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Title: Cu and Zn Substituted Silicon Clathrates with the Cubic Type-II Structure: Synthesis and Characterization of Cs8Na 16Cu3.8Si132.2 and Cs8Na16Zn6.9Si129.1

Journal Article · · Zeitschrift fuer Anorganische und Allgemeine Chemie
 [1];  [1]
  1. Department of Chemistry and Biochemistry, University of Delaware, 19716 Newark DE USA

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0008885
OSTI ID:
1378150
Journal Information:
Zeitschrift fuer Anorganische und Allgemeine Chemie, Journal Name: Zeitschrift fuer Anorganische und Allgemeine Chemie; ISSN 0044-2313
Publisher:
WileyCopyright Statement
Country of Publication:
Germany
Language:
English
Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

References (21)

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Synthesis and characterization of framework-substituted Cs8Na16Cu5Ge131 journal February 2009
Copper and Zinc Substitutions in Clathrates of Tin: Synthesis, Structural Characterization, and Physical Properties of A 8 Cu 2.67 Sn 43.33 and A 8 Zn 4 Sn 42 ( A = K, Rb, Cs) with the Type-I Structure journal August 2013
Clathrates Ba 8 {Zn,Cd} x Si 46− x , x ∼7: synthesis, crystal structure and thermoelectric properties journal August 2009
New type-I clathrates with ordered Eu distribution journal August 2006
Inorganic clathrate-II materials of group 14: synthetic routes and physical properties journal January 2008
Structural, Chemical, and Transport Properties of a New Clathrate Compound:  Cs 8 Zn 4 Sn 42 journal September 1999
Clathrates of Group 14 with Alkali Metals: An Exploration journal August 2000
On the possibility for Rb- and Eu-cation ordering in type-I clathrates: synthesis and homogeneity range of the novel compounds Rb 8– x Eu x (In,Ge) 46 (0.6 ≤ x ≤ 1.8) journal November 2013
Synthesis and single-crystal X-ray diffraction studies of new framework substituted type II clathrates, Cs8Na16AgxGe136−x (x<7) journal March 2007
Precursor routes to quaternary intermetallics: Synthesis, crystal structure, and physical properties of clathrate-II Cs8Na16Al24Si112 journal May 2016
Ternary clathrates Ba–Zn–Ge: phase equilibria, crystal chemistry and physical properties journal May 2007
A Combined Metal-Halide/Metal Flux Synthetic Route towards Type-I Clathrates: Crystal Structures and Thermoelectric Properties of A 8 Al 8 Si 38 (A=K, Rb, and Cs) journal September 2014
Si-based Clathrates with Partial Substitution by Zn and Ga: K 8 Zn 3.5 Si 42.5 , Rb 7.9 Zn 3.6 Si 42.4 , and Cs 8- x Ga 8- y Si 38+ y : Si-based Clathrates with Partial Substitution by Zn and Ga journal May 2015
Preparation of anionic clathrate-II K 24- x Ge 136 by filling of Ge( cF 136) journal September 2014
New Type-I and Type-II Clathrates in the Systems Cs–Na–Ga–Si, Rb–Na–Ga–Si, and Rb–Na–Zn–Si journal March 2014
Synthesis, Structural Characterization, and Physical Properties of the Type-I Clathrates A 8 Zn 18 As 28 ( A = K, Rb, Cs) and Cs 8 Cd 18 As 28 journal September 2012
Thermoelectric clathrates of type I journal January 2010
Significance tests on the crystallographic R factor journal May 1965
Synthesis and Characterization of Stable Stoichiometric Clathrates of Silicon and Germanium:  Cs 8 Na 16 Si 136 and Cs 8 Na 16 Ge 136 journal April 1999
Tin Clathrates with the Type II Structure journal January 2013