HACA's Heritage: A Free‐Radical Pathway to Phenanthrene in Circumstellar Envelopes of Asymptotic Giant Branch Stars

Yang, Tao; Kaiser, Ralf I.; Troy, Tyler P.; Xu, Bo; Kostko, Oleg; Ahmed, Musahid; Mebel, Alexander M.; Zagidullin, Marsel V.; Azyazov, Valeriy N.

doi:10.1002/ange.201701259

HACA's Heritage: A Free‐Radical Pathway to Phenanthrene in Circumstellar Envelopes of Asymptotic Giant Branch Stars

Journal Article · Wed Mar 22 04:00:00 EDT 2017 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201701259· OSTI ID:1377931

^[1]; ^[1]; Troy, Tyler P. ^[2]; Xu, Bo ^[2]; ^[2]; ^[2]; Mebel, Alexander M. ^[3]; Zagidullin, Marsel V. ^[4]; Azyazov, Valeriy N. ^[4]

Department of Chemistry University of Hawai'i at Manoa Honolulu HI 96822 USA
Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Department of Chemistry and Biochemistry Florida International University Miami FL 33199 USA
Department of Physics Samara National Research University Samara 443086 Russian Federation

Abstract

The hydrogen‐abstraction/acetylene‐addition (HACA) mechanism has been central for the last decades in attempting to rationalize the formation of polycyclic aromatic hydrocarbons (PAHs) as detected in carbonaceous meteorites such as in Murchison. Nevertheless, the basic reaction mechanisms leading to the formation of even the simplest tricyclic PAHs like anthracene and phenanthrene are still elusive. Here, by exploring the previously unknown chemistry of the ortho ‐biphenylyl radical with acetylene, we deliver compelling evidence on the efficient synthesis of phenanthrene in carbon‐rich circumstellar environments. However, the lack of formation of the anthracene isomer implies that HACA alone cannot be responsible for the formation of PAHs in extreme environments. Considering the overall picture, alternative pathways such as vinylacetylene‐mediated reactions are required to play a crucial role in the synthesis of complex PAHs in circumstellar envelopes of dying carbon‐rich stars.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; FG02-04ER15570; FG02-03ER15411; AC02-05CH11231

OSTI ID:: 1377931

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 16 Vol. 129; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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HACA's Heritage: A Free-Radical Pathway to Phenanthrene in Circumstellar Envelopes of Asymptotic Giant Branch Stars

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