffraction data reveals that SFM crystallizes in the simple cubic perovskite structure with iron and molybdenum disordered on the B-site. No structure transition was observed by variable temperature powder X-ray diffraction measurements in the temperature range of 25–800 °C. XPS results show that the iron and molybdenum valences change with an increase in temperature, where the mixed oxidation states of both iron and molybdenum are believed to be responsible for the increase in the electrical conductivity with increasing temperature. SFM exhibits excellent redox stability and has been used as both anode and cathode for solid oxide fuel cells. Presence of sulfur species in the fuel or direct utilization of hydrocarbon fuel can result in loss of activity, however, as shown in this paper, the anode performance can be regenerated from sulfur poisoning or coking by treating the anode in an oxidizing atmosphere. Thus, SFM can be used as a regenerating anode for direct oxidation of sulfur-containing hydrocarbon fuels.
- Research Organization:
- Energy Frontier Research Centers (EFRC) (United States). Heterogeneous Functional Materials Center (HeteroFoaM)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- DOE Contract Number:
- SC0001061
- OSTI ID:
- 1381049
- Journal Information:
- Journal of Power Sources, Vol. 196, Issue 22; Related Information: HeteroFoaM partners with University of South Carolina (lead); University of California, Santa Barbara; University of Connecticut; Georgia Institute of Technology; Princeton University; Rochester Institute of Technology; Savannah River National Laboratory; University of South Carolina; University of Utah; ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
Similar Records
Evaluation of Cr-Tolerance of the Sr 2 Fe 1.5 Mo 0.5 O 6-δ Cathode for Solid Oxide Fuel Cells
Electrical characterization and water sensitivity of Sr2Fe1.5Mo0.5O6-δ as a possible solid oxide fuel cell electrode
Related Subjects
catalysis (heterogeneous)
energy storage (including batteries and capacitors)
hydrogen and fuel cells
mechanical behavior
charge transport
membrane
carbon sequestration
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)