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Li- and Mn-Rich Cathode Materials: Challenges to Commercialization

Journal Article · · Advanced Energy Materials
 [1];  [2];  [2];  [3];  [1];  [3];  [2];  [1]
  1. Energy and Environmental Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard Richland WA 99354 USA
  2. School of Energy and Chemical Engineering, Green Energy Materials Development Center, Ulsan National Institute of Science and Technology (UNIST), Korea 689-798
  3. Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 902 Battelle Boulevard Richland WA 99354 USA
+ Show Author Affiliations
The lithium- and manganese-rich (LMR) layered structure cathode exhibit one of the highest specific energy (~900 Wh kg-1) among all the cathode materials. However, the practical applications of LMR cathodes are still hindered by several significant challenges including voltage fade, large initial capacity loss, poor rate capability and limited cycle life. Herein, we review the recent progresses and understandings on the application of LMR cathode materials from practical point of view. Several key parameters of LMR cathodes that affect the LMR/graphite full cell operation are systematically analysed. These factors include the first cycle capacity loss, voltage fade, powder tap density, electrode density of LMR based cathode etc. New approaches to minimize the detrimental effect of these factors are highlighted in this work. We also provided the perspectives for the future research on LMR cathode materials, focusing on addressing the fundamental problems of LMR cathodes while always keeping practical considerations in mind.
Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1373002
Report Number(s):
PNNL-SA-117202; 48379; VT1201000
Journal Information:
Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 6 Vol. 7; ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English

References (182)

Electrochemical kinetics of the 0.5Li2MnO3·0.5LiMn0.42Ni0.42Co0.16O2 ‘composite’ layered cathode material for lithium-ion batteries journal January 2012
Understanding the Origin of Li 2 MnO 3 Activation in Li-Rich Cathode Materials for Lithium-Ion Batteries journal November 2015
High Capacity Li-Rich Positive Electrode Materials with Reduced First-Cycle Irreversible Capacity Loss journal January 2015
The Effects of AlF[sub 3] Coating on the Performance of Li[Li[sub 0.2]Mn[sub 0.54]Ni[sub 0.13]Co[sub 0.13]]O[sub 2] Positive Electrode Material for Lithium-Ion Battery journal January 2008
Understanding the stepwise capacity increase of high energy low-Co Li-rich cathode materials for lithium ion batteries journal January 2014
Recent Developments in Synthesis of xLi2MnO3 · (1 − x)LiMO2 (M = Ni, Co, Mn) Cathode Powders for High-Energy Lithium Rechargeable Batteries journal September 2014
Investigations on cellulose-based high voltage composite cathodes for lithium ion batteries journal September 2011
Synthesis, Characterization and Electrochemistry of Lithium Battery Electrodes: x Li 2 MnO 3 ·(1 − x )LiMn 0.333 Ni 0.333 Co 0.333 O 2 (0 ≤ x ≤ 0.7) journal October 2008
Pre-heat treatment of carbonate precursor firstly in nitrogen and then oxygen atmospheres: A new procedure to improve tap density of high-performance cathode material Li1.167(Ni0.139Co0.139Mn0.556)O2 for lithium ion batteries journal October 2015
Charge/discharge behavior of Li[Ni0.20Li0.20Mn0.60]O2 and Li[Co0.20Li0.27Mn0.53]O2 cathode materials in lithium secondary batteries journal March 2005
Structural and electrochemical properties of (1−x) Li[Ni0.20Li0.20Mn0.60]O2–xLi[Co0.50Li0.167Mn0.333]O2 for lithium secondary batteries journal September 2005
A high energy density full lithium-ion cell based on specially matched coulombic efficiency journal January 2016
Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li 1.2 Ni 0.15 Co 0.1 Mn 0.55 O 2 Cathode Materials journal December 2013
Understanding the Effect of Lithium Bis(oxalato) Borate (LiBOB) on the Structural and Electrochemical Aging of Li and Mn Rich High Capacity Li 1.2 Ni 0.16 Mn 0.56 Co 0.08 O 2 Cathodes journal January 2015
Enhanced performance of sulfone-based electrolytes at lithium ion battery electrodes, including the LiNi0.5Mn1.5O4 high voltage cathode journal September 2014
Influence of Ru substitution on Li-rich 0.55Li2MnO3·0.45LiNi1/3Co1/3Mn1/3O2 cathode for Li-ion batteries journal October 2012
Quantifying the promise of lithium–air batteries for electric vehicles journal January 2014
Fabrication and Performance of High Energy Li-Ion Battery Based on the Spherical Li[Li 0.2 Ni 0.16 Co 0.1 Mn 0.54 ]O 2 Cathode and Si Anode journal December 2015
Development of a scalable spray pyrolysis process for the production of non-hollow battery materials journal November 2014
Tailoring atomic distribution in micron-sized and spherical Li-rich layered oxides as cathode materials for advanced lithium-ion batteries journal January 2016
Conductive Surface Modification with Aluminum of High Capacity Layered Li[Li 0.2 Mn 0.54 Ni 0.13 Co 0.13 ]O 2 Cathodes journal May 2010
The Effects of Acid Treatment on the Electrochemical Properties of 0.5 Li2MnO3 ∙ 0.5 LiNi0.44Co0.25Mn0.31O2 Electrodes in Lithium Cells journal January 2006
High capacity Li[Li0.2Ni0.2Mn0.6]O2 cathode materials via a carbonate co-precipitation method journal November 2006
Enhanced high-rate capability and cycling stability of Na-stabilized layered Li1.2[Co0.13Ni0.13Mn0.54]O2 cathode material journal January 2013
Effect of Cr doping on the structural, electrochemical properties of Li[Li0.2Ni0.2−x/2Mn0.6−x/2Crx]O2 (x=0, 0.02, 0.04, 0.06, 0.08) as cathode materials for lithium secondary batteries journal May 2007
K + -Doped Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 : A Novel Cathode Material with an Enhanced Cycling Stability for Lithium-Ion Batteries journal June 2014
Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives journal October 2015
Mitigating Voltage Fade in Cathode Materials by Improving the Atomic Level Uniformity of Elemental Distribution journal April 2014
Improved rate capability of the conducting functionalized FTO-coated Li-[Li 0.2 Mn 0.54 Ni 0.13 Co 0.13 ]O 2 cathode material for Li-ion batteries journal January 2015
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
  • Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T.
  • Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267 https://doi.org/10.1039/b417616m
journal March 2005
Effect of lithium ions on oxygen reduction in ionic liquid-based electrolytes journal October 2011
Unravelling structural ambiguities in lithium- and manganese-rich transition metal oxides journal October 2015
Pr 6 O 11 -Coated High Capacity Layered Li[Li 0.17 Ni 0.17 Co 0.10 Mn 0.56 ]O 2 as a Cathode Material for Lithium Ion Batteries journal January 2014
Review—Li-Rich Layered Oxide Cathodes for Next-Generation Li-Ion Batteries: Chances and Challenges journal January 2015
Insignificant impact of designed oxygen release from high capacity Li[(Ni1/2Mn1/2)xCoy(Li1/3Mn2/3)1/3]O2 (x+y=2/3) positive electrodes during the cycling of Li-ion cells journal April 2006
Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries journal November 2012
Al Doping for Mitigating the Capacity Fading and Voltage Decay of Layered Li and Mn-Rich Cathodes for Li-Ion Batteries journal February 2016
High Capacity Li[Li[sub 0.2]Mn[sub 0.54]Ni[sub 0.13]Co[sub 0.13]]O[sub 2]–VO[sub 2](B) Composite Cathodes with Controlled Irreversible Capacity Loss for Lithium-Ion Batteries journal January 2011
Cobalt-doped lithium-rich cathode with superior electrochemical performance for lithium-ion batteries journal January 2015
Understanding the Anomalous Capacity of Li / Li [ NixLi ( 1 / 3 − 2x / 3 ) Mn ( 2 / 3 − x / 3 ) ]  O2 Cells Using In Situ X-Ray Diffraction and Electrochemical Studies journal January 2002
Surface modification of Li1.2Mn0.54Co0.13Ni0.13O2 with conducting polypyrrole journal June 2013
Synthesis, Structure, and Electrochemical Behavior of Li[Ni[sub x]Li[sub 1/3−2x/3]Mn[sub 2/3−x/3]]O[sub 2] journal January 2002
Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors journal September 2012
Ti-substituted Li[Li 0.26 Mn 0.6−x Ti x Ni 0.07 Co 0.07 ]O 2 layered cathode material with improved structural stability and suppressed voltage fading journal January 2015
Correlation Between Oxygen Vacancy, Microstrain, and Cation Distribution in Lithium-Excess Layered Oxides During the First Electrochemical Cycle journal April 2013
Tris(pentafluorophenyl) borane-containing electrolytes for electrochemical reversibility of lithium peroxide-based electrodes in lithium–oxygen batteries journal March 2013
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study journal January 2011
Li 2 MnO 3 based Li-rich cathode materials: towards a better tomorrow of high energy lithium ion batteries journal July 2014
Evolutions of Li 1.2 Mn 0.61 Ni 0.18 Mg 0.01 O 2 during the Initial Charge/Discharge Cycle Studied by Advanced Electron Microscopy journal September 2012
Improved Electrochemical Performance and Thermal Stability of Li-excess Li1.18Co0.15Ni0.15Mn0.52O2 Cathode Material by Li3PO4 Surface Coating journal August 2015
Improving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive electrode with alumina journal July 2013
Eliminating the irreversible capacity loss of high capacity layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode by blending with other lithium insertion hosts journal June 2009
Carbon-coated high capacity layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathodes journal June 2010
High Capacity, Surface-Modified Layered Li [Li (1−x) ∕ 3Mn (2−x) ∕ 3Nix ∕ 3Cox ∕ 3 ] O2 Cathodes with Low Irreversible Capacity Loss journal March 2006
The Role of AlF3 Coatings in Improving Electrochemical Cycling of Li-Enriched Nickel-Manganese Oxide Electrodes for Li-Ion Batteries journal February 2012
Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries journal January 2007
Surface study of electrodes after long-term cycling in Li1.2Ni0.15Mn0.55Co0.1O2–graphite lithium-ion cells journal February 2014
Sulfone-based electrolytes for high-voltage Li-ion batteries journal May 2009
Improved electrochemical performance of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode material by fluorine incorporation journal August 2013
Dual active material composite cathode structures for Li-ion batteries journal March 2008
Solid electrolyte coated high voltage layered–layered lithium-rich composite cathode: Li1.2Mn0.525Ni0.175Co0.1O2 journal January 2013
Electrochemical Kinetics and Performance of Layered Composite Cathode Material Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2 journal January 2013
Electrochemical performance studies of Li-rich cathode materials with different primary particle sizes journal April 2014
Synthesis of layered–layered xLi2MnO3·(1−x)LiMO2 (M = Mn, Ni, Co) nanocomposite electrodes materials by mechanochemical process journal December 2012
Effect of surface modifications on the layered solid solution cathodes (1−z) Li[Li1/3Mn2/3]O2−(z) Li[Mn0.5−yNi0.5−yCo2y]O2 journal February 2009
Changes in the structure and physical properties of the solid solution LiNi1–xMnxO2 with variation in its composition journal February 2003
The significance of the Li2MnO3 component in ‘composite’ xLi2MnO3·(1−x)LiMn0.5Ni0.5O2 electrodes journal October 2004
Advanced Li-Rich Cathode Collaborated with Graphite/Silicon Anode for High Performance Li-Ion Batteries in Half and Full Cells journal November 2015
High rate capability caused by surface cubic spinels in Li-rich layer-structured cathodes for Li-ion batteries journal October 2013
Electrochemical Behavior of Suberonitrile as a High-Potential Electrolyte Additive and Co-Solvent for Li[Li 0.2 Mn 0.56 Ni 0.16 Co 0.08 ]O 2 Cathode Material journal January 2015
Structural and Chemical Evolution of Li- and Mn-Rich Layered Cathode Material journal February 2015
Suppressing the voltage-fading of layered lithium-rich cathode materials via an aqueous binder for Li-ion batteries journal January 2016
Sn-stabilized Li-rich layered Li(Li 0.17 Ni 0.25 Mn 0.58 )O 2 oxide as a cathode for advanced lithium-ion batteries journal January 2015
Conflicting Roles of Nickel in Controlling Cathode Performance in Lithium Ion Batteries journal September 2012
Anomalous capacity and cycling stability of xLi2MnO3·(1−x)LiMO2 electrodes (M=Mn, Ni, Co) in lithium batteries at 50°C journal April 2007
Failure mechanism of layered lithium-rich oxide/graphite cell and its solution by using electrolyte additive journal June 2016
Enhanced electrochemical performance in lithium ion batteries of a hollow spherical lithium-rich cathode material synthesized by a molten salt method journal November 2013
Electrochemical behavior of sebaconitrile as a cosolvent in the formulation of electrolytes at high potentials for lithium-ion batteries journal January 2014
A diisocyanate/sulfone binary electrolyte based on lithium difluoro(oxalate)borate for lithium batteries journal January 2013
Synthesis and Electrochemical Performances of Y-Doped Lithium-Rich Layered Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2 Cathode Material journal January 2016
New electrolytes using Li2O or Li2O2 oxides and tris(pentafluorophenyl) borane as boron based anion receptor for lithium batteries journal August 2008
Gas–solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries journal July 2016
Carbonate coprecipitation preparation of Li-rich layered oxides using the oxalate anion ligand as high-energy, high-power and durable cathode materials for lithium-ion batteries journal January 2015
Synthesis–Structure–Property Relations in Layered, “Li-excess” Oxides Electrode Materials Li[Li[sub 1/3−2x/3]Ni[sub x]Mn[sub 2/3−x/3]]O[sub 2] (x=1/3, 1/4, and 1/5) journal January 2010
One-Electron Oxidation of an Organic Molecule by B(C 6 F 5 ) 3 ; Isolation and Structures of Stable Non- para -substituted Triarylamine Cation Radical and Bis(triarylamine) Dication Diradicaloid journal September 2013
Retarded phase transition by fluorine doping in Li-rich layered Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 cathode material journal June 2015
An Advanced Lithium Ion Battery Based on Amorphous Silicon Film Anode and Integrated xLi2MnO3.(1-x)LiNiyMnzCo1-y-zO2 Cathode journal January 2013
Electrochemical Behavior of Layered Solid Solution Li2MnO3−LiMO2 (M = Ni, Mn, Co) Li-Ion Cathodes with and without Alumina Coatings journal January 2011
Eliminating Voltage Decay of Lithium-Rich Li 1.14 Mn 0.54 Ni 0.14 Co 0.14 O 2 Cathodes by Controlling the Electrochemical Process journal March 2015
Hierarchical Mesoporous Lithium-Rich Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2 Cathode Material Synthesized via Ice Templating for Lithium-Ion Battery journal July 2016
Interface modifications by anion receptors for high energy lithium ion batteries journal March 2014
Probing the initiation of voltage decay in Li-rich layered cathode materials at the atomic scale journal January 2015
A comparison of preparation method on the electrochemical performance of cathode material Li[Li0.2Mn0.54Ni0.13Co0.13]O2 for lithium ion battery journal March 2011
The structure, morphology, and electrochemical properties of Li1+xNi1/6Co1/6Mn4/6O2.25+x/2 (0.1≤x≤0.7) cathode materials journal April 2012
Tunable and Robust Phosphite-Derived Surface Film to Protect Lithium-Rich Cathodes in Lithium-Ion Batteries journal April 2015
Examining Hysteresis in Composite x Li 2 MnO 3 ·(1– x )LiMO 2 Cathode Structures journal March 2013
Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of a Solid Solution journal August 2011
The effects of TiO2 coating on the electrochemical performance of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode material for lithium-ion battery journal September 2008
Exploring Electrochemistry and Interface Characteristics of Lithium-Ion Cells with Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 Positive and Li 4 Ti 5 O 12 Negative Electrodes journal January 2015
Ultrathin Spinel Membrane-Encapsulated Layered Lithium-Rich Cathode Material for Advanced Li-Ion Batteries journal May 2014
Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li 2 MnO 3 −LiCo 1/3 Ni 1/3 Mn 1/3 O 2 journal March 2011
Reinvestigation on the state-of-the-art nonaqueous carbonate electrolytes for 5 V Li-ion battery applications journal September 2012
Multifunctional AlPO 4 Coating for Improving Electrochemical Properties of Low-Cost Li[Li 0.2 Fe 0.1 Ni 0.15 Mn 0.55 ]O 2 Cathode Materials for Lithium-Ion Batteries journal February 2015
Facile synthesis of spherical xLi2MnO3·(1−x)Li(Mn0.33Co0.33Ni0.33)O2 as cathode materials for lithium-ion batteries with improved electrochemical performance journal February 2015
Synthesis of Li[Li1.19Ni0.16Co0.08Mn0.57]O2 cathode materials with a high volumetric capacity for Li-ion batteries journal April 2012
Cation Ordering in Layered O3 Li[Ni x Li 1/3 - 2 x /3 Mn 2/ 3 - x /3 ]O 2 (0 ≤ x ≤ 1 / 2 ) Compounds journal May 2005
Nanoscale Surface Modification of Lithium-Rich Layered-Oxide Composite Cathodes for Suppressing Voltage Fade journal September 2015
Electrochemical performance of 0.5Li2MnO3–0.5Li(Mn0.375Ni0.375Co0.25)O2 composite cathode in pyrrolidinium-based ionic liquid electrolytes journal October 2015
Effect of MnO2 modification on electrochemical performance of LiNi0.2Li0.2Mn0.6O2 layered solid solution cathode journal January 2013
Three-dimensional fusiform hierarchical micro/nano Li 1.2 Ni 0.2 Mn 0.6 O 2 with a preferred orientation (110) plane as a high energy cathode material for lithium-ion batteries journal January 2016
Layered Li2MnO3·3LiNi0.5−xMn0.5−xCo2xO2 microspheres with Mn-rich cores as high performance cathode materials for lithium ion batteries journal January 2013
Electrochemical Performance of a Layered-Spinel Integrated Li[Ni 1/3 Mn 2/3 ]O 2 as a High Capacity Cathode Material for Li-Ion Batteries journal March 2015
Understanding the interfacial phenomena of a 4.7 V and 55 °C Li-ion battery with Li-rich layered oxide cathode and graphite anode and its correlation to high-energy cycling performance journal August 2016
Functioning Mechanism of AlF 3 Coating on the Li- and Mn-Rich Cathode Materials journal November 2014
Advances in Sustain Stable Voltage of Cr-Doped Li-Rich Layered Cathodes for Lithium Ion Batteries journal January 2014
Nanostructured Hybrid Layered-Spinel Cathode Material Synthesized by Hydrothermal Method for Lithium-Ion Batteries journal May 2014
The effects of N-methyl-N-butylpyrrolidinium bis(trifluoromethylsulfonyl)imide–based electrolyte on the electrochemical performance of high capacity cathode material Li[Li0.2Mn0.54Ni0.13Co0.13]O2 journal January 2012
Growth mechanism of Ni0.3Mn0.7CO3 precursor for high capacity Li-ion battery cathodes journal January 2011
Atomic-Resolution Visualization of Distinctive Chemical Mixing Behavior of Ni, Co, and Mn with Li in Layered Lithium Transition-Metal Oxide Cathode Materials journal July 2015
Electrochemical characterization of Li2MnO3–Li[Ni1/3Co1/3Mn1/3]O2–LiNiO2 cathode synthesized via co-precipitation for lithium secondary batteries journal April 2009
Synthesis of LiNi0.5Mn1.5O4 and 0.5Li2MnO3–0.5LiNi1/3Co1/3Mn1/3O2 hollow nanowires by electrospinning journal January 2013
Direct Atomic-Resolution Observation of Two Phases in the Li 1.2 Mn 0.567 Ni 0.166 Co 0.067 O 2 Cathode Material for Lithium-Ion Batteries journal April 2013
Tris(hexafluoro-iso-propyl)phosphate as an SEI-Forming Additive on Improving the Electrochemical Performance of the Li[Li 0.2 Mn 0.56 Ni 0.16 Co 0.08 ]O 2 Cathode Material journal December 2012
Initial Coulombic efficiency improvement of the Li1.2Mn0.567Ni0.166Co0.067O2 lithium-rich material by ruthenium substitution for manganese journal January 2012
Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries journal December 2012
Suppressed capacity/voltage fading of high-capacity lithium-rich layered materials via the design of heterogeneous distribution in the composition journal January 2014
A New Spinel-Layered Li-Rich Microsphere as a High-Rate Cathode Material for Li-Ion Batteries journal April 2014
A Layer-Structured Electrode Material Reformed by a PO 4 -O 2 Hybrid Framework toward Enhanced Lithium Storage and Stability journal January 2016
A Comparison of High Capacity xLi[sub 2]MnO[sub 3]⋅(1−x)LiMO[sub 2] (M=Ni,Co,Mn) Cathodes in Lithium-Ion Cells with Li[sub 4]Ti[sub 5]O[sub 12]- and Carbon-Encapsulated Anatase TiO[sub 2] Anodes journal January 2010
A Novel Surface Treatment Method and New Insight into Discharge Voltage Deterioration for High-Performance 0.4Li 2 MnO 3- 0.6LiNi 1/3 Co 1/3 Mn 1/3 O 2 Cathode Materials journal June 2014
Performance Enhancement of 4.8 V Li 1.2 Mn 0.525 Ni 0.175 Co 0.1 O 2 Battery Cathode Using Fluorinated Linear Carbonate as a High-Voltage Additive journal January 2014
Conductivity and electrochemical performance of cathode xLi2MnO3·(1−x)LiMn1/3Ni1/3Co1/3O2 (x=0.1, 0.2, 0.3, 0.4) at different temperatures journal January 2013
Review—Lithium-Excess Layered Cathodes for Lithium Rechargeable Batteries journal January 2015
History, Evolution, and Future Status of Energy Storage journal May 2012
New Insights into Improving Rate Performance of Lithium-Rich Cathode Material journal May 2015
Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2 journal June 2006
The effects of LiTi 2 (PO 4 ) 3 modification on the performance of spherical Li 1.5 Ni 0.25 Mn 0.75 O 2+δ cathode material journal January 2016
Lithium- and Manganese-Rich Oxide Cathode Materials for High-Energy Lithium Ion Batteries journal August 2016
Effect of Lithium Bis(oxalato)borate Additive on Electrochemical Performance of Li 1.17 Ni 0.17 Mn 0.5 Co 0.17 O 2 Cathodes for Lithium-Ion Batteries journal January 2014
Layered Lithium-Rich Oxide Nanoparticles Doped with Spinel Phase: Acidic Sucrose-Assistant Synthesis and Excellent Performance as Cathode of Lithium Ion Battery journal February 2016
Local Structure of Layered Oxide Electrode Materials for Lithium-Ion Batteries journal January 2010
High capacity Li[Li0.2Mn0.54Ni0.13Co0.13]O2–V2O5 composite cathodes with low irreversible capacity loss for lithium ion batteries journal January 2009
Polyimide Encapsulated Lithium-Rich Cathode Material for High Voltage Lithium-Ion Battery journal October 2014
Enhanced Li Storage Performance of LiNi 0.5 Mn 1.5 O 4 –Coated 0.4Li 2 MnO 3 ·0.6LiNi 1/3 Co 1/3 Mn 1/3 O 2 Cathode Materials for Li-Ion Batteries journal September 2014
Surface Modification of Li-Excess Mn-based Cathode Materials journal January 2010
Mitigation of Layered to Spinel Conversion of a Li-Rich Layered Metal Oxide Cathode Material for Li-Ion Batteries journal December 2013
The Configurational Space of Rocksalt-Type Oxides for High-Capacity Lithium Battery Electrodes journal May 2014
Improving High Voltage Interfacial and Structural Stability of Layered Lithium-Rich Oxide Cathode by Using a Boracic Electrolyte Additive journal January 2016
A novel layered Li [Li0.12NizMg0.32−zMn0.56]O2 cathode material for lithium-ion batteries journal October 2004
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries journal January 2014
Host Structural Stabilization of Li 1.232 Mn 0.615 Ni 0.154 O 2 through K-Doping Attempt: toward Superior Electrochemical Performances journal January 2016
Evolution of Lattice Structure and Chemical Composition of the Surface Reconstruction Layer in Li 1.2 Ni 0.2 Mn 0.6 O 2 Cathode Material for Lithium Ion Batteries journal December 2014
Probing the electrode/electrolyte interface in the lithium excess layered oxide Li1.2Ni0.2Mn0.6O2 journal January 2013
Mechanism of Electrochemical Activity in Li 2 MnO 3 journal May 2003
Role of Cobalt Content in Improving the Low-Temperature Performance of Layered Lithium-Rich Cathode Materials for Lithium-Ion Batteries journal August 2015
Effect of amorphous FePO4 coating on structure and electrochemical performance of Li1.2Ni0.13Co0.13Mn0.54O2 as cathode material for Li-ion batteries journal August 2013
Correlating cation ordering and voltage fade in a lithium–manganese-rich lithium-ion battery cathode oxide: a joint magnetic susceptibility and TEM study journal January 2013
Aluminum Borate Coating on High-Voltage Cathodes for Li-Ion Batteries journal January 2015
Mechanisms Associated with the “Plateau” Observed at High Voltage for the Overlithiated Li 1.12 (Ni 0.425 Mn 0.425 Co 0.15 ) 0.88 O 2 System journal August 2008
Role of carbon coating in improving electrochemical performance of Li-rich Li(Li 0.2 Mn 0.54 Ni 0.13 Co 0.13 )O 2 cathode journal January 2014
The effects of Mo doping on 0.3Li[Li0.33Mn0.67]O2·0.7Li[Ni0.5Co0.2Mn0.3]O2 cathode material journal January 2012
Countering the Voltage Decay in High Capacity xLi 2 MnO 3 •(1–x)LiMO 2 Electrodes (M=Mn, Ni, Co) for Li + -Ion Batteries journal January 2012
6Li MAS NMR and in situ X-ray studies of lithium nickel manganese oxides journal June 2003
Quantifying Hysteresis and Voltage Fade in xLi 2 MnO 3 ● (1-x)LiMn 0.5 Ni 0.5 O 2 Electrodes as a Function of Li 2 MnO 3 Content journal December 2013
Perfluoroalkyl-substituted ethylene carbonates: Novel electrolyte additives for high-voltage lithium-ion batteries journal January 2014
Synthetic optimization of Li[Ni1/3Co1/3Mn1/3]O2 via co-precipitation journal December 2004
Continuous activation of Li2MnO3 component upon cycling in Li1.167Ni0.233Co0.100Mn0.467Mo0.033O2 cathode material for lithium ion batteries journal January 2013
Tris(trimethylsilyl)borate as an electrolyte additive for improving interfacial stability of high voltage layered lithium-rich oxide cathode/carbonate-based electrolyte journal July 2015
First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries journal July 2013
Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment journal April 2009
Synthesis and electrochemical properties of layered Li[Li0.15Ni(0.275−x/2)AlxMn(0.575−x/2)]O2 materials prepared by sol–gel method journal June 2003
High-Energy Cathode Materials (Li 2 MnO 3 –LiMO 2 ) for Lithium-Ion Batteries journal March 2013
Synthesis and electrochemical characteristics of Li 1.2 (Ni 0.2 Mn 0.6 ) x (Co 0.4 Mn 0.4 ) y (Ni 0.4 Mn 0.4 ) 1−x−y O 2 (0 ≤ x + y ≤ 1) cathode materials for lithium ion batteries journal January 2015
Comments on stabilizing layered manganese oxide electrodes for Li batteries journal November 2013
Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 journal January 2010
New electrolytes for lithium ion batteries using LiF salt and boron based anion receptors journal October 2008
Effects of structural defects on the electrochemical activation of Li2MnO3 journal September 2015
Countering Voltage Decay and Capacity Fading of Lithium-Rich Cathode Material at 60 °C by Hybrid Surface Protection Layers journal April 2015
Enhanced Electrochemical Performance of Li[Li[sub 0.2]Ni[sub 0.2]Mn[sub 0.6]]O[sub 2] Modified by Manganese Oxide Coating for Lithium-Ion Batteries journal January 2011
Layered Li(Li0.2Ni0.15+0.5zCo0.10Mn0.55−0.5z)O2−zFz cathode materials for Li-ion secondary batteries journal August 2005
High-Performance Li(Li 0.18 Ni 0.15 Co 0.15 Mn 0.52 )O 2 @Li 4 M 5 O 12 Heterostructured Cathode Material Coated with a Lithium Borate Oxide Glass Layer journal August 2015
LixNi0.25Mn0.75Oy (0.5 ≤x≤ 2, 2 ≤y≤ 2.75) compounds for high-energy lithium-ion batteries journal January 2009

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Related Subjects

Environmental Molecular Sciences Laboratory
Li-rich Mn-rich cathode
doping/coating
full cell
initial capacity loss
rate capability
voltage fade