57Fe Mössbauer study of stoichiometric iron-based superconductor CaKFe4As4: a comparison to KFe2As2 and CaFe2As2

Bud’ko, Sergey L.; Kong, Tai; Meier, William R.; Ma, Xiaoming; Canfield, Paul C.

doi:10.1080/14786435.2017.1347726

⁵⁷Fe Mössbauer study of stoichiometric iron-based superconductor CaKFe₄As₄: a comparison to KFe₂As₂ and CaFe₂As₂

Journal Article · Thu Jul 06 00:00:00 EDT 2017 · Philosophical Magazine (2003, Print)

DOI:https://doi.org/10.1080/14786435.2017.1347726· OSTI ID:1379173

Bud’ko, Sergey L. ^[1]; ^[2]; Meier, William R. ^[1]; Ma, Xiaoming ^[3]; Canfield, Paul C. ^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States)
Ames Lab. and Iowa State Univ., Ames, IA (United States); Princeton Univ., Princeton, NJ (United States)
Chinese Academy of Sciences, Beijing (China); South Univ. of Science and Technology of China, Shenzhen (China)

⁵⁷Fe Mössbauer spectra at different temperatures between ~5 and ~300 K were measured on an oriented mosaic of single crystals of CaKFe₄ As₄. The data indicate that is a well formed compound with narrow spectral lines, no traces of other, Fe – containing, secondary phases in the spectra and no static magnetic order. There is no discernible feature at the superconducting transition temperature in any of the hyperfine parameters. The temperature dependence of the quadrupole splitting approximately follows the empirical ‘T^3/2 law’. Furthermore, the hyperfine parameters of CaKFe₄ As₄ are compared with those for measured in this work, and the literature data for CaFe₂ As₂, and were found to be in between those for these two, ordered, 122 compounds, in agreement with the gross view of CaKFe₄ As₄ as a structural analog of KFe₂ As₂ and CaFe₂ As₂ that has alternating Ca- and K-layers in the structure.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1379173

Report Number(s):: IS-J--9429

Journal Information:: Philosophical Magazine (2003, Print), Journal Name: Philosophical Magazine (2003, Print) Journal Issue: 29 Vol. 97; ISSN 1478-6435

Publisher:: Taylor & FrancisCopyright Statement

Country of Publication:: United States

Language:: English

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