High-Pressure Study of Perovskites and Postperovskites in the (Mg,Fe)GeO 3 System

Stan, Camelia V.; Dutta, Rajkrishna; Cava, Robert J.; Prakapenka, Vitali B.; Duffy, Thomas S.

doi:10.1021/acs.inorgchem.7b00774

High-Pressure Study of Perovskites and Postperovskites in the (Mg,Fe)GeO ₃ System

Journal Article · Mon Jun 26 04:00:00 EDT 2017 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.7b00774· OSTI ID:1372253

^[1]; Dutta, Rajkrishna ^[2]; Cava, Robert J. ^[3]; Prakapenka, Vitali B. ^[4]; Duffy, Thomas S. ^[2]

Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States; Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States
Department of Geosciences, Princeton University, Princeton, New Jersey 08544, United States
Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States
GeoSoilEnviroCARS, University of Chicago, Argonne National Lab, Argonne, Illinois 60439, United States

The effect of incorporation of Fe²⁺ on the perovskite (Pbnm) and postperovskite (Cmcm) structures was investigated in the (Mg,Fe)GeO₃ system at high pressures and temperatures using laser-heated diamond anvil cell and synchrotron X-ray diffraction. Samples with compositions of Mg# ≥ 48 were shown to transform to the perovskite (~30 GPa and ~1500 K) and postperovskite (>55 GPa, ~1600–1800 K) structures. Compositions with Mg# ≥ 78 formed single-phase perovskite and postperovskite, whereas those with Mg# < 78 showed evidence for partial decomposition. The incorporation of Fe into the perovskite structure causes a decrease in octahedral distortion as well as a modest decrease in bulk modulus (K₀) and a modest increase in zero-pressure volume (V₀). It also leads to a decrease in the perovskite-to-postperovskite phase transition pressure by ~9.5 GPa over compositions from Mg#78 to Mg#100.

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)

DOE Contract Number:: AC02-05CH11231; FG02-08ER46544; FG02-94ER14466; AC02-06CH11357

OSTI ID:: 1372253

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 14 Vol. 56; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: ENGLISH

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