A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries

Gao, Hongcai; Xue, Leigang; Xin, Sen; Park, Kyusung; Goodenough, John B.

doi:10.1002/ange.201702003

Title: A Plastic–Crystal Electrolyte Interphase for All‐Solid‐State Sodium Batteries

Journal Article · Wed Apr 12 00:00:00 EDT 2017 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201702003· OSTI ID:1379982

Gao, Hongcai ^[1]; Xue, Leigang ^[1]; Xin, Sen ^[1]; Park, Kyusung ^[1];

^[1]

Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA

Abstract The development of all‐solid‐state rechargeable batteries is plagued by a large interfacial resistance between a solid cathode and a solid electrolyte that increases with each charge–discharge cycle. The introduction of a plastic–crystal electrolyte interphase between a solid electrolyte and solid cathode particles reduces the interfacial resistance, increases the cycle life, and allows a high rate performance. Comparison of solid‐state sodium cells with 1) solid electrolyte Na ₃ Zr ₂ (Si ₂ PO ₄ ) particles versus 2) plastic–crystal electrolyte in the cathode composites shows that the former suffers from a huge irreversible capacity loss on cycling whereas the latter exhibits a dramatically improved electrochemical performance with retention of capacity for over 100 cycles and cycling at 5 C rate. The application of a plastic–crystal electrolyte interphase between a solid electrolyte and a solid cathode may be extended to other all‐solid‐state battery cells.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0005397

OSTI ID:: 1379982

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 129 Journal Issue: 20; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (54)

Fast Na+-ion transport in skeleton structures Goodenough, J. B.; Hong, H. Y-P.; Kafalas, J. A. Materials Research Bulletin, Vol. 11, Issue 2 https://doi.org/10.1016/0025-5408(76)90077-5	journal	February 1976
Interface-Engineered All-Solid-State Li-Ion Batteries Based on Garnet-Type Fast Li ⁺ Conductors van den Broek, Jan; Afyon, Semih; Rupp, Jennifer L. M. Advanced Energy Materials, Vol. 6, Issue 19 https://doi.org/10.1002/aenm.201600736	journal	July 2016
The plastic-crystalline phase of succinonitrile as a universal matrix for solid-state ionic conductors Alarco, Pierre-Jean; Abu-Lebdeh, Yaser; Abouimrane, Ali Nature Materials, Vol. 3, Issue 7 https://doi.org/10.1038/nmat1158	journal	June 2004
Conductive Organic Plastic Crystals Based on Pyrazolium Imides Abu-Lebdeh, Yaser; Alarco, Pierre-Jean; Armand, Michel Angewandte Chemie International Edition, Vol. 42, Issue 37 https://doi.org/10.1002/anie.200250706	journal	September 2003
Investigation on diffusion behavior of Li+ in LiFePO4 by capacity intermittent titration technique (CITT) Tang, Xin-Cun; Li, Lian-Xing; Lai, Qiong-Lin Electrochimica Acta, Vol. 54, Issue 8 https://doi.org/10.1016/j.electacta.2008.10.065	journal	March 2009
Enhanced electrochemical properties of PEO-based composite polymer electrolyte with shape-selective molecular sieves Xi, Jingyu; Qiu, Xinping; Cui, Mengzhong Journal of Power Sources, Vol. 156, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.06.007	journal	June 2006
Spark Plasma Sintering (SPS) of NASICON Ceramics Lee, Ji-Sun; Chang, Chae-Myung; Lee, Young IL Journal of the American Ceramic Society, Vol. 87, Issue 2 https://doi.org/10.1111/j.1551-2916.2004.00305.x	journal	February 2004
Static and dynamic wetting behaviour of ionic liquids Delcheva, Iliana; Ralston, John; Beattie, David A. Advances in Colloid and Interface Science, Vol. 222 https://doi.org/10.1016/j.cis.2014.07.003	journal	August 2015
Application of quasi-solid-state silica nanoparticles–ionic liquid composite electrolytes to all-solid-state lithium secondary battery Ito, Seitaro; Unemoto, Atsushi; Ogawa, Hideyuki Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.049	journal	June 2012
Development of Sulfide Solid Electrolytes and Interface Formation Processes for Bulk-Type All-Solid-State Li and Na Batteries Hayashi, Akitoshi; Sakuda, Atsushi; Tatsumisago, Masahiro Frontiers in Energy Research, Vol. 4 https://doi.org/10.3389/fenrg.2016.00025	journal	July 2016
Sodium and sodium-ion energy storage batteries Ellis, Brian L.; Nazar, Linda F. Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4, p. 168-177 https://doi.org/10.1016/j.cossms.2012.04.002	journal	August 2012
Dielectric Modification of 5V-Class Cathodes for High-Voltage All-Solid-State Lithium Batteries Yada, Chihiro; Ohmori, Akihiro; Ide, Kazuto Advanced Energy Materials, Vol. 4, Issue 9 https://doi.org/10.1002/aenm.201301416	journal	March 2014
Ionic conductivity in crystalline polymer electrolytes Gadjourova, Zlatka; Andreev, Yuri G.; Tunstall, David P. Nature, Vol. 412, Issue 6846 https://doi.org/10.1038/35087538	journal	August 2001
Evaluation of the wetting time of porous electrodes in electrolytic solutions containing ionic liquid Kühnel, Ruben-Simon; Obeidi, Shahmahmood; Lübke, Mechthild Journal of Applied Electrochemistry, Vol. 43, Issue 7 https://doi.org/10.1007/s10800-013-0558-x	journal	May 2013
Electrochemical energy storage in a sustainable modern society Goodenough, John B. Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42613K	journal	January 2014
Relaxation dynamics and ionic conductivity in a fragile plastic crystal Bauer, Th.; Köhler, M.; Lunkenheimer, P. The Journal of Chemical Physics, Vol. 133, Issue 14 https://doi.org/10.1063/1.3487521	journal	October 2010
Phase Transitions in Plastic Crystals Staveley, L. A. K. Annual Review of Physical Chemistry, Vol. 13, Issue 1 https://doi.org/10.1146/annurev.pc.13.100162.002031	journal	October 1962
Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries Hayashi, Akitoshi; Noi, Kousuke; Sakuda, Atsushi Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1843	journal	January 2012
Review—Solid Electrolytes in Rechargeable Electrochemical Cells Goodenough, John B.; Singh, Preetam Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0021514jes	journal	January 2015
Inorganic solid/organic liquid hybrid electrolyte for use in Li-ion battery Asl, Nina Mahootcheian; Keith, Joshua; Lim, Cheolwoong Electrochimica Acta, Vol. 79 https://doi.org/10.1016/j.electacta.2012.06.038	journal	September 2012
Electrochemical Nature of the Cathode Interface for a Solid-State Lithium-Ion Battery: Interface between LiCoO ₂ and Garnet-Li ₇ La ₃ Zr ₂ O ₁₂ Park, Kyusung; Yu, Byeong-Chul; Jung, Ji-Won Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b03870	journal	October 2016
An All-solid-state and All-organic Sodium-ion Battery based on Redox-active Polymers and Plastic Crystal Electrolyte Zhu, Xiaoming; Zhao, Ruirui; Deng, Wenwen Electrochimica Acta, Vol. 178 https://doi.org/10.1016/j.electacta.2015.07.163	journal	October 2015
Characterization of NaX (X: TFSI, FSI) – PEO based solid polymer electrolytes for sodium batteries Boschin, Andrea; Johansson, Patrik Electrochimica Acta, Vol. 175 https://doi.org/10.1016/j.electacta.2015.03.228	journal	September 2015
Reduction of charge-transfer resistance at the solid electrolyte – electrode interface by pulsed laser deposition of films from a crystalline Li2PO2N source West, William C.; Hood, Zachary D.; Adhikari, Shiba P. Journal of Power Sources, Vol. 312 https://doi.org/10.1016/j.jpowsour.2016.02.034	journal	April 2016
Novel technique to form electrode–electrolyte nanointerface in all-solid-state rechargeable lithium batteries Hayashi, Akitoshi; Nishio, Yusuke; Kitaura, Hirokazu Electrochemistry Communications, Vol. 10, Issue 12 https://doi.org/10.1016/j.elecom.2008.09.026	journal	December 2008
A ceramic/polymer composite solid electrolyte for sodium batteries Zhang, Zhizhen; Zhang, Qiangqiang; Ren, Cheng Journal of Materials Chemistry A, Vol. 4, Issue 41 https://doi.org/10.1039/C6TA07590H	journal	January 2016
Survey of the transport properties of sodium superionic conductor materials for use in sodium batteries Guin, M.; Tietz, F. Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.09.137	journal	January 2015
In Situ Synthesis of a Hierarchical All-Solid-State Electrolyte Based on Nitrile Materials for High-Performance Lithium-Ion Batteries Zhou, Dong; He, Yan-Bing; Liu, Ruliang Advanced Energy Materials, Vol. 5, Issue 15 https://doi.org/10.1002/aenm.201500353	journal	May 2015
Interfacial Observation between LiCoO ₂ Electrode and Li ₂ S−P ₂ S ₅ Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron Microscopy ^† Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm901819c	journal	February 2010
The use of protic ionic liquids with cathodes for sodium-ion batteries Vogl, T.; Vaalma, C.; Buchholz, D. Journal of Materials Chemistry A, Vol. 4, Issue 27 https://doi.org/10.1039/C6TA02277D	journal	January 2016
Charge transfer kinetics at the solid–solid interface in porous electrodes Bai, Peng; Bazant, Martin Z. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4585	journal	April 2014
A Battery Made from a Single Material Han, Fudong; Gao, Tao; Zhu, Yujie Advanced Materials, Vol. 27, Issue 23 https://doi.org/10.1002/adma.201500180	journal	April 2015
A hybrid solid electrolyte for flexible solid-state sodium batteries Kim, Jae-Kwang; Lim, Young Jun; Kim, Hyojin Energy & Environmental Science, Vol. 8, Issue 12 https://doi.org/10.1039/C5EE01941A	journal	January 2015
Point contacts in solid state ionics: finite element calculations and local conductivity measurements Fleig, J. Solid State Ionics, Vol. 86-88 https://doi.org/10.1016/0167-2738(96)00316-5	journal	July 1996
A Sodium-Ion Battery with a Low-Cost Cross-Linked Gel-Polymer Electrolyte Gao, Hongcai; Zhou, Weidong; Park, Kyusung Advanced Energy Materials, Vol. 6, Issue 18 https://doi.org/10.1002/aenm.201600467	journal	June 2016
Routes to High Energy Cathodes of Sodium-Ion Batteries Fang, Chun; Huang, Yunhui; Zhang, Wuxing Advanced Energy Materials, Vol. 6, Issue 5 https://doi.org/10.1002/aenm.201501727	journal	December 2015
Impedance Characterization of Li Ion Transport at the Interface between Laminated Ceramic and Polymeric Electrolytes Tenhaeff, W. E.; Perry, K. A.; Dudney, N. J. Journal of The Electrochemical Society, Vol. 159, Issue 12 https://doi.org/10.1149/2.063212jes	journal	January 2012
Design principles for electrolytes and interfaces for stable lithium-metal batteries Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.114	journal	September 2016
Towards greener and more sustainable batteries for electrical energy storage Larcher, D.; Tarascon, J-M. Nature Chemistry, Vol. 7, Issue 1 https://doi.org/10.1038/nchem.2085	journal	November 2014
Lithium-Ion Electrolytes Containing Ester Cosolvents for Improved Low Temperature Performance Smart, M. C.; Ratnakumar, B. V.; Chin, K. B. Journal of The Electrochemical Society, Vol. 157, Issue 12 https://doi.org/10.1149/1.3501236	journal	January 2010
Electrochemical Polarization Stern, M.; Geaby, A. L. Journal of The Electrochemical Society, Vol. 104, Issue 1 https://doi.org/10.1149/1.2428496	journal	January 1957
Solid state thin-film lithium battery systems Dudney, N. J.; Neudecker, B. J. Current Opinion in Solid State and Materials Science, Vol. 4, Issue 5 https://doi.org/10.1016/S1359-0286(99)00052-2	journal	October 1999
Lithium-doped plastic crystal electrolytes exhibiting fast ion conduction for secondary batteries MacFarlane, Douglas R.; Huang, Junhua; Forsyth, Maria Nature, Vol. 402, Issue 6763 https://doi.org/10.1038/45514	journal	December 1999
Conductive Organic Plastic Crystals Based on Pyrazolium Imides Abu-Lebdeh, Yaser; Alarco, Pierre-Jean; Armand, Michel Angewandte Chemie, Vol. 115, Issue 37 https://doi.org/10.1002/ange.200250706	journal	September 2003
Electrochemical performance of an all-solid-state lithium ion battery with garnet-type oxide electrolyte Ohta, Shingo; Kobayashi, Tetsuro; Seki, Juntaro Journal of Power Sources, Vol. 202 https://doi.org/10.1016/j.jpowsour.2011.10.064	journal	March 2012
Modification of Interface Between LiCoO[sub 2] Electrode and Li[sub 2]S–P[sub 2]S[sub 5] Solid Electrolyte Using Li[sub 2]O–SiO[sub 2] Glassy Layers Sakuda, Atsushi; Kitaura, Hirokazu; Hayashi, Akitoshi Journal of The Electrochemical Society, Vol. 156, Issue 1 https://doi.org/10.1149/1.3005972	journal	January 2009
Importance of Coulombic Efficiency Measurements in R&D Efforts to Obtain Long-Lived Li-Ion Batteries Dahn, J. R.; Burns, J. C.; Stevens, D. A. Interface magazine, Vol. 25, Issue 3 https://doi.org/10.1149/2.F07163if	journal	January 2016
Characterization of the interface between LiCoO2 and Li7La3Zr2O12 in an all-solid-state rechargeable lithium battery Kim, Ki Hyun; Iriyama, Yasutoshi; Yamamoto, Kazuo Journal of Power Sources, Vol. 196, Issue 2 https://doi.org/10.1016/j.jpowsour.2010.07.073	journal	January 2011
Preparation and performance of a non-ionic plastic crystal electrolyte with the addition of polymer for lithium ion batteries Wang, Qiujun; Fan, Huanhuan; Fan, Li-Zhen Electrochimica Acta, Vol. 114 https://doi.org/10.1016/j.electacta.2013.10.111	journal	December 2013
In Situ STEM-EELS Observation of Nanoscale Interfacial Phenomena in All-Solid-State Batteries Wang, Ziying; Santhanagopalan, Dhamodaran; Zhang, Wei Nano Letters, Vol. 16, Issue 6 https://doi.org/10.1021/acs.nanolett.6b01119	journal	May 2016
Hierarchical Carbon Framework Wrapped Na ₃ V ₂ (PO ₄ ) ₃ as a Superior High-Rate and Extended Lifespan Cathode for Sodium-Ion Batteries Fang, Yongjin; Xiao, Lifen; Ai, Xinping Advanced Materials, Vol. 27, Issue 39 https://doi.org/10.1002/adma.201502018	journal	August 2015
Interfacial behaviours between lithium ion conductors and electrode materials in various battery systems Wu, Bingbin; Wang, Shanyu; Evans IV, Willie J. Journal of Materials Chemistry A, Vol. 4, Issue 40 https://doi.org/10.1039/C6TA05439K	journal	January 2016
Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction Bachman, John Christopher; Muy, Sokseiha; Grimaud, Alexis Chemical Reviews, Vol. 116, Issue 1 https://doi.org/10.1021/acs.chemrev.5b00563	journal	December 2015
Preparation and Electrical Properties of Dense Ceramics with NASICON Composition Sintered at Reduced Temperatures Sch�f, O.; Weibel, A.; Llewellyn, P. L. Journal of Electroceramics, Vol. 13, Issue 1-3 https://doi.org/10.1007/s10832-004-5198-4	journal	July 2004

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