Isolated, well-defined organovanadium(iii) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes

Sohn, H.; Camacho-Bunquin, J.; Langeslay, R. R.; Ignacio-de Leon, P. A.; Niklas, J.; Poluektov, O. G.; Liu, C.; Connell, J. G.; Yang, D.; Kropf, J.; Kim, H.; Stair, P. C.; Ferrandon, M.; Delferro, M.

doi:10.1039/c7cc01876b

Isolated, well-defined organovanadium(iii) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes

Journal Article · Wed May 03 00:00:00 EDT 2017 · ChemComm

DOI:https://doi.org/10.1039/c7cc01876b· OSTI ID:1372471

Sohn, H. ^[1]; ^[1]; ^[1]; Ignacio-de Leon, P. A. ^[1]; ^[1]; Poluektov, O. G. ^[1]; Liu, C. ^[1]; Connell, J. G. ^[1]; Yang, D. ^[1]; Kropf, J. ^[1]; Kim, H. ^[2]; Stair, P. C. ^[2]; Ferrandon, M. ^[1]; ^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); Northwestern Univ., Evanston, IL (United States)

Well-defined, isolated, single-site organovanadium(III) catalyst on SiO₂ [(SiO₂)V(Mes)(THF)] were synthesized via surface organometallic chemistry, and fully characterized using a combination of analytical and spectroscopic techniques (EA, ICP, ¹H NMR, TGA-MS, EPR, XPS, DR-UV/Vis, UV-Raman, DRIFTS, XAS). The catalysts exhibit unprecedented reactivity in liquid- and gas-phase alkene/alkyne hydrogenation. Catalyst poisoning experiments revealed that 100% of the V sites are active for hydrogenation.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1372471

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 53 Vol. 53; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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