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Methods for enhancing P-type doping in III-V semiconductor films

Patent ·
OSTI ID:1373713

Methods of doping a semiconductor film are provided. The methods comprise epitaxially growing the III-V semiconductor film in the presence of a dopant, a surfactant capable of acting as an electron reservoir, and hydrogen, under conditions that promote the formation of a III-V semiconductor film doped with the p-type dopant. In some embodiments of the methods, the epitaxial growth of the doped III-V semiconductor film is initiated at a first hydrogen partial pressure which is increased to a second hydrogen partial pressure during the epitaxial growth process.

Research Organization:
University of Utah Research Foundation, Salt Lake City, UT (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-04ER46148
Assignee:
University of Utah Research Foundation
Patent Number(s):
9,721,810
Application Number:
13/322,403
OSTI ID:
1373713
Country of Publication:
United States
Language:
English

References (13)

Layer-by-layer growth of Ag on Ag(111) induced by enhanced nucleation: A model study for surfactant-mediated growth journal August 1993
Enhanced cation-substituted p-type doping in GaP from dual surfactant effects journal January 2010
Sb and Bi surfactant effects on homo-epitaxy of GaAs on (001) patterned substrates journal May 2004
Generalized Electron Counting in Determination of Metal-Induced Reconstruction of Compound Semiconductor Surfaces journal September 2006
Dual-Surfactant Effect to Enhance p -Type Doping in III-V Semiconductor Thin Films journal November 2008
Surfactants in epitaxial growth journal August 1989
The use of a surfactant (Sb) to induce triple period ordering in GaInP journal March 2000
Surfactant effects on doping of GaAs grown by organometallic vapor phase epitaxy journal May 2001
X-ray standing-wave study of an Sb-terminated GaAs(001)-(2×4) surface journal July 1995
Importance of the additional step-edge barrier in determining film morphology during epitaxial growth journal May 1995
Effects of surfactants Sb and Bi on the incorporation of zinc and carbon in III/V materials grown by organometallic vapor-phase epitaxy journal August 2006
Spectroscopy of hydrogen‐related complexes in GaP:Zn journal October 1994
Zn enhancement during surfactant-mediated growth of GaInP and GaP journal January 2006

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