Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and methane and alcohol reforming

Rodriguez, José A.; Grinter, David C.; Liu, Zongyuan; Palomino, Robert M.; Senanayake, Sanjaya D.

doi:10.1039/C6CS00863A

Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO ₂ hydrogenation, and methane and alcohol reforming

Journal Article · Fri Feb 17 00:00:00 UTC 2017 · Chemical Society Reviews

DOI:https://doi.org/10.1039/C6CS00863A· OSTI ID:1377054

^[1]; ^[2]; ^[3]; ^[2]; Senanayake, Sanjaya D. ^[2]

Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; State Univ. of New York (SUNY), Stony Brook, NY (United States). Dept. of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
State Univ. of New York (SUNY), Stony Brook, NY (United States). Dept. of Chemistry

Model metal/ceria and ceria/metal catalysts have been shown to be excellent systems for studying fundamental phenomena linked to the operation of technical catalysts. In the last fifteen years, many combinations of well-defined systems involving different kinds of metals and ceria have been prepared and characterized using the modern techniques of surface science. So far most of the catalytic studies have been centered on a few reactions: CO oxidation, the hydrogenation of CO₂, and the production of hydrogen through the water–gas shift reaction and the reforming of methane or alcohols. By using model catalysts it is been possible to examine in detail correlations between the structural, electronic and catalytic properties of ceria–metal interfaces. In situ techniques (X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, infrared spectroscopy, scanning tunneling microscopy) have been combined to study the morphological changes under reaction conditions and investigate the evolution of active phases involved in the cleavage of C–O, C–H and C–C bonds. Several studies with model ceria catalysts have shown the importance of strong metal–support interactions. Generally, a substantial body of knowledge has been acquired and concepts have been developed for a more rational approach to the design of novel technical catalysts containing ceria.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI ID:: 1377054

Report Number(s):: BNL--114201-2017-JA; KC0302010

Journal Information:: Chemical Society Reviews, Journal Name: Chemical Society Reviews Journal Issue: 7 Vol. 46; ISSN 0306-0012; ISSN CSRVBR

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Oxidation State Imaging of Ceria Island Growth on Re(0001) Grinter, David C.; Yim, Chi-Ming; Pang, Chi L. The Journal of Physical Chemistry C, Vol. 117, Issue 32 https://doi.org/10.1021/jp405887h	journal	August 2013
Spectromicroscopy of a Model Water–Gas Shift Catalyst: Gold Nanoparticles Supported on Ceria Grinter, David C.; Muryn, Chris; Santos, Benito The Journal of Physical Chemistry C, Vol. 118, Issue 33 https://doi.org/10.1021/jp5055205	journal	August 2014
Pathways for Ethanol Dehydrogenation and Dehydration Catalyzed by Ceria (111) and (100) Surfaces Beste, Ariana; Overbury, Steven H. The Journal of Physical Chemistry C, Vol. 119, Issue 5 https://doi.org/10.1021/jp509686f	journal	January 2015
CO Oxidation on a CeO _x /Pt(111) Inverse Model Catalyst Surface: Catalytic Promotion and Tuning of Kinetic Phase Diagrams Suchorski, Y.; Wrobel, R.; Becker, S. The Journal of Physical Chemistry C, Vol. 112, Issue 50 https://doi.org/10.1021/jp806033v	journal	November 2008
Destruction of SO ₂ on Au and Cu Nanoparticles Dispersed on MgO(100) and CeO ₂ (111) ^† Rodriguez, José A.; Liu, Ping; Pérez, Manuel The Journal of Physical Chemistry A, Vol. 114, Issue 11 https://doi.org/10.1021/jp905761s	journal	March 2010
Unraveling the Active Site in Copper−Ceria Systems for the Water−Gas Shift Reaction: In Situ Characterization of an Inverse Powder CeO _{2− x} /CuO−Cu Catalyst Barrio, Laura; Estrella, Michael; Zhou, Gong The Journal of Physical Chemistry C, Vol. 114, Issue 8 https://doi.org/10.1021/jp910342b	journal	February 2010
Structural and Redox Properties of Ceria in Alumina-Supported Ceria Catalyst Supports Martínez-Arias, A.; Fernández-García, M.; Salamanca, L. N. The Journal of Physical Chemistry B, Vol. 104, Issue 17 https://doi.org/10.1021/jp992796y	journal	May 2000
Growth and Surface Structure of Ti-Doped CeO _x (111) Thin Films Zhou, Yinghui; Zhou, Jing The Journal of Physical Chemistry Letters, Vol. 1, Issue 11 https://doi.org/10.1021/jz1004297	journal	May 2010
Nanopattering in CeO _x /Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity Senanayake, Sanjaya D.; Sadowski, Jerzy T.; Evans, Jaime The Journal of Physical Chemistry Letters, Vol. 3, Issue 7 https://doi.org/10.1021/jz300159p	journal	March 2012
Growth and Sintering of Au−Pt Nanoparticles on Oxidized and Reduced CeO _x (111) Thin Films by Scanning Tunneling Microscopy Zhou, Yinghui; Zhou, Jing The Journal of Physical Chemistry Letters, Vol. 1, Issue 3 https://doi.org/10.1021/jz900397y	journal	January 2010
Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles Vayssilov, Georgi N.; Lykhach, Yaroslava; Migani, Annapaola Nature Materials, Vol. 10, Issue 4 https://doi.org/10.1038/nmat2976	journal	March 2011
Gold catalysts for pure hydrogen production in the water–gas shift reaction: activity, structure and reaction mechanism Burch, Robbie Phys. Chem. Chem. Phys., Vol. 8, Issue 47 https://doi.org/10.1039/B607837K	journal	January 2006
A review of dry (CO ₂ ) reforming of methane over noble metal catalysts Pakhare, Devendra; Spivey, James Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60395D	journal	January 2014
Sensitivity of CO oxidation toward metal oxidation state in ceria-supported catalysts: an operando DRIFTS-MS study Kaftan, Andre; Kollhoff, Fabian; Nguyen, Thanh-Son Catalysis Science & Technology, Vol. 6, Issue 3 https://doi.org/10.1039/C5CY00827A	journal	January 2016
Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO ₂ (111) catalysts: an in situ study of C–C and O–H bond scission Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru Physical Chemistry Chemical Physics, Vol. 18, Issue 25 https://doi.org/10.1039/C6CP01212D	journal	January 2016
Use of biofuels to produce hydrogen (reformation processes) Piscina, Pilar Ramírez de la; Homs, Narcís Chemical Society Reviews, Vol. 37, Issue 11 https://doi.org/10.1039/b712181b	journal	January 2008
Catalysis and the nature of mixed-metal oxides at the nanometer level: special properties of MOx/TiO2(110) {M= V, W, Ce} surfaces Rodriguez, José A.; Stacchiola, Dario Physical Chemistry Chemical Physics, Vol. 12, Issue 33 https://doi.org/10.1039/c003665j	journal	January 2010
Kinetics and mechanism of the water-gas shift reaction catalysed by the clean and Cs-promoted Cu(110) surface: a comparison with Cu(111) Nakamura, Junji; Campbell, Joseph M.; Campbell, Charles T. Journal of the Chemical Society, Faraday Transactions, Vol. 86, Issue 15 https://doi.org/10.1039/ft9908602725	journal	January 1990
A theoretical insight into the catalytic effect of a mixed-metal oxide at the nanometer level: The case of the highly active metal/CeOx/TiO2(110) catalysts Graciani, Jesús; Plata, José J.; Sanz, Javier Fdez. The Journal of Chemical Physics, Vol. 132, Issue 10 https://doi.org/10.1063/1.3337918	journal	March 2010
High catalytic activity of Au/CeOx/TiO2(110) controlled by the nature of the mixed-metal oxide at the nanometer level Park, J. B.; Graciani, J.; Evans, J. Proceedings of the National Academy of Sciences, Vol. 106, Issue 13 https://doi.org/10.1073/pnas.0812604106	journal	March 2009
Catalytic Properties of Ceria and CeO ₂ -Containing Materials Trovarelli, Alessandro Catalysis Reviews, Vol. 38, Issue 4 https://doi.org/10.1080/01614949608006464	journal	November 1996
Simulations of ceria nanoparticles Cormack, A. N.; Lamphier, S.; Wang, Bu Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 471, Issue 2182 https://doi.org/10.1098/rspa.2015.0218	journal	October 2015
Cerium oxides and cerium-platinum surface alloys on Pt(111) single-crystal surfaces studied by scanning tunneling microscopy Berner, Ulrich; Schierbaum, Klaus-Dieter Physical Review B, Vol. 65, Issue 23 https://doi.org/10.1103/PhysRevB.65.235404	journal	May 2002
Origin of chemical contrast in low-energy electron reflectivity of correlated multivalent oxides: The case of ceria Flege, Jan Ingo; Kaemena, Björn; Meyer, Axel Physical Review B, Vol. 88, Issue 23 https://doi.org/10.1103/PhysRevB.88.235428	journal	December 2013
Diffusion Barriers Block Defect Occupation on Reduced CeO 2 ( 111 ) Lustemberg, P. G.; Pan, Y.; Shaw, B. -J. Physical Review Letters, Vol. 116, Issue 23 https://doi.org/10.1103/PhysRevLett.116.236101	journal	June 2016
Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction Rodriguez, J. A.; Ma, S.; Liu, P. Science, Vol. 318, Issue 5857 https://doi.org/10.1126/science.1150038	journal	December 2007
Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding Farmer, J. A.; Campbell, C. T. Science, Vol. 329, Issue 5994 https://doi.org/10.1126/science.1191778	journal	August 2010
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2 Graciani, J.; Mudiyanselage, K.; Xu, F. Science, Vol. 345, Issue 6196 https://doi.org/10.1126/science.1253057	journal	July 2014

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Selective Aerobic Oxidation of Vanillyl Alcohol to Vanillin Catalysed by Nanostructured Ce-Zr-O Solid Solutions Reddy, P. R. G. Nallappa; Rao, Bolla Govinda; Rao, Tumula Venkateshwar Catalysis Letters, Vol. 149, Issue 2 https://doi.org/10.1007/s10562-019-02658-1	journal	January 2019
Effects of preparation mode and doping on the genesis and properties of Ni/Ce1-xMxOy nanocrystallites (M = Gd, La, Mg) for catalytic applications Matus, Ekaterina V.; Okhlopkova, Lyudmila B.; Sukhova, Olga B. Journal of Nanoparticle Research, Vol. 21, Issue 1 https://doi.org/10.1007/s11051-018-4454-5	journal	January 2019
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