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Deprotonation of a Hydridoborate Anion
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January 2017 |
Stable Versions of Transient Push-Pull Carbenes: Extending Lifetimes from Nanoseconds to Weeks
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May 2000 |
Selektive Generierung und Abfangreaktion eines NHC-stabilisierten B-H-Borylens
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April 2011 |
Synthese und strukturelle Charakterisierung eines stabilen dimeren Bor(II)-Dikations
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December 2007 |
Diborabutatrien: ein elektronenarmes Cumulen
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May 2014 |
Beyond catalysis: N-heterocyclic carbene complexes as components for medicinal, luminescent, and functional materials applications
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January 2010 |
Determining the Ligand Properties of N-Heterocyclic Carbenes from 77 Se NMR Parameters : Ligand Properties of N-Heterocyclic Carbenes
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April 2015 |
A Stable Neutral Diborene Containing a BB Double Bond
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October 2007 |
A 9-Borylated Acridinyl Radical
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February 2007 |
On the Existence of a Tungsten Carbonyl Carbene Complex
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Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion
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Peculiar boron startles again
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June 2015 |
Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature
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February 2016 |
Synthesis and Characterization of B-Heterocyclic π-Radical and Its Reactivity as a Boryl Radical
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December 2012 |
Intramolecularly Stabilized Heavier Tetrylenes: From Monodentate to Bidentate Ligands: Intramolecularly Stabilized Tetrylenes
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October 2015 |
[Bis(trimethylsilyl)methylen](diisopropylamino)boran: ein Allen-homologes NBC-System
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June 1987 |
Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron
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July 2016 |
Synthesis and structure of novel polycyclic species from toluene and m-xylene and the dehalogenation product of difluoro(diisopropylamino)borane
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October 1989 |
Dibora[2]ferrocenophane: A Carbene-Stabilized Diborene in a Strained cis -Configuration
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December 2016 |
31 P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes
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February 2013 |
Isolierung eines neutralen, Bor‐haltigen Radikals, stabilisiert durch ein cyclisches (Alkyl)(amino)carben
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June 2014 |
Durch N-heterocyclische Carbene stabilisierte Borylradikale
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December 2016 |
The Parent Borylene: Betwixt and Between
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January 2012 |
Synthesis and Structure of the First Terminal Borylene Complexes
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December 1998 |
Formation of a borylene by photolysis of an overcrowded bis(methylseleno)borane
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July 1999 |
The synthesis and structure of a carbene-stabilized iminocarboranyl-boron( i ) compound
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January 2015 |
Electron-Precise Coordination Modes of Boron-Centered Ligands
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July 2010 |
Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2
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March 2012 |
Carbene-Bound Borane and Silane Adducts: A Comprehensive DFT Study on Their Stability and Propensity for Hydride-Mediated Ring Expansion
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October 2013 |
Electronically Excited States of Borylenes
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August 2016 |
“Umpolung” at Boron by Reduction of [B(CN)4]− and Formation of the Dianion [B(CN)3]2−
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October 2011 |
Proton Affinities of Cationic Carbone Adducts [AC(PPh 3 ) 2 ] + (A=Halogen, Hydrogen, Methyl) and Unusual Electronic Structures of the Cations and Dications [AC(H)(PPh 3 ) 2 ] 2+
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May 2016 |
The Medicinal Applications of Imidazolium Carbene−Metal Complexes
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August 2009 |
Synthese und Reaktivität von Verbindungen mit elektronenpräzisen B-B-Einfach- und B-B-Mehrfachbindungen
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December 2016 |
Deprotonation of a Borohydride: Synthesis of a Carbene-Stabilized Boryl Anion
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June 2013 |
Infrared Spectra of Boron-Ammonia Reaction Products in Solid Argon
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September 1995 |
NHC-Stabilized 1-Hydro-1 H -borole and Its Nondegenerate Sigmatropic Isomers
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Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes
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September 2014 |
Die Synthese von B 2 (SIDip) 2 und seine Reaktivität zwischen denen von Diboracumulenen und Diborinen
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October 2015 |
N-heterocyclic carbene metal complexes: photoluminescence and applications
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January 2014 |
A Singlet Phosphinidene Stable at Room Temperature
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July 2016 |
Isolation of 1,2,4,3-Triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) Derivatives and Reactivity toward CO and Isonitriles
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May 2016 |
9-Fluorenyliden-2,2,6,6-tetramethylpiperidinoboran: ein Allen-Isoster mit zweifach koordiniertem Bor und BC-Doppelbindung
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May 1985 |
9-Fluorenylidene-2,2,6,6-tetramethylpiperidinoborane: an Allene Isoester with Two-Coordinated Boron and BC Double Bond
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May 1985 |
Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square
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October 2016 |
Isolation and Reduction of Sterically Encumbered Arylboron Dihalides: Novel Boranediyl Insertion into C−C σ-Bonds
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January 1996 |
First structural characterization of a boron-centered radical: x-ray crystal structure of [Li(12-crown-4)2]+ [BMes3]-.bul.
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July 1986 |
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent
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June 2001 |
A 9-Borylated Acridinyl Radical
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February 2007 |
Einfach substituierte Boraethene
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December 1985 |
Carbenes Introduction
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August 2009 |
Stable singlet carbenes as mimics for transition metal centers
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January 2011 |
Simply Substituted Boraethenes
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December 1985 |
Synthese und Struktur der ersten terminalen Borylenkomplexe
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November 1998 |
Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene
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January 2017 |
A facile and selective route to remarkably inert monocyclic NHC-stabilized boriranes
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January 2015 |
The Synthesis of B 2 (SIDip) 2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes
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October 2015 |
Diverse reactivity of a tricoordinate organoboron L 2 PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors
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January 2015 |
Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond
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June 2012 |
Chemistry of boron and silicon subhalides
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April 1973 |
N,N′-Bis(2,2-dimethylpropyl)benzimidazolin-2-ylidene: A Stable Nucleophilic Carbene Derived from Benzimidazole
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N -Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands †
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February 2011 |
Zur Frage eines Wolfram-Carbonyl-Carben-Komplexes
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July 1964 |
Boryl Anions
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January 2015 |
Synthesis and Structure of a Carbene-Stabilized π-Boryl Anion
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Deprotonierung eines Hydridoborat-Anions
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January 2017 |
Ring Enlargement of Three-Membered Boron Heterocycles upon Reaction with Organic π Systems: Implications for the Trapping of Borylenes
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June 2016 |
Synthesis and Structural Characterization of a Stable Dimeric Boron(II) Dication
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December 2007 |
Erzeugung zweifach koordinierter Bor(I)-Einheiten durch Fragmentierung eines molekularen Tetra-Bor(I)-Quadrats
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October 2016 |
Multiple complexation of CO and related ligands to a main-group element
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June 2015 |
The generation and some reactions of methylborylene
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December 1976 |
N , N ′-Diamidocarbenes: Isolable Divalent Carbons with Bona Fide Carbene Reactivity
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July 2016 |
Formation of Boron–Main-Group Element Bonds by Reactions with a Tricoordinate Organoboron L 2 PhB: (L = Oxazol-2-ylidene)
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January 2017 |
Experimental Assessment of the Strengths of B–B Triple Bonds
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January 2015 |
Ligand versus Complex: C−F and C−H Bond Activation of Polyfluoroaromatics at a Cyclic (Alkyl)(Amino)Carbene
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March 2017 |
Boron as an Electron-Pair Donor for B⋅⋅⋅Cl Halogen Bonds
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August 2016 |
Dibora[2]ferrocenophan: ein carbenstabilisiertes Diboren in einer gespannten cis -Konfiguration
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December 2016 |
Pulsed laser evaporated boron atom reactions with acetylene. Infrared spectra and quantum chemical structure and frequency calculations for several novel organoborane BC2H2 and HBC2 molecules
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June 1993 |
“Umpolung” von Bor im [B(CN)4]− Anion durch Reduktion zum Dianion [B(CN)3]2−
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October 2011 |
Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C–H Bond
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November 2011 |
Klassische und nichtklassische Methylenborane
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July 1993 |
A stable crystalline carbene
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Boron-Fluorine Chemistry. I. Boron Monofluoride and Some Derivatives
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Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile
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June 2014 |
Singlet Diradicals: from Transition States to Crystalline Compounds
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March 2002 |
Microwave spectroscopic study of the BBr molecule
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September 1997 |
25 years of N-heterocyclic carbenes: activation of both main-group element–element bonds and NHCs themselves
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January 2016 |
CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap
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May 2006 |
Dative Wechselwirkungen einer Bor-zentrierten Lewis-Base mit Gruppe-13-Elementen
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November 2015 |
Silylated Group 14 Ylenes: An Emerging Class of Reactive Compounds: Silylated Group 14 Ylenes: An Emerging Class of Compounds
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July 2015 |
Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise
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December 2014 |
Photochemical Generation of Triphenylsilylboranediyl (C6H5)3SiB: from Organosilylboranes
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June 1984 |
Alkene–Carbene Isomerization induced by Borane: Access to an Asymmetrical Diborene
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March 2017 |
Cyclische Alkylaminocarbene (CAACs): Neues von guten Bekannten
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June 2017 |
Group 1 and 2 cyclic (alkyl)(amino)carbene complexes
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January 2015 |
Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene
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September 1988 |
Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)
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A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom-Transfer Agent
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September 2012 |
Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives
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June 2009 |
From an Electron-Rich Bis(boraketenimine) to an Electron-Poor Diborene
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February 2015 |
Trapping the Elusive Parent Borylene
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April 2011 |
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron-Rich Ligands for Transition-Metal Catalysts: A Quaternary Carbon Atom Makes the Difference
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September 2005 |
Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene
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January 2016 |
Zur Borylierung von Benzol und Naphthalin durch Dehalogenierungsprodukte von Dichlor(diisopropylamino)boran
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June 1988 |
The Parent Borylene: Betwixt and Between
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January 2012 |
The Lightest Element Phosphoranylidene: NHC-Supported Cyclic Borylidene-Phosphorane with Significant B=P Character
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March 2017 |
An N , N ′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry
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November 2009 |
An overview of N-heterocyclic carbenes
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June 2014 |
Highly Energetic Tetraazidoborate Anion and Boron Triazide Adducts †
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March 2001 |
31 P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes
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January 2013 |
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron-Rich Ligands for Transition-Metal Catalysts: A Quaternary Carbon Atom Makes the Difference
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September 2005 |
Main-group elements as transition metals
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Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation
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July 2016 |
Singlet (Phosphino)phosphinidenes are Electrophilic
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June 2016 |
[Bis(diisopropylamino)phosphino]trimethylsilyl-carben: Ein stabiles nucleophiles Carben
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May 1989 |
Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene
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January 2017 |
Synthesis and Structural Characterization of Carbene-Stabilized Carborane-Fused Azaborolyl Radical Cation and Dicarbollyl-Fused Azaborole
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July 2016 |
Intramolecular “Hydroiminiumation and -amidiniumation” of Alkenes: A Convenient, Flexible, and Scalable Route to Cyclic Iminium and Imidazolinium Salts
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April 2007 |
Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes
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September 2014 |
Reactions of Persistent Carbenes with Hydrogen-Terminated Silicon Surfaces
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June 2016 |
Carbene Ligands in Surface Chemistry: From Stabilization of Discrete Elemental Allotropes to Modification of Nanoscale and Bulk Substrates
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September 2015 |
Planar, Twisted, and Trans-Bent: Conformational Flexibility of Neutral Diborenes
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March 2008 |
N-Heterocyclic Carbene Stabilized Boryl Radicals
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December 2016 |
Classical and Nonclassical Methyleneboranes
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July 1993 |
Stable Carbenes: From ‘Laboratory Curiosities' to Catalysis Mainstays
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June 2013 |
An efficient synthetic route to stable bis(carbene)borylenes [(L 1 )(L 2 )BH]
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January 2014 |
The Lightest Element Phosphoranylidene: NHC-Supported Cyclic Borylidene-Phosphorane with Significant B=P Character
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March 2017 |
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
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May 2006 |
Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene
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June 2014 |
Comparative Reactivity of Different Types of Stable Cyclic and Acyclic Mono- and Diamino Carbenes with Simple Organic Substrates
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March 2014 |
σ-Bond Stretching: A Static Approach for a Dynamic Process
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January 2004 |
Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron
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January 2017 |
Formation and Reactivity of Electron-Precise B−B Single and Multiple Bonds
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December 2016 |
Deprotonierung eines Borhydrids und Synthese eines Carben- stabilisierten Borylanions
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June 2013 |
[Bis(diisopropylamino)phosphino]trimethylsilylcarbene: A Stable Nucleophilic Carbene
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May 1989 |
Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center
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Insertion of Cyclic Alkyl(amino) Carbene into the Si–H Bonds of Hydrochlorosilanes
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Radical-Type Reactivity of the 1,3-Dibora-2,4-Diphosphoniocyclobutane-1,3-diyl
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February 2004 |
N-heterocyclic silylenes as powerful steering ligands in catalysis
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February 2017 |
Phenylborylene: Direct Spectroscopic Characterization in Inert Gas Matrices
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March 2006 |
Convenient access to the tricyanoborate dianion B(CN) 3 2− and selected reactions as a boron-centred nucleophile
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January 2015 |
Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)
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April 2007 |
Adduct Formation, B−H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs
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August 2016 |
Reactivity of Borylenes toward Ethyne, Ethene, and Methane
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October 2012 |
Isolation of a Diborane(6) Dication: Formation and Cleavage of an Electron-Precise B(sp 3 )–B(sp 3 ) Bond
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June 2016 |
Facile Splitting of Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center
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April 2007 |
CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap
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May 2006 |
Carbene Stabilization of Highly Reactive Main-Group Molecules
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December 2011 |
Diborabutatriene: An Electron-Deficient Cumulene
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May 2014 |
Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile
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June 2014 |
Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene
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December 2016 |
Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base
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November 2015 |
Transition metal borylene complexes
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Photochemische Erzeugung von Triphenylsilylborandiyl (C6H5)3SiB: aus Organosilylboranen
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June 1984 |
Von einem elektronenreichen Bis(boraketenimin) zu einem elektronenarmen Diboren
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February 2015 |
Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center
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October 2010 |
σ-Bond Stretching: A Static Approach for a Dynamic Process
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January 2004 |
Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77 Se NMR Chemical Shifts of Their Selenium Adducts
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September 2013 |
Persistent and Stable Radicals of the Heavier Main Group Elements and Related Species
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March 2003 |
Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines
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July 2011 |