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Title: Borylene: eine aufstrebende Verbindungsklasse

Journal Article · · Angewandte Chemie

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0009376
OSTI ID:
1375474
Journal Information:
Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 129 Journal Issue: 35; ISSN 0044-8249
Publisher:
German Chemical SocietyCopyright Statement
Country of Publication:
Germany
Language:
English

References (161)

Coordination of non-stabilized germylenes, stannylenes, and plumbylenes to transition metals journal January 2014
Deprotonation of a Hydridoborate Anion journal January 2017
Stable Versions of Transient Push-Pull Carbenes: Extending Lifetimes from Nanoseconds to Weeks journal May 2000
Selektive Generierung und Abfangreaktion eines NHC-stabilisierten B-H-Borylens journal April 2011
Synthese und strukturelle Charakterisierung eines stabilen dimeren Bor(II)-Dikations journal December 2007
Diborabutatrien: ein elektronenarmes Cumulen journal May 2014
Beyond catalysis: N-heterocyclic carbene complexes as components for medicinal, luminescent, and functional materials applications journal January 2010
Determining the Ligand Properties of N-Heterocyclic Carbenes from 77 Se NMR Parameters : Ligand Properties of N-Heterocyclic Carbenes journal April 2015
A Stable Neutral Diborene Containing a BB Double Bond journal October 2007
A 9-Borylated Acridinyl Radical journal February 2007
On the Existence of a Tungsten Carbonyl Carbene Complex journal August 1964
Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion journal October 2006
Peculiar boron startles again journal June 2015
Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature journal February 2016
Synthesis and Characterization of B-Heterocyclic π-Radical and Its Reactivity as a Boryl Radical journal December 2012
Intramolecularly Stabilized Heavier Tetrylenes: From Monodentate to Bidentate ­Ligands: Intramolecularly Stabilized Tetrylenes journal October 2015
[Bis(trimethylsilyl)methylen](diisopropylamino)boran: ein Allen-homologes NBC-System journal June 1987
Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron journal July 2016
Synthesis and structure of novel polycyclic species from toluene and m-xylene and the dehalogenation product of difluoro(diisopropylamino)borane journal October 1989
Dibora[2]ferrocenophane: A Carbene-Stabilized Diborene in a Strained cis -Configuration journal December 2016
31 P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes journal February 2013
Isolierung eines neutralen, Bor‐haltigen Radikals, stabilisiert durch ein cyclisches (Alkyl)(amino)carben journal June 2014
Durch N-heterocyclische Carbene stabilisierte Borylradikale journal December 2016
The Parent Borylene: Betwixt and Between journal January 2012
Synthesis and Structure of the First Terminal Borylene Complexes journal December 1998
Formation of a borylene by photolysis of an overcrowded bis(methylseleno)borane journal July 1999
The synthesis and structure of a carbene-stabilized iminocarboranyl-boron( i ) compound journal January 2015
Electron-Precise Coordination Modes of Boron-Centered Ligands journal July 2010
Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2 journal March 2012
Carbene-Bound Borane and Silane Adducts: A Comprehensive DFT Study on Their Stability and Propensity for Hydride-Mediated Ring Expansion journal October 2013
Electronically Excited States of Borylenes journal August 2016
“Umpolung” at Boron by Reduction of [B(CN)4]− and Formation of the Dianion [B(CN)3]2− journal October 2011
Proton Affinities of Cationic Carbone Adducts [AC(PPh 3 ) 2 ] + (A=Halogen, Hydrogen, Methyl) and Unusual Electronic Structures of the Cations and Dications [AC(H)(PPh 3 ) 2 ] 2+ journal May 2016
The Medicinal Applications of Imidazolium Carbene−Metal Complexes journal August 2009
Synthese und Reaktivität von Verbindungen mit elektronenpräzisen B-B-Einfach- und B-B-Mehrfachbindungen journal December 2016
Deprotonation of a Borohydride: Synthesis of a Carbene-Stabilized Boryl Anion journal June 2013
Infrared Spectra of Boron-Ammonia Reaction Products in Solid Argon journal September 1995
NHC-Stabilized 1-Hydro-1 H -borole and Its Nondegenerate Sigmatropic Isomers journal May 2011
Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes journal September 2014
Die Synthese von B 2 (SIDip) 2 und seine Reaktivität zwischen denen von Diboracumulenen und Diborinen journal October 2015
N-heterocyclic carbene metal complexes: photoluminescence and applications journal January 2014
A Singlet Phosphinidene Stable at Room Temperature journal July 2016
Isolation of 1,2,4,3-Triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) Derivatives and Reactivity toward CO and Isonitriles journal May 2016
9-Fluorenyliden-2,2,6,6-tetramethylpiperidinoboran: ein Allen-Isoster mit zweifach koordiniertem Bor und BC-Doppelbindung journal May 1985
9-Fluorenylidene-2,2,6,6-tetramethylpiperidinoborane: an Allene Isoester with Two-Coordinated Boron and BC Double Bond journal May 1985
Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square journal October 2016
Isolation and Reduction of Sterically Encumbered Arylboron Dihalides:  Novel Boranediyl Insertion into C−C σ-Bonds journal January 1996
First structural characterization of a boron-centered radical: x-ray crystal structure of [Li(12-crown-4)2]+ [BMes3]-.bul. journal July 1986
(Amino)(Aryl)Carbenes: Stable Singlet Carbenes Featuring a Spectator Substituent journal June 2001
A 9-Borylated Acridinyl Radical journal February 2007
Einfach substituierte Boraethene journal December 1985
Carbenes Introduction journal August 2009
Stable singlet carbenes as mimics for transition metal centers journal January 2011
Simply Substituted Boraethenes journal December 1985
Synthese und Struktur der ersten terminalen Borylenkomplexe journal November 1998
Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene journal January 2017
A facile and selective route to remarkably inert monocyclic NHC-stabilized boriranes journal January 2015
The Synthesis of B 2 (SIDip) 2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes journal October 2015
Diverse reactivity of a tricoordinate organoboron L 2 PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors journal January 2015
Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond journal June 2012
Chemistry of boron and silicon subhalides journal April 1973
N,N′-Bis(2,2-dimethylpropyl)benzimidazolin-2-ylidene: A Stable Nucleophilic Carbene Derived from Benzimidazole journal June 1999
N -Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands journal February 2011
Zur Frage eines Wolfram-Carbonyl-Carben-Komplexes journal July 1964
Boryl Anions book January 2015
Synthesis and Structure of a Carbene-Stabilized π-Boryl Anion journal February 2010
Deprotonierung eines Hydridoborat-Anions journal January 2017
Ring Enlargement of Three-Membered Boron Heterocycles upon Reaction with Organic π Systems: Implications for the Trapping of Borylenes journal June 2016
Synthesis and Structural Characterization of a Stable Dimeric Boron(II) Dication journal December 2007
Erzeugung zweifach koordinierter Bor(I)-Einheiten durch Fragmentierung eines molekularen Tetra-Bor(I)-Quadrats journal October 2016
Multiple complexation of CO and related ligands to a main-group element journal June 2015
The generation and some reactions of methylborylene journal December 1976
N , N ′-Diamidocarbenes: Isolable Divalent Carbons with Bona Fide Carbene Reactivity journal July 2016
Formation of Boron–Main-Group Element Bonds by Reactions with a Tricoordinate Organoboron L 2 PhB: (L = Oxazol-2-ylidene) journal January 2017
Experimental Assessment of the Strengths of B–B Triple Bonds journal January 2015
Ligand versus Complex: C−F and C−H Bond Activation of Polyfluoroaromatics at a Cyclic (Alkyl)(Amino)Carbene journal March 2017
Boron as an Electron-Pair Donor for B⋅⋅⋅Cl Halogen Bonds journal August 2016
Dibora[2]ferrocenophan: ein carbenstabilisiertes Diboren in einer gespannten cis -Konfiguration journal December 2016
Pulsed laser evaporated boron atom reactions with acetylene. Infrared spectra and quantum chemical structure and frequency calculations for several novel organoborane BC2H2 and HBC2 molecules journal June 1993
“Umpolung” von Bor im [B(CN)4]− Anion durch Reduktion zum Dianion [B(CN)3]2−  journal October 2011
Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C–H Bond journal November 2011
Klassische und nichtklassische Methylenborane journal July 1993
A stable crystalline carbene journal January 1991
Boron-Fluorine Chemistry. I. Boron Monofluoride and Some Derivatives journal March 1967
Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile journal June 2014
Singlet Diradicals: from Transition States to Crystalline Compounds journal March 2002
Microwave spectroscopic study of the BBr molecule journal September 1997
25 years of N-heterocyclic carbenes: activation of both main-group element–element bonds and NHCs themselves journal January 2016
CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap journal May 2006
Dative Wechselwirkungen einer Bor-zentrierten Lewis-Base mit Gruppe-13-Elementen journal November 2015
Silylated Group 14 Ylenes: An Emerging Class of Reactive Compounds: Silylated Group 14 Ylenes: An Emerging Class of Compounds journal July 2015
Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise journal December 2014
Photochemical Generation of Triphenylsilylboranediyl (C6H5)3SiB: from Organosilylboranes journal June 1984
Alkene–Carbene Isomerization induced by Borane: Access to an Asymmetrical Diborene journal March 2017
Cyclische Alkylaminocarbene (CAACs): Neues von guten Bekannten journal June 2017
Group 1 and 2 cyclic (alkyl)(amino)carbene complexes journal January 2015
Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene journal September 1988
Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs) journal April 2007
A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom-Transfer Agent journal September 2012
Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives journal June 2009
From an Electron-Rich Bis(boraketenimine) to an Electron-Poor Diborene journal February 2015
Trapping the Elusive Parent Borylene journal April 2011
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron-Rich Ligands for Transition-Metal Catalysts: A Quaternary Carbon Atom Makes the Difference journal September 2005
Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene journal January 2016
Zur Borylierung von Benzol und Naphthalin durch Dehalogenierungsprodukte von Dichlor(diisopropylamino)boran journal June 1988
The Parent Borylene: Betwixt and Between journal January 2012
The Lightest Element Phosphoranylidene: NHC-Supported Cyclic Borylidene-Phosphorane with Significant B=P Character journal March 2017
An N , N ′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry journal November 2009
An overview of N-heterocyclic carbenes journal June 2014
Highly Energetic Tetraazidoborate Anion and Boron Triazide Adducts journal March 2001
31 P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes journal January 2013
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron-Rich Ligands for Transition-Metal Catalysts: A Quaternary Carbon Atom Makes the Difference journal September 2005
Main-group elements as transition metals journal January 2010
Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation journal July 2016
Singlet (Phosphino)phosphinidenes are Electrophilic journal June 2016
[Bis(diisopropylamino)phosphino]trimethylsilyl-carben: Ein stabiles nucleophiles Carben journal May 1989
Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene journal January 2017
Synthesis and Structural Characterization of Carbene-Stabilized Carborane-Fused Azaborolyl Radical Cation and Dicarbollyl-Fused Azaborole journal July 2016
Intramolecular “Hydroiminiumation and -amidiniumation” of Alkenes:  A Convenient, Flexible, and Scalable Route to Cyclic Iminium and Imidazolinium Salts journal April 2007
Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes journal September 2014
Reactions of Persistent Carbenes with Hydrogen-Terminated Silicon Surfaces journal June 2016
Carbene Ligands in Surface Chemistry: From Stabilization of Discrete Elemental Allotropes to Modification of Nanoscale and Bulk Substrates journal September 2015
Planar, Twisted, and Trans-Bent:  Conformational Flexibility of Neutral Diborenes journal March 2008
N-Heterocyclic Carbene Stabilized Boryl Radicals journal December 2016
Classical and Nonclassical Methyleneboranes journal July 1993
Stable Carbenes: From ‘Laboratory Curiosities' to Catalysis Mainstays journal June 2013
An efficient synthetic route to stable bis(carbene)borylenes [(L 1 )(L 2 )BH] journal January 2014
The Lightest Element Phosphoranylidene: NHC-Supported Cyclic Borylidene-Phosphorane with Significant B=P Character journal March 2017
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory journal May 2006
Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene journal June 2014
Comparative Reactivity of Different Types of Stable Cyclic and Acyclic Mono- and Diamino Carbenes with Simple Organic Substrates journal March 2014
σ-Bond Stretching: A Static Approach for a Dynamic Process journal January 2004
Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron journal January 2017
Formation and Reactivity of Electron-Precise B−B Single and Multiple Bonds journal December 2016
Deprotonierung eines Borhydrids und Synthese eines Carben- stabilisierten Borylanions journal June 2013
[Bis(diisopropylamino)phosphino]trimethylsilylcarbene: A Stable Nucleophilic Carbene journal May 1989
Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center journal October 2010
Insertion of Cyclic Alkyl(amino) Carbene into the Si–H Bonds of Hydrochlorosilanes journal February 2016
Radical-Type Reactivity of the 1,3-Dibora-2,4-Diphosphoniocyclobutane-1,3-diyl journal February 2004
N-heterocyclic silylenes as powerful steering ligands in catalysis journal February 2017
Phenylborylene:  Direct Spectroscopic Characterization in Inert Gas Matrices journal March 2006
Convenient access to the tricyanoborate dianion B(CN) 3 2− and selected reactions as a boron-centred nucleophile journal January 2015
Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs) journal April 2007
Adduct Formation, B−H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs journal August 2016
Reactivity of Borylenes toward Ethyne, Ethene, and Methane journal October 2012
Isolation of a Diborane(6) Dication: Formation and Cleavage of an Electron-Precise B(sp 3 )–B(sp 3 ) Bond journal June 2016
Facile Splitting of Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center journal April 2007
CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap journal May 2006
Carbene Stabilization of Highly Reactive Main-Group Molecules journal December 2011
Diborabutatriene: An Electron-Deficient Cumulene journal May 2014
Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile journal June 2014
Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene journal December 2016
Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base journal November 2015
Transition metal borylene complexes journal January 2013
Photochemische Erzeugung von Triphenylsilylborandiyl (C6H5)3SiB: aus Organosilylboranen journal June 1984
Von einem elektronenreichen Bis(boraketenimin) zu einem elektronenarmen Diboren journal February 2015
Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center journal October 2010
σ-Bond Stretching: A Static Approach for a Dynamic Process journal January 2004
Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77 Se NMR Chemical Shifts of Their Selenium Adducts journal September 2013
Persistent and Stable Radicals of the Heavier Main Group Elements and Related Species journal March 2003
Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines journal July 2011