Ion-Specific Interfacial Crystallization of Polymer-Grafted Nanoparticles

Zhang, Honghu; Wang, Wenjie; Mallapragada, Surya; Travesset, Alex; Vaknin, David

doi:10.1021/acs.jpcc.7b02549

Ion-Specific Interfacial Crystallization of Polymer-Grafted Nanoparticles

Journal Article · Tue Jun 27 00:00:00 EDT 2017 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.7b02549· OSTI ID:1379197

Zhang, Honghu ^[1]; Wang, Wenjie ^[1]; Mallapragada, Surya ^[1]; ^[1]; ^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States)

In this study, ion-specific effects on the assembly and crystallization of polyethylene-glycol-grafted Au nanoparticles (PEG-AuNPs) at the vapor–liquid interface are examined by surface sensitive synchrotron X-ray scattering methods. We show that monovalent salts, such as KCl and NaCl, that do not advance phase separation of pure PEG at room temperature induce two-dimensional (2D) self-assembly and crystallization of PEG-AuNPs with some distinctions. Whereas for KCl the 2D hexagonal coherence length of the PEG-AuNP superlattices is remarkably large compared to other salts (over micron-sized crystalline grains), NaCl induces coexistence of two hexagonal structures. Using various salts, we find that the value of the lattice constant is correlated to the ionic hydration entropy consistent with the Hofmeister series.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1379197

Alternate ID(s):: OSTI ID: 1376242

Report Number(s):: IS-J--9419

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 28 Vol. 121; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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