Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Correlation between Chiral Modifier Adsorption and Enantioselectivity in Hydrogenation Catalysis

Journal Article · · Angewandte Chemie
Not Available
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
SC0008703
OSTI ID:
1378795
Journal Information:
Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 27 Vol. 129; ISSN 0044-8249
Publisher:
German Chemical SocietyCopyright Statement
Country of Publication:
Germany
Language:
English

References (29)

Adsorption of 1-(1-Naphthyl)ethylamine from Solution onto Platinum Surfaces: Implications for the Chiral Modification of Heterogeneous Catalysts journal February 2013
Adsorption of 1-(1-Naphthyl)ethylamine from Solution onto Platinum Surfaces: Implications for the Chiral Modification of Heterogeneous Catalysts journal February 2013
Enantioselective Hydrogenation of Ethyl Pyruvate over Pt/Alumina Modified by (R)-1-(1-Naphthyl)ethylamine Derivatives journal May 1996
Role of the modifier in the enantioselective hydrogenation of ethyl pyruvate over Pt/Al2O3 catalyst journal January 1990
Enantioselective hydrogenation of ?-ketoesters over Pt/alumina modified with cinchonidine: theoretical investigation of the substrate-modifier interaction journal January 1994
Enantioselective hydrogenation of ethyl pyruvate catalysed by cinchonine-modified Pt/Al2O3: tilted adsorption geometry of cinchonine journal April 2005
Unexpected Inversion in Enantioselectivity in the Hydrogenation N-acetyl Dehydrophenylalanine Methyl Ester using Cinchona-Modified Pd/Al2O3 catalyst journal September 2005
Origin of enhanced rate in the platinum-catalysed enantioselective hydrogenation of methyl pyruvate journal September 1991
A decade+ of operando spectroscopy studies journal April 2017
Molecular catalysis science: Nanoparticle synthesis and instrument development for studies under reaction conditions journal August 2015
Adsorption and thermal decomposition of N-methylaniline on Pt(111) journal November 2009
Dependence of the adsorption of chiral compounds on their enantiomeric composition journal November 2014
Water at Interfaces journal April 2016
Cinchona-Modified Platinum Catalysts: From Ligand Acceleration to Technical Processes journal December 2007
Probing Liquid/Solid Interfaces at the Molecular Level journal January 2012
Atomic-Scale Observations of Catalyst Structures under Reaction Conditions and during Catalysis journal March 2016
Origins of Enantioselectivity in Reductions of Ketones on Cinchona Alkaloid Modified Platinum journal January 2004
Factors Controlling Adsorption Equilibria from Solution onto Solid Surfaces:  The Uptake of Cinchona Alkaloids on Platinum Surfaces journal December 2007
1-(1-Naphthyl)Ethylamine Adsorption on Platinum Surfaces: On the Mechanism of Chiral Modification in Catalysis journal November 2008
Highly Enantioselective Heterogeneously Catalyzed Hydrogenation of α-Ketoesters under Mild Conditions journal May 1999
Role of the Solvent in the Adsorption−Desorption Equilibrium of Cinchona Alkaloids between Solution and a Platinum Surface:  Correlations among Solvent Polarity, Cinchona Solubility, and Catalytic Performance journal January 2005
The Role of Modifier Structure in Heterogeneous Enantioselective Hydrogenation:  One-to-One Interactions of 1-Phenyl-1,2-propanedione and Methyl Pyruvate with Modifiers on the Pt(111) Surface journal March 2007
In Situ Characterization of Adsorbates in Solid−Liquid Interfaces by Reflection−Absorption Infrared Spectroscopy journal April 2003
Enantioselective hydrogenation of ethyl pyruvate over Pt/alumina: systematic variation of the modifier structure journal December 1997
1-(1-Naphthyl)ethylamine and derivatives thereof as chiral modifiers in the enantioselective hydrogenation of ethyl pyruvate over Pt–alumina journal January 1995
New advances in the use of infrared absorption spectroscopy for the characterization of heterogeneous catalytic reactions journal January 2014
Adsorption and stability of chiral modifiers based on 1-(1-naphthyl)-ethylamine for Pt catalysed heterogeneous asymmetric hydrogenations journal January 2015
Determination of geometric orientation of adsorbed cinchonidine on Pt and Fe and quiphos on Pt nanoclusters via DRIFTS journal January 2006
Direct Observation of Molecular Preorganization for Chirality Transfer on a Catalyst Surface journal November 2011

Similar Records

Correlation between Chiral Modifier Adsorption and Enantioselectivity in Hydrogenation Catalysis
Journal Article · Sun May 14 20:00:00 EDT 2017 · Angewandte Chemie (International Edition) · OSTI ID:1533111

Chiral metal surfaces for enantioselective processes
Journal Article · Mon Aug 03 00:00:00 EDT 2020 · Nature Materials · OSTI ID:1801871

Related Subjects