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Unravelling the origin of irreversible capacity loss in NaNiO 2 for high voltage sodium ion batteries

Journal Article · · Nano Energy
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Layered transition metal compounds have attracted much attention due to their high theoretical capacity and energy density for sodium ion batteries. However, this kind of material suffers from serious irreversible capacity decay during the charge and discharge process. Here, using synchrotron-based operando transmission X-ray microscopy and high-energy X-ray diffraction combined with electrochemical measurements, the visualization of the dissymmetric phase transformation and structure evolution mechanism of layered NaNiO2 material during initial charge and discharge cycles are clarified. Phase transformation and deformation of NaNiO2 during the voltage range of below 3.0 V and over 4.0 V are responsible for the irreversible capacity loss during the first cycling, which is also confirmed by the evolution of reaction kinetics behavior obtained by the galvanostatic intermittent titration technique. These findings reveal the origin of the irreversibility of NaNiO2 and offer valuable insight into the phase transformation mechanism, which will provide underlying guidance for further development of high-performance sodium ion batteries.
Research Organization:
Argonne National Laboratory (ANL)
Sponsoring Organization:
National Natural Science Foundation of China (NSFC); USDOE Office of Science - Office of Basic Energy Sciences - Scientific User Facilities Division
DOE Contract Number:
AC02-06CH11357
OSTI ID:
1377596
Journal Information:
Nano Energy, Journal Name: Nano Energy Vol. 34; ISSN 2211-2855
Publisher:
Elsevier
Country of Publication:
United States
Language:
English

References (35)

Galvanostatic Intermittent Titration Technique for Phase-Transformation Electrodes journal January 2010
Visualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging journal April 2015
GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal March 2013
In Situ Three-Dimensional Synchrotron X-Ray Nanotomography of the (De)lithiation Processes in Tin Anodes journal March 2014
Probing three-dimensional sodiation–desodiation equilibrium in sodium-ion batteries by in situ hard X-ray nanotomography journal June 2015
Electrical Energy Storage for the Grid: A Battery of Choices journal November 2011
Role of Ligand-to-Metal Charge Transfer in O3-Type NaFeO 2 –NaNiO 2 Solid Solution for Enhanced Electrochemical Properties journal January 2014
Origins of Large Voltage Hysteresis in High-Energy-Density Metal Fluoride Lithium-Ion Battery Conversion Electrodes journal February 2016
In situ chemical mapping of a lithium-ion battery using full-field hard X-ray spectroscopic imaging journal January 2013
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries journal April 2012
A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries journal January 2015
Determination of the Kinetic Parameters of Mixed-Conducting Electrodes and Application to the System Li[sub 3]Sb journal January 1977
Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries journal April 2015
Sodium deintercalation from sodium iron oxide journal June 1994
Structural evolution and electrochemistry of monoclinic NaNiO2 upon the first cycling process journal July 2014
Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li 1.20 Mn 0.54 Co 0.13 Ni 0.13 O 2 in Li Ion Batteries journal March 2014
In Situ X-Ray Diffraction Study of P2-Na[sub 2/3][Ni[sub 1/3]Mn[sub 2/3]]O[sub 2] journal January 2001
Chemical and electrochemical deintercalations of the layered compounds LiMO2 (M = Cr, Co) and NaM′O2 (M′ Cr, Fe, Co, Ni) journal January 1983
Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles journal August 2016
Etude par desintercalation electrochimique des systemes NaxCrO2 et NaxNiO2 journal August 1982
Research Development on Sodium-Ion Batteries journal October 2014
Nickel hydroxide and derived phases obtained by chimie douce from NaNiO2 journal February 1989
Electrochemical Properties of Monoclinic NaNiO 2 journal November 2012
P2-type Na 2/3 Ni 1/3 Mn 2/3−x Ti x O 2 as a new positive electrode for higher energy Na-ion batteries journal January 2014
Olivine LiFePO 4 : the remaining challenges for future energy storage journal January 2015
Improved electrochemical performance and capacity fading mechanism of nano-sized LiMn 0.9 Fe 0.1 PO 4 cathode modified by polyacene coating journal January 2015
Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries journal June 2013
Combining In Situ Synchrotron X-Ray Diffraction and Absorption Techniques with Transmission Electron Microscopy to Study the Origin of Thermal Instability in Overcharged Cathode Materials for Lithium-Ion Batteries journal June 2012
Opportunities and challenges for a sustainable energy future journal August 2012
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage journal January 2013
In operando tracking phase transformation evolution of lithium iron phosphate with hard X-ray microscopy journal August 2014
Layered oxides as positive electrode materials for Na-ion batteries journal May 2014
XAS Investigation of Inhomogeneous Metal-Oxygen Bond Covalency in Bulk and Surface for Charge Compensation in Li-Ion Battery Cathode Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Material journal January 2005
Alkali Metal-Nickel Oxides of the Type MNiO 2 journal March 1954
An advanced cathode for Na-ion batteries with high rate and excellent structural stability journal January 2013

Cited By (11)

Unexpectedly high electrochemical performances of a monoclinic Na 2.4 V 2 (PO 4 ) 3 /conductive polymer composite for Na-ion batteries journal January 2018
Operando X-ray Diffraction Characterization for Understanding the Intrinsic Electrochemical Mechanism in Rechargeable Battery Materials journal April 2017
Na 0.97 KFe(SO 4 ) 2 : an iron-based sulfate cathode material with outstanding cyclability and power capability for Na-ion batteries journal January 2018
Progressive concentration gradient nickel-rich oxide cathode material for high-energy and long-life lithium-ion batteries journal January 2019
Electrochemistry and Solid‐State Chemistry of NaMeO 2 (Me = 3d Transition Metals) journal June 2018
Exploring a high capacity O3-type cathode for sodium-ion batteries and its structural evolution during an electrochemical process journal January 2018
Iodine-doped sulfurized polyacrylonitrile with enhanced electrochemical performance for room-temperature sodium/potassium sulfur batteries journal January 2019
Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures journal January 2019
Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries journal February 2018
Do imaging techniques add real value to the development of better post-Li-ion batteries? journal January 2018
Ni-based cathode materials for Na-ion batteries journal June 2019

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Related Subjects

high voltage
irreversible capacity loss
layered structure materials
sodium-ion batteries
synchrotron-based techniques