Magnetic phase transitions and magnetoelastic coupling in S=12 Heisenberg antiferromagnets

al-Wahish, Amal; O'Neal, K. R.; Lee, C.; Fan, S.; Hughey, K.; Yokosuk, M. O.; Clune, A. J.; Li, Z.; Schlueter, J. A.; Manson, J. L.; Whangbo, M. -H.; Musfeldt, J. L.

doi:10.1103/PhysRevB.95.104437

Title: Magnetic phase transitions and magnetoelastic coupling in $S = \frac{1}{2}$ Heisenberg antiferromagnets

Journal Article · Wed Mar 01 00:00:00 EST 2017 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.95.104437· OSTI ID:1374881

al-Wahish, Amal; O'Neal, K. R.; Lee, C.; Fan, S.; Hughey, K.; Yokosuk, M. O.; Clune, A. J.; Li, Z.; Schlueter, J. A.; Manson, J. L.; Whangbo, M. -H.; Musfeldt, J. L.

We combined magneto-infrared spectroscopy and first-principles calculations to unravel the role of spin-phonon coupling in the vicinity of the magnetic field-driven phase transitions in two chemically similar S = 1/2 Heisenberg antiferromagnets, CuF2(H2O)(2)(3-Clpy) and [Cu(pyz)(2)(HF2)]PF6. This comparison resolves questions about the conditions under which the lattice participates in magnetic-field-driven transitions and, at the same time, provides a way to predict how the lattice is likely to support microscopic spin rearrangements.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science - Office of Basic Energy Sciences - Materials Sciences and Engineering Division; National Science Foundation (NSF)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1374881

Journal Information:: Physical Review B, Vol. 95, Issue 10; ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

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