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Tunable room-temperature single-photon emission at telecom wavelengths from sp3 defects in carbon nanotubes

Journal Article · · Nature Photonics

Generating quantum light emitters that operate at room temperature and at telecom wavelengths remains a significant materials challenge. To achieve this goal requires light sources that emit in the near-infrared wavelength region and that, ideally, are tunable to allow desired output wavelengths to be accessed in a controllable manner. Here, we show that exciton localization at covalently introduced aryl sp3 defect sites in single-walled carbon nanotubes provides a route to room-temperature single-photon emission with ultrahigh single-photon purity (99%) and enhanced emission stability approaching the shot-noise limit. Moreover, we demonstrate that the inherent optical tunability of single-walled carbon nanotubes, present in their structural diversity, allows us to generate room-temperature single-photon emission spanning the entire telecom band. Furthermore, single-photon emission deep into the centre of the telecom C band (1.55 um) is achieved at the largest nanotube diameters we explore (0.936 nm).

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1379462
Alternate ID(s):
OSTI ID: 1406208
OSTI ID: 1392859
Report Number(s):
NREL/JA--5900-68252
Journal Information:
Nature Photonics, Journal Name: Nature Photonics Journal Issue: 9 Vol. 11; ISSN 1749-4885
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

References (52)

Solid-State Approach for Fabrication of Photostable, Oxygen-Doped Carbon Nanotubes journal September 2015
Isolation of Specific Small-Diameter Single-Wall Carbon Nanotube Species via Aqueous Two-Phase Extraction journal January 2014
Diamond Nanophotonics journal July 2014
Optical Excitation of Carbon Nanotubes Drives Localized Diazonium Reactions journal September 2016
Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes journal April 2016
Broadband Tunable, Polarization-Selective and Directional Emission of (6,5) Carbon Nanotubes Coupled to Plasmonic Crystals journal April 2016
Photoluminescence Dynamics of Aryl sp 3 Defect States in Single-Walled Carbon Nanotubes journal August 2016
Robust Multicolor Single Photon Emission from Point Defects in Hexagonal Boron Nitride journal July 2016
Photoluminescence Imaging of Polyfluorene Surface Structures on Semiconducting Carbon Nanotubes: Implications for Thin Film Exciton Transport journal November 2016
Molecularly Tunable Fluorescent Quantum Defects journal May 2016
Quantum Light Signatures and Nanosecond Spectral Diffusion from Cavity-Embedded Carbon Nanotubes journal January 2012
Disorder Limited Exciton Transport in Colloidal Single-Wall Carbon Nanotubes journal September 2012
Luminescence Properties of Individual Empty and Water-Filled Single-Walled Carbon Nanotubes journal February 2012
Role of Surfactants and Salt in Aqueous Two-Phase Separation of Carbon Nanotubes toward Simple Chirality Isolation journal January 2014
Electronic Structure and Chemical Nature of Oxygen Dopant States in Carbon Nanotubes journal October 2014
Polyfluorene-Sorted, Carbon Nanotube Array Field-Effect Transistors with Increased Current Density and High On/Off Ratio journal November 2014
Brightening of carbon nanotube photoluminescence through the incorporation of sp3 defects journal July 2013
Industrial-scale separation of high-purity single-chirality single-wall carbon nanotubes for biological imaging journal June 2016
Prolonged spontaneous emission and dephasing of localized excitons in air-bridged carbon nanotubes journal July 2013
Ultralow mode-volume photonic crystal nanobeam cavities for high-efficiency coupling to individual carbon nanotube emitters journal November 2014
Bright, long-lived and coherent excitons in carbon nanotube quantum dots journal June 2013
Room-temperature single-photon generation from solitary dopants of carbon nanotubes journal July 2015
Quantum emission from hexagonal boron nitride monolayers journal October 2015
Optically active quantum dots in monolayer WSe2 journal May 2015
Single photon emitters in exfoliated WSe2 structures journal May 2015
Single quantum emitters in monolayer semiconductors journal May 2015
Voltage-controlled quantum light from an atomically thin semiconductor journal May 2015
Carbon-nanotube photonics and optoelectronics journal June 2008
Fully integrated quantum photonic circuit with an electrically driven light source journal September 2016
Solid-state single-photon emitters journal September 2016
A single molecule as a high-fidelity photon gun for producing intensity-squeezed light journal December 2016
Emergence of new red-shifted carbon nanotube photoluminescence based on proximal doped-site design journal June 2016
Photoluminescence imaging of solitary dopant sites in covalently doped single-wall carbon nanotubes journal January 2015
Tuning of the photoluminescence and up-conversion photoluminescence properties of single-walled carbon nanotubes by chemical functionalization journal January 2016
Single-photon emission in telecommunication band from an InAs quantum dot grown on InP with molecular-beam epitaxy journal August 2013
Single-photon emission at 1.5 μm from an InAs/InP quantum dot with highly suppressed multi-photon emission probabilities journal September 2016
Single-photon sources journal May 2005
Single-photon sources journal April 2005
Diamond-based single-photon emitters journal June 2011
Photon Antibunching in the Photoluminescence Spectra of a Single Carbon Nanotube journal May 2008
Widely Tunable Single-Photon Source from a Carbon Nanotube in the Purcell Regime journal June 2016
A single molecule as a high-fidelity photon gun for producing intensity-squeezed light
  • Chu, Xiao-Liu; Gotzinger, Stephan; Sandoghdar, Vahid
  • 2017 Conference on Lasers and Electro-Optics Europe (CLEO/Europe) & European Quantum Electronics Conference (EQEC), 2017 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC) https://doi.org/10.1109/cleoe-eqec.2017.8087610
conference June 2017
Structure-Assigned Optical Spectra of Single-Walled Carbon Nanotubes journal November 2002
Oxygen Doping Modifies Near-Infrared Band Gaps in Fluorescent Single-Walled Carbon Nanotubes journal November 2010
Experimental realization of an absolute single-photon source based on a single nitrogen vacancy center in a nanodiamond journal January 2017
Quantum Emission from Hexagonal Boron Nitride Monolayers conference January 2016
Nitrogen-vacancy centers: Physics and applications journal February 2013
Quantum computing with defects journal October 2013
Experimental realization of an absolute single-photon source based on a single nitrogen vacancy center in a nanodiamond collection January 2017
Prolonged spontaneous emission and dephasing of localized excitons in air-bridged carbon nanotubes text January 2013
Ultralow mode-volume photonic crystal nanobeam cavities for high efficiency coupling to individual carbon nanotube emitters text January 2014
Single Quantum Emitters in Monolayer Semiconductors preprint January 2014

Cited By (47)

Photon Correlation Spectroscopy of Luminescent Quantum Defects in Carbon Nanotubes journal September 2019
Probing Trions at Chemically Tailored Trapping Defects journal October 2019
Purcell-enhanced quantum yield from carbon nanotube excitons coupled to plasmonic nanocavities journal November 2017
Single-defect spectroscopy in the shortwave infrared journal June 2019
Creating fluorescent quantum defects in carbon nanotubes using hypochlorite and light journal June 2019
Many-particle excitations in non-covalently doped single-walled carbon nanotubes journal October 2019
Superior properties in room-temperature colloidal-dot quantum emitters revealed by ultralow-dark-count detections of temporally-purified single photons journal November 2019
Manufacture of Networks from Large Diameter Single-Walled Carbon Nanotubes of Particular Electrical Character journal April 2019
Brightening of Long, Polymer-Wrapped Carbon Nanotubes by sp$^{3}$ Functionalization in Organic Solvents text January 2019
Recent Advances in Applications of Sorted Single‐Walled Carbon Nanotubes journal May 2019
Infrared Organic Light-Emitting Diodes with Carbon Nanotube Emitters journal January 2018
Solution-Processing of High-Purity Semiconducting Single-Walled Carbon Nanotubes for Electronics Devices journal July 2018
New Light on Molecule–Nanotube Hybrids journal September 2019
Intrinsic and Extrinsically Limited Thermoelectric Transport within Semiconducting Single‐Walled Carbon Nanotube Networks journal February 2019
Photochemical Creation of Fluorescent Quantum Defects in Semiconducting Carbon Nanotube Hosts journal December 2017
Photochemical Creation of Fluorescent Quantum Defects in Semiconducting Carbon Nanotube Hosts journal January 2018
Nonradiative Excited‐State Decay via Conical Intersection in Graphene Nanostructures journal September 2019
Brightening and Guiding Single‐Photon Emission by Plasmonic Waveguide–Slit Structures on a Metallic Substrate journal September 2019
Separation of Large‐Diameter Metallic and Semiconducting Single‐Walled Carbon Nanotubes by Iterative Temperature‐Assisted Gel‐Column Chromatography for Enhanced Device Applications journal January 2020
Building Blocks for Quantum Network Based on Group‐IV Split‐Vacancy Centers in Diamond journal October 2019
High‐Purity Triggered Single‐Photon Emission from Symmetric Single InAs/InP Quantum Dots around the Telecom C‐Band Window journal October 2019
Nanotube chemistry tunes light journal September 2017
Photonic crystal cavities from hexagonal boron nitride journal July 2018
Bright room temperature single photon source at telecom range in cubic silicon carbide journal October 2018
Narrow-band single-photon emission through selective aryl functionalization of zigzag carbon nanotubes journal September 2018
Carbon nanotubes as emerging quantum-light sources journal June 2018
Controlling the optical properties of carbon nanotubes with organic colour-centre quantum defects journal June 2019
Single-step isolation of carbon nanotubes with narrow-band light emission characteristics journal January 2019
Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas journal January 2018
Control of near infrared photoluminescence properties of single-walled carbon nanotubes by functionalization with dendrons journal January 2018
Intrinsic limits of defect-state photoluminescence dynamics in functionalized carbon nanotubes journal January 2019
Chirality enriched carbon nanotubes with tunable wrapping via corona phase exchange purification (CPEP) journal January 2019
Controlling photon antibunching from 1D emitters using optical antennas journal January 2019
Locally defined quantum emission from epitaxial few-layer tungsten diselenide journal May 2019
Photonic quantum information processing: A concise review journal December 2019
Exciton relaxation in carbon nanotubes via electronic-to-vibrational energy transfer journal October 2019
Probing the mechanics of aqueous two-phase extraction using large diameter single-walled carbon nanotubes journal July 2018
Quantum light sources from semiconductor journal July 2019
Probing the origin of photoluminescence brightening in graphene nanoribbons journal April 2019
Single photon emission in WSe 2 up 160 K by quantum yield control journal May 2019
Superinjection in Diamond p - i - n Diodes: Bright Single-Photon Electroluminescence of Color Centers Beyond the Doping Limit journal August 2019
Room-Temperature Single-Photon Emission from Micrometer-Long Air-Suspended Carbon Nanotubes journal November 2017
High Efficiency Dark-to-Bright Exciton Conversion in Carbon Nanotubes journal December 2019
Room temperature solid-state quantum emitters in the telecom range journal March 2018
Room-temperature single photon emission from micron-long air-suspended carbon nanotubes text January 2017
Superinjection in diamond p-i-n diodes: bright single-photon electroluminescence of color centers beyond the doping limit text January 2018
High efficiency dark-to-bright exciton conversion in carbon nanotubes text January 2019

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