Recognition and Extraction of Cesium Hydroxide and Carbonate by Using a Neutral Multitopic Ion‐Pair Receptor

He, Qing; Peters, Gretchen Marie; Lynch, Vincent M.; Sessler, Jonathan L.

doi:10.1002/ange.201705788

Title: Recognition and Extraction of Cesium Hydroxide and Carbonate by Using a Neutral Multitopic Ion‐Pair Receptor

Journal Article · Fri Aug 04 00:00:00 EDT 2017 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201705788· OSTI ID:1373982

^[1];

^[1]; Lynch, Vincent M. ^[1];

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Department of Chemistry University of Texas at Austin 105 E. 24th Street A5300 Austin TX 78712-1224 USA

Abstract Current approaches to lowering the pH of basic media rely on the addition of a proton source. An alternative approach is described herein that involves the liquid–liquid extraction‐based removal of cesium salts, specifically CsOH and Cs ₂ CO ₃ , from highly basic media. A multitopic ion‐pair receptor ( 2 ) is used that can recognize and extract the hydroxide and carbonate anions as their cesium salts, as confirmed by ¹ H NMR spectroscopic titrations, ICP‐MS, single‐crystal structural analyses, and theoretical calculations. A sharp increase in the pH and cesium concentrations in the receiving phase is observed when receptor 2 is employed as a carrier in U‐tube experiments involving the transport of CsOH through an intervening chloroform layer. The pH of the source phase likewise decreases.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-01ER15186

OSTI ID:: 1373982

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 129 Journal Issue: 43; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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