Characterizing the electronic states of the second-row transition metal cations using high-resolution ion mobility mass spectrometry

Manard, Manuel J.; Kemper, Paul R.

doi:10.1016/j.ijms.2016.07.006

Title: Characterizing the electronic states of the second-row transition metal cations using high-resolution ion mobility mass spectrometry

Journal Article · Mon Aug 01 00:00:00 EDT 2016 · International Journal of Mass Spectrometry

DOI:https://doi.org/10.1016/j.ijms.2016.07.006· OSTI ID:1378286

Manard, Manuel J.; Kemper, Paul R.

Reduced mobilities for ground-state and electronic excited-state configurations of the second-row transition metal cations, excluding Tc+, have been measured. These values were obtained using an ion mobility mass spectrometer that uses a 2 m drift tube to generate high-resolution ion mobility data. Several of these atomic cations have been previously studied and the results obtained here are compared to reduced mobilities reported in the literature. In all cases, ions were generated using pulsed-laser vaporization of either a metal rod or foil target. Presented here for the first time are the reduced mobilities of Y+, Ru+, and Rh+. A discussion of the observed trends in the mobilities of the second-row transition metal series, relative to those measured for the first-row series, is also provided.

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Research Organization:: National Security Technologies, LLC. (NSTec), Las Vegas, NV (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-06NA25946

OSTI ID:: 1378286

Alternate ID(s):: OSTI ID: 1576490

Report Number(s):: DOE/NV/25946-2873; S1387380616301154; PII: S1387380616301154

Journal Information:: International Journal of Mass Spectrometry, Journal Name: International Journal of Mass Spectrometry Vol. 407 Journal Issue: C; ISSN 1387-3806

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

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Cited by: 8 works

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