Isolated, well-defined organovanadium(iii) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes

Sohn, H.; Camacho-Bunquin, J.; Langeslay, R. R.; Ignacio-de Leon, P. A.; Niklas, J.; Poluektov, O. G.; Liu, C.; Connell, J. G.; Yang, D.; Kropf, J.; Kim, H.; Stair, P. C.; Ferrandon, M.; Delferro, M.

doi:10.1039/c7cc01876b

Isolated, well-defined organovanadium(iii) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes

Journal Article · Wed May 03 00:00:00 EDT 2017 · ChemComm

DOI:https://doi.org/10.1039/c7cc01876b· OSTI ID:1372471

Sohn, H. ^[1]; ^[1]; ^[1]; Ignacio-de Leon, P. A. ^[1]; ^[1]; Poluektov, O. G. ^[1]; Liu, C. ^[1]; Connell, J. G. ^[1]; Yang, D. ^[1]; Kropf, J. ^[1]; Kim, H. ^[2]; Stair, P. C. ^[2]; Ferrandon, M. ^[1]; ^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); Northwestern Univ., Evanston, IL (United States)

Well-defined, isolated, single-site organovanadium(III) catalyst on SiO₂ [(SiO₂)V(Mes)(THF)] were synthesized via surface organometallic chemistry, and fully characterized using a combination of analytical and spectroscopic techniques (EA, ICP, ¹H NMR, TGA-MS, EPR, XPS, DR-UV/Vis, UV-Raman, DRIFTS, XAS). The catalysts exhibit unprecedented reactivity in liquid- and gas-phase alkene/alkyne hydrogenation. Catalyst poisoning experiments revealed that 100% of the V sites are active for hydrogenation.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1372471

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 53 Vol. 53; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (34)

Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry Copéret, Christophe; Chabanas, Mathieu; Petroff Saint-Arroman, Romain Angewandte Chemie International Edition, Vol. 42, Issue 2, p. 156-181 https://doi.org/10.1002/anie.200390072	journal	January 2003
Z -Selective Semihydrogenation of Alkynes Catalyzed by a Cationic Vanadium Bisimido Complex La Pierre, Henry S.; Arnold, John; Toste, F. Dean Angewandte Chemie International Edition, Vol. 50, Issue 17 https://doi.org/10.1002/anie.201007876	journal	March 2011
Discovery of Highly Selective Alkyne Semihydrogenation Catalysts Based on First-Row Transition-Metallated Porous Organic Polymers Tanabe, Kristine K.; Ferrandon, Magali S.; Siladke, Nathan A. Angewandte Chemie International Edition, Vol. 53, Issue 45 https://doi.org/10.1002/anie.201405080	journal	September 2014
The influence of TiO2 on the speciation and hydrogenation activity of Co/Al2O3 catalysts Stranick, M. Journal of Catalysis, Vol. 125, Issue 1 https://doi.org/10.1016/0021-9517(90)90091-W	journal	September 1990
Surface organometallic chemistry of vanadium(V): reactivity of (ButN)VNp3 towards silica Wolke, Silvana I.; Buffon, Regina; Filho, Ubirajara P. Rodrigues Journal of Organometallic Chemistry, Vol. 625, Issue 1 https://doi.org/10.1016/S0022-328X(00)00908-6	journal	April 2001
Promotion of Pt/Al2O3 catalysts with chromium ions and investigation of the changes in their hydrogenating/dehydrogenating activity Vlaev, L. T.; Mohamed, M. M.; Damyanov, D. P. Applied Catalysis, Vol. 63, Issue 1 https://doi.org/10.1016/S0166-9834(00)81720-0	journal	January 1990
Silica-supported alkylidene complexes: their preparation, characterization and reactivity, especially towards olefins Beaudoin, Marcel C.; Womiloju, Omisola; Fu, Anqiu Journal of Molecular Catalysis A: Chemical, Vol. 190, Issue 1-2 https://doi.org/10.1016/S1381-1169(02)00248-0	journal	December 2002
Site-specific oxygen-18 labelling of silica-supported vanadium(V) complexes: Implications for oxidation catalysis Rice, Gordon L.; Scott, Susannah L. Journal of Molecular Catalysis A: Chemical, Vol. 125, Issue 1 https://doi.org/10.1016/S1381-1169(97)00093-9	journal	October 1997
Selective hydrogenation of mixed C4 containing high vinyl acetylene by Mn-Pd, Ni-Pd and Ag-Pd on Al2O3 catalysts Insorn, Paisan; Kitiyanan, Boonyarach Catalysis Today, Vol. 256 https://doi.org/10.1016/j.cattod.2015.01.042	journal	November 2015
Oxo/imido heterometathesis of N-sulfinylamines and carbonyl compounds catalyzed by silica-supported vanadium oxochloride Zhizhko, Pavel A.; Zhizhin, Anton A.; Zarubin, Dmitry N. Journal of Catalysis, Vol. 283, Issue 1 https://doi.org/10.1016/j.jcat.2011.07.011	journal	October 2011
Single-site zinc on silica catalysts for propylene hydrogenation and propane dehydrogenation: Synthesis and reactivity evaluation using an integrated atomic layer deposition-catalysis instrument Camacho-Bunquin, Jeffrey; Aich, Payoli; Ferrandon, Magali Journal of Catalysis, Vol. 345 https://doi.org/10.1016/j.jcat.2016.10.017	journal	January 2017
Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities Copéret, Christophe; Comas-Vives, Aleix; Conley, Matthew P. Chemical Reviews, Vol. 116, Issue 2 https://doi.org/10.1021/acs.chemrev.5b00373	journal	January 2016
Energy of Supported Metal Catalysts: From Single Atoms to Large Metal Nanoparticles James, Trevor E.; Hemmingson, Stephanie L.; Campbell, Charles T. ACS Catalysis, Vol. 5, Issue 10 https://doi.org/10.1021/acscatal.5b01372	journal	September 2015
EPR as a Tool To Investigate the Transition Metal Chemistry on Oxide Surfaces Dyrek, Krystyna; Che, Michel Chemical Reviews, Vol. 97, Issue 1 https://doi.org/10.1021/cr950259d	journal	February 1997
Propylene Hydrogenation and Propane Dehydrogenation by a Single-Site Zn ²⁺ on Silica Catalyst Schweitzer, Neil M.; Hu, Bo; Das, Ujjal ACS Catalysis, Vol. 4, Issue 4 https://doi.org/10.1021/cs401116p	journal	March 2014
Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts Carrero, C. A.; Schloegl, R.; Wachs, I. E. ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs5003417	journal	September 2014
Cascade Catalysis for the Homogeneous Hydrogenation of CO ₂ to Methanol Huff, Chelsea A.; Sanford, Melanie S. Journal of the American Chemical Society, Vol. 133, Issue 45 https://doi.org/10.1021/ja208760j	journal	November 2011
Kinetics and Mechanisms of Thermally Induced Alkane Eliminations from Silica-Supported Bis(alkyl)chromium(IV) and -vanadium(IV) Complexes Amor Nait Ajjou, Jamila; Rice, Gordon L.; Scott, Susannah L. Journal of the American Chemical Society, Vol. 120, Issue 51 https://doi.org/10.1021/ja9831507	journal	December 1998
Benzene Selectivity in Competitive Arene Hydrogenation: Effects of Single-Site Catalyst···Acidic Oxide Surface Binding Geometry Gu, Weixing; Stalzer, Madelyn Marie; Nicholas, Christopher P. Journal of the American Chemical Society, Vol. 137, Issue 21, p. 6770-6780 https://doi.org/10.1021/jacs.5b03254	journal	April 2015
Robust and Porous β-Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation Thacker, Nathan C.; Lin, Zekai; Zhang, Teng Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.5b13394	journal	March 2016
Cooperativity and Dynamics Increase the Performance of NiFe Dry Reforming Catalysts Kim, Sung Min; Abdala, Paula Macarena; Margossian, Tigran Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b11487	journal	January 2017
Precursor Nuclearity Effects in Supported Vanadium Oxides Prepared by Organometallic Grafting Wegener, Staci L.; Kim, Hacksung; Marks, Tobin J. The Journal of Physical Chemistry Letters, Vol. 2, Issue 3 https://doi.org/10.1021/jz101490p	journal	January 2011
Characterization of Silica-Supported Vanadium(V) Complexes Derived from Molecular Precursors and Their Ligand Exchange Reactions Rice, Gordon L.; Scott, Susannah L. Langmuir, Vol. 13, Issue 6 https://doi.org/10.1021/la960679d	journal	March 1997
Chemistry of the vanadium-carbon .sigma. bond. 1. Insertion of carbon monoxide, isocyanides, carbon dioxide, and heterocumulenes into the V-C bond of tris(mesityl)vanadium(III) Vivanco, Marilin; Ruiz, Javier; Floriani, Carlo Organometallics, Vol. 12, Issue 5 https://doi.org/10.1021/om00029a041	journal	May 1993
Synthesis of a Base-Free Titanium Imido and a Transient Alkylidene from a Titanocene Dinitrogen Complex. Studies on TiNR Hydrogenation, Nitrene Group Transfer, and Comparison of 1,2-Addition Rates Hanna, Tamara E.; Keresztes, Ivan; Lobkovsky, Emil Organometallics, Vol. 23, Issue 14 https://doi.org/10.1021/om049817h	journal	July 2004
Vanadium Oxo Organometallic Species Supported on Silica for the Selective Non-oxidative Dehydrogenation of Propane Szeto, Kai C.; Loges, Björn; Merle, Nicolas Organometallics, Vol. 32, Issue 21 https://doi.org/10.1021/om400795s	journal	October 2013
Synthesis and Catalytic Hydrogenation Reactivity of a Chromium Catecholate Porous Organic Polymer Camacho-Bunquin, Jeffrey; Siladke, Nathan A.; Zhang, Guanghui Organometallics, Vol. 34, Issue 5 https://doi.org/10.1021/om501321t	journal	February 2015
A Transient Vanadium(III) Neopentylidene Complex. Redox Chemistry and Reactivity of the VCH ^t Bu Functionality Kilgore, Uriah J.; Sengelaub, Caitlin A.; Fan, Hongjun Organometallics, Vol. 28, Issue 3 https://doi.org/10.1021/om800800g	journal	February 2009
Activation and discovery of earth-abundant metal catalysts using sodium tert-butoxide Docherty, Jamie H.; Peng, Jingying; Dominey, Andrew P. Nature Chemistry, Vol. 9, Issue 6 https://doi.org/10.1038/nchem.2697	journal	January 2017
The recent development of efficient Earth-abundant transition-metal nanocatalysts Wang, Dong; Astruc, Didier Chemical Society Reviews, Vol. 46, Issue 3 https://doi.org/10.1039/C6CS00629A	journal	January 2017
Organometallic model complexes elucidate the active gallium species in alkane dehydrogenation catalysts based on ligand effects in Ga K-edge XANES Getsoian, Andrew “Bean”; Das, Ujjal; Camacho-Bunquin, Jeffrey Catalysis Science & Technology, Vol. 6, Issue 16 https://doi.org/10.1039/C6CY00698A	journal	January 2016
Structures of paramagnetic Viv amido complexes grafted onto metal oxide surfaces: Model systems for heterogeneous vanadium catalysts Grasser, Stefan; Haeßner, Carmen; Köhler, Klaus Physical Chemistry Chemical Physics, Vol. 5, Issue 9 https://doi.org/10.1039/b301205k	journal	March 2003
Porous vanadium-doped titania with active hydrogen: a renewable reductant for chemoselective hydrogenation of nitroarenes under ambient conditions Su, Juan; Zou, Xiao-Xin; Li, Guo-Dong Chemical Communications, Vol. 48, Issue 72 https://doi.org/10.1039/c2cc33969b	journal	January 2012
Surface structural-chemical characterization of a single-site d0 heterogeneous arene hydrogenation catalyst having 100% active sites Williams, L. A.; Guo, N.; Motta, A. Proceedings of the National Academy of Sciences, Vol. 110, Issue 2 https://doi.org/10.1073/pnas.1220240110	journal	December 2012

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