Hidden Order and Dimensional Crossover of the Charge Density Waves in TiSe2

Chen, P.; Chan, Y. -H.; Fang, X. -Y.; Mo, S. -K.; Hussain, Z.; Fedorov, A. -V.; Chou, M. Y.; Chiang, T. -C.

doi:10.1038/srep37910

Title: Hidden Order and Dimensional Crossover of the Charge Density Waves in TiSe₂

Journal Article · Tue Nov 29 00:00:00 EST 2016 · Scientific Reports

DOI:https://doi.org/10.1038/srep37910· OSTI ID:1379594

Chen, P. ^[1]; Chan, Y. -H. ^[2]; Fang, X. -Y. ^[3]; Mo, S. -K. ^[4]; Hussain, Z. ^[4]; Fedorov, A. -V. ^[4]; Chou, M. Y. ^[5]; Chiang, T. -C. ^[6]

Univ. of Illinois, Urbana-Champaign, IL (United States). Dept. of Physics, Frederick Seitz Materials Research Lab.; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Inst. of Atomic and Molecular Sciences, Taipei (Taiwan)
Univ. of Illinois, Urbana-Champaign, IL (United States). Dept. of Physics, Frederick Seitz Materials Research Lab.
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Inst. of Atomic and Molecular Sciences, Taipei (Taiwan); National Taiwan Univ., Taipei (Taiwan). Dept. of Physics
Univ. of Illinois, Urbana-Champaign, IL (United States). Dept. of Physics, Frederick Seitz Materials Research Lab.; National Taiwan Univ., Taipei (Taiwan). Dept. of Physics

Charge density wave (CDW) formation, a key physics issue for materials, arises from interactions among electrons and phonons that can also lead to superconductivity and other competing or entangled phases. The prototypical system TiSe ₂, with a particularly simple (2 × 2 × 2) transition and no Kohn anomalies caused by electron-phonon coupling, is a fascinating but unsolved case after decades of research. Our angle-resolved photoemission measurements of the band structure as a function of temperature, aided by first-principles calculations, reveal a hitherto undetected but crucial feature: a (2 × 2) electronic order in each layer sets in at ~232 K before the widely recognized three-dimensional structural order at ~205 K. The dimensional crossover, likely a generic feature of such layered materials, involves renormalization of different band gaps in two stages.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; FG02-07ER46383

OSTI ID:: 1379594

Journal Information:: Scientific Reports, Vol. 6, Issue 1; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 26 works

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Cited By (8)

Non-linear enhancement of thermoelectric performance of a TiSe ₂ monolayer due to tensile strain, from first-principles calculations Nayeb Sadeghi, Safoura; Zebarjadi, Mona; Esfarjani, Keivan Journal of Materials Chemistry C, Vol. 7, Issue 24 https://doi.org/10.1039/c9tc00183b	journal	January 2019
Critical Role of the Exchange Interaction for the Electronic Structure and Charge-Density-Wave Formation in ${TiSe}_{2}$ Hellgren, Maria; Baima, Jacopo; Bianco, Raffaello Physical Review Letters, Vol. 119, Issue 17 https://doi.org/10.1103/physrevlett.119.176401	journal	October 2017
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Excitonic and lattice contributions to the charge density wave in $1 T - TiS e_{2}$ revealed by a phonon bottleneck Hedayat, H.; Sayers, C. J.; Bugini, D. Physical Review Research, Vol. 1, Issue 2 https://doi.org/10.1103/physrevresearch.1.023029	journal	September 2019
Angle-resolved photoemission spectroscopy for the study of two-dimensional materials Mo, Sung-Kwan Nano Convergence, Vol. 4, Issue 1 https://doi.org/10.1186/s40580-017-0100-7	journal	March 2017

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Title: Hidden Order and Dimensional Crossover of the Charge Density Waves in TiSe₂