Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework

Buru, Cassandra T.; Li, Peng; Mehdi, B. Layla; Dohnalkova, Alice; Platero-Prats, Ana E.; Browning, Nigel D.; Chapman, Karena W.; Hupp, Joseph T.; Farha, Omar K.

doi:10.1021/acs.chemmater.7b00750

Title: Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework

Journal Article · Wed May 24 00:00:00 EDT 2017 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.7b00750· OSTI ID:1372079

^[1];

^[1]; Mehdi, B. Layla ^[2]; Dohnalkova, Alice ^[2];

^[3]; Browning, Nigel D. ^[4]; Chapman, Karena W. ^[3];

^[1];

^[5]

Northwestern Univ., Evanston, IL (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Univ. of Washington, Seattle, WA (United States)
Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)

A Keggin-type polyoxometalate (H₃PW₁₂O₄₀) was incorporated into a mesoporous Zr-based MOF (NU-1000) via an impregnation method in aqueous media, resulting in the hybrid material, PW₁₂@NU-1000. The POM@MOF composite was characterized by a suite of physical methods, indicating the retention of crystallinity and high porosity of the parent MOF. The hybrid material was also stable to leaching in aqueous media at varying pH. Lastly, the material was tested as a heterogeneous catalyst for the oxidation of 2-chloroethyl ethyl sulfide using hydrogen peroxide as the oxidant. PW₁₂@NU-1000 was shown to have a higher catalytic activity than either of the individual constituents alone.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)

Sponsoring Organization:: US Army Research Office (ARO); National Science Foundation (NSF); W.M. Keck Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1372079

Journal Information:: Chemistry of Materials, Vol. 29, Issue 12; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 127 works

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References (59)

Building MOF bottles around phosphotungstic acid ships: One-pot synthesis of bi-functional polyoxometalate-MIL-101 catalysts Juan-Alcañiz, Jana; Ramos-Fernandez, Enrique V.; Lafont, Ugo Journal of Catalysis, Vol. 269, Issue 1 https://doi.org/10.1016/j.jcat.2009.11.011	journal	January 2010
Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates Mizuno, N.; Yamaguchi, K.; Kamata, K. Coordination Chemistry Reviews, Vol. 249, Issue 17-18 https://doi.org/10.1016/j.ccr.2004.11.019	journal	September 2005
Study of Guest Molecules in Metal–Organic Frameworks by Powder X-ray Diffraction: Analysis of Difference Envelope Density Yakovenko, Andrey A.; Wei, Zhangwen; Wriedt, Mario Crystal Growth & Design, Vol. 14, Issue 11 https://doi.org/10.1021/cg500525g	journal	October 2014
Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane at Low Temperature Li, Zhanyong; Peters, Aaron W.; Bernales, Varinia ACS Central Science, Vol. 3, Issue 1 https://doi.org/10.1021/acscentsci.6b00290	journal	November 2016
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
MIL-101 Supported Polyoxometalates: Synthesis, Characterization, and Catalytic Applications in Selective Liquid-Phase Oxidation Maksimchuk, Nataliya V.; Kholdeeva, Oxana A.; Kovalenko, Konstantin A. Israel Journal of Chemistry, Vol. 51, Issue 2 https://doi.org/10.1002/ijch.201000082	journal	February 2011
Stable Metal–Organic Framework-Supported Niobium Catalysts Ahn, Sol; Thornburg, Nicholas E.; Li, Zhanyong Inorganic Chemistry, Vol. 55, Issue 22 https://doi.org/10.1021/acs.inorgchem.6b02103	journal	October 2016
Evaluation of Brønsted acidity and proton topology in Zr- and Hf-based metal–organic frameworks using potentiometric acid–base titration Klet, Rachel C.; Liu, Yangyang; Wang, Timothy C. Journal of Materials Chemistry A, Vol. 4, Issue 4 https://doi.org/10.1039/C5TA07687K	journal	January 2016
Heterogeneous selective oxidation catalysts based on coordination polymer MIL-101 and transition metal-substituted polyoxometalates Maksimchuk, N.; Timofeeva, M.; Melgunov, M. Journal of Catalysis, Vol. 257, Issue 2 https://doi.org/10.1016/j.jcat.2008.05.014	journal	July 2008
Preparation and characterization of polyphosphotungstate/ZrO2 nanocomposite and their sonocatalytic and photocatalytic activity under UV light illumination Salavati, Hossein; Tavakkoli, Nahid; Hosseinpoor, Marzieh Ultrasonics Sonochemistry, Vol. 19, Issue 3 https://doi.org/10.1016/j.ultsonch.2011.09.001	journal	May 2012
³¹ P nuclear magnetic resonance investigation of solid dodecatungstophosphoric acid H ₃ PW ₁₂ O ₄₀ ·xH ₂ O at different hydration levels Chidichimo, G.; Golemme, A.; Imbardelli, D. J. Chem. Soc., Faraday Trans., Vol. 88, Issue 3 https://doi.org/10.1039/FT9928800483	journal	January 1992
Role of Water in Polyoxometalate-Catalyzed Oxidations in Nonaqueous Media. Scope, Kinetics, and Mechanism of Oxidation of Thioether Mustard (HD) Analogs by tert-Butyl Hydroperoxide Catalyzed by H5PV2Mo10O40 Gall, Robin Damico; Faraj, Mahmoud; Hill, Craig L. Inorganic Chemistry, Vol. 33, Issue 22 https://doi.org/10.1021/ic00100a028	journal	October 1994
Regioselective Atomic Layer Deposition in Metal–Organic Frameworks Directed by Dispersion Interactions Gallington, Leighanne C.; Kim, In Soo; Liu, Wei-Guang Journal of the American Chemical Society, Vol. 138, Issue 41 https://doi.org/10.1021/jacs.6b08711	journal	October 2016
Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
Best Practices for the Synthesis, Activation, and Characterization of Metal–Organic Frameworks Howarth, Ashlee J.; Peters, Aaron W.; Vermeulen, Nicolaas A. Chemistry of Materials, Vol. 29, Issue 1 https://doi.org/10.1021/acs.chemmater.6b02626	journal	September 2016
Main-Group Element, Organic, and Organometallic Derivatives of Polyoxometalates Gouzerh, Pierre; Proust, Anna Chemical Reviews, Vol. 98, Issue 1 https://doi.org/10.1021/cr960393d	journal	February 1998
Defining the Proton Topology of the Zr₆-Based Metal–Organic Framework NU-1000 Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723 https://doi.org/10.1021/jz501899j	journal	October 2014
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828	journal	May 2013
Solar-Driven Water Oxidation and Decoupled Hydrogen Production Mediated by an Electron-Coupled-Proton Buffer Bloor, Leanne G.; Solarska, Renata; Bienkowski, Krzysztof Journal of the American Chemical Society, Vol. 138, Issue 21 https://doi.org/10.1021/jacs.6b03187	journal	May 2016
One-pot hydrothermal synthesis of H3PW12O40 supported on zeolite imidazolate frameworks (ZIF-8): a highly efficient heterogeneous catalyst for oxidation of sulfides to sulfoxides and sulfones Ebrahimi, Negar; Fazaeli, Razieh; Aliyan, Hamid Zeitschrift für Naturforschung B, Vol. 71, Issue 3 https://doi.org/10.1515/znb-2015-0142	journal	March 2016
Questioning the paradigm of metal complex promoted phosphodiester hydrolysis: [Mo ₇ O ₂₄ ] ⁶⁻ polyoxometalate cluster as an unlikely catalyst for the hydrolysis of a DNA model substrate Cartuyvels, Els; Absillis, Gregory; Parac-Vogt, Tatjana N. Chem. Commun., Issue 1 https://doi.org/10.1039/B714860G	journal	January 2008
Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices Long, De-Liang; Burkholder, Eric; Cronin, Leroy Chem. Soc. Rev., Vol. 36, Issue 1 https://doi.org/10.1039/B502666K	journal	January 2007
Hydrolytic Stability and Hydrogen Peroxide Activation of Zirconium-Based Oxoclusters: Hydrolytic Stability of Zirconium-Based Oxoclusters Faccioli, Francesco; Bauer, Matthias; Pedron, Danilo European Journal of Inorganic Chemistry, Vol. 2015, Issue 2 https://doi.org/10.1002/ejic.201402767	journal	November 2014
Immobilization of Co-containing polyoxometalates in MIL-101(Cr): structural integrity versus chemical transformation Salomon, William; Yazigi, François-Joseph; Roch-Marchal, Catherine Dalton Trans., Vol. 43, Issue 33 https://doi.org/10.1039/C4DT01286K	journal	January 2014
Hybrid Polyoxotungstate/MIL-101 Materials: Synthesis, Characterization, and Catalysis of H ₂ O ₂ -Based Alkene Epoxidation Maksimchuk, Nataliya V.; Kovalenko, Konstantin A.; Arzumanov, Sergey S. Inorganic Chemistry, Vol. 49, Issue 6 https://doi.org/10.1021/ic902459f	journal	March 2010
Toward Design Rules for Enzyme Immobilization in Hierarchical Mesoporous Metal-Organic Frameworks Li, Peng; Modica, Justin A.; Howarth, Ashlee J. Chem, Vol. 1, Issue 1 https://doi.org/10.1016/j.chempr.2016.05.001	journal	July 2016
Insights into the electrochemical behaviour of composite materials: Monovacant polyoxometalates @ porous metal-organic framework de Sousa, Patrícia M. Paes; Grazina, Raquel; Barbosa, André D. S. Electrochimica Acta, Vol. 87 https://doi.org/10.1016/j.electacta.2012.09.099	journal	January 2013
Distinguishing Homogeneous from Heterogeneous Water Oxidation Catalysis when Beginning with Polyoxometalates Stracke, Jordan J.; Finke, Richard G. ACS Catalysis, Vol. 4, Issue 3 https://doi.org/10.1021/cs4011716	journal	January 2014
Postsynthetic modification of metal–organic frameworks Wang, Zhenqiang; Cohen, Seth M. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b802258p	journal	January 2009
A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination Song, Jie; Luo, Zhen; Britt, David K. Journal of the American Chemical Society, Vol. 133, Issue 42, p. 16839-16846 https://doi.org/10.1021/ja203695h	journal	October 2011
Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation Deria, Pravas; Bury, Wojciech; Hupp, Joseph T. Chemical Communications, Vol. 50, Issue 16, p. 1965-1968 https://doi.org/10.1039/c3cc48562e	journal	January 2014
New Heterogeneous Polyoxometalate Based Mesoporous Catalysts for Hydrogen Peroxide Mediated Oxidation Reactions Vasylyev, Maxym V.; Neumann, Ronny Journal of the American Chemical Society, Vol. 126, Issue 3 https://doi.org/10.1021/ja036702g	journal	January 2004
Synthesis and acidic catalytic properties of ordered mesoporous alumina–tungstophosphoric acid composites Armatas, Gerasimos S.; Katsoulidis, Alexandros P.; Petrakis, Dimitris E. Journal of Materials Chemistry, Vol. 20, Issue 39 https://doi.org/10.1039/c0jm01283a	journal	January 2010
High Efficiency Adsorption and Removal of Selenate and Selenite from Water Using Metal–Organic Frameworks Howarth, Ashlee J.; Katz, Michael J.; Wang, Timothy C. Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b03904	journal	June 2015
Efficient and selective oxidation of sulfur mustard using singlet oxygen generated by a pyrene-based metal–organic framework Liu, Yangyang; Buru, Cassandra T.; Howarth, Ashlee J. Journal of Materials Chemistry A, Vol. 4, Issue 36 https://doi.org/10.1039/C6TA05903A	journal	January 2016
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area Ferey, G.; Mellot-Draznieks, C.; Serre, C. Science, Vol. 309, Issue 5743, p. 2040-2042 https://doi.org/10.1126/science.1116275	journal	September 2005
Towards efficient polyoxometalate encapsulation in MIL-100(Cr): influence of synthesis conditions Juan-Alcañiz, Jana; Goesten, Maarten G.; Ramos-Fernandez, Enrique V. New Journal of Chemistry, Vol. 36, Issue 4 https://doi.org/10.1039/c2nj20587d	journal	January 2012
Highly Stable Crystalline Catalysts Based on a Microporous Metal−Organic Framework and Polyoxometalates Sun, Chun-Yan; Liu, Shu-Xia; Liang, Da-Dong Journal of the American Chemical Society, Vol. 131, Issue 5 https://doi.org/10.1021/ja807357r	journal	February 2009
Polyoxometalate [γ-SiW10O34(H2O)2]4− on MCM-41 as catalysts for sulfide oxygenation with hydrogen peroxide Thompson, Dylan J.; Zhang, Yang; Ren, Tong Journal of Molecular Catalysis A: Chemical, Vol. 392 https://doi.org/10.1016/j.molcata.2014.05.015	journal	October 2014
Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard Howarth, Ashlee J.; Buru, Cassandra T.; Liu, Yangyang Chemistry - A European Journal, Vol. 23, Issue 1 https://doi.org/10.1002/chem.201604972	journal	November 2016
Host (aluminum incorporated mesocellulous silica foam (Al-MCF))-guest (tungsten polyoxometalate) nanocomposite material: an efficient and reusable catalyst for selective oxidation of sulfides to sulfoxides and sulfones Fazaeli, Razieh; Aliyan, Hamid; Ahmadi, Mohammad Ali Catalysis Communications, Vol. 29 https://doi.org/10.1016/j.catcom.2012.09.018	journal	December 2012
1H, 31P NMR MAS, infrared and catalytic studies of heteropolyacid H3PW12O40 supported on MgF2 Mastikhin, V. M.; Terskikh, V. V.; Timofeeva, M. N. Journal of Molecular Catalysis A: Chemical, Vol. 95, Issue 2 https://doi.org/10.1016/1381-1169(94)00003-4	journal	January 1995
Polyoxometalates: Building Blocks for Functional Nanoscale Systems Long, De-Liang; Tsunashima, Ryo; Cronin, Leroy Angewandte Chemie International Edition, Vol. 49, Issue 10, p. 1736-1758 https://doi.org/10.1002/anie.200902483	journal	March 2010
Polyoxometalate based open-frameworks (POM-OFs) Miras, Haralampos N.; Vilà-Nadal, Laia; Cronin, Leroy Chemical Society Reviews, Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00097H	journal	January 2014
An Exceptionally Stable Metal–Organic Framework Supported Molybdenum(VI) Oxide Catalyst for Cyclohexene Epoxidation Noh, Hyunho; Cui, Yuexing; Peters, Aaron W. Journal of the American Chemical Society, Vol. 138, Issue 44 https://doi.org/10.1021/jacs.6b08898	journal	October 2016
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
Polyoxometalate water oxidation catalysts and the production of green fuel Lv, Hongjin; Geletii, Yurii V.; Zhao, Chongchao Chemical Society Reviews, Vol. 41, Issue 22, p. 7572-7589 https://doi.org/10.1039/c2cs35292c	journal	January 2012
Broad-Spectrum Liquid- and Gas-Phase Decontamination of Chemical Warfare Agents by One-Dimensional Heteropolyniobates Guo, Weiwei; Lv, Hongjin; Sullivan, Kevin P. Angewandte Chemie International Edition, Vol. 55, Issue 26 https://doi.org/10.1002/anie.201601620	journal	April 2016
Efficient extraction of sulfate from water using a Zr-metal–organic framework Howarth, Ashlee J.; Wang, Timothy C.; Al-Juaid, Salih S. Dalton Transactions, Vol. 45, Issue 1 https://doi.org/10.1039/C5DT04163E	journal	January 2016
Mechanism of H ₂ O ₂ Decomposition on Transition Metal Oxide Surfaces Lousada, Cláudio M.; Johansson, Adam Johannes; Brinck, Tore The Journal of Physical Chemistry C, Vol. 116, Issue 17 https://doi.org/10.1021/jp300255h	journal	April 2012
Live encapsulation of a Keggin polyanion in NH2-MIL-101(Al) observed by in situ time resolved X-ray scattering Juan-Alcañiz, Jana; Goesten, Maarten; Martinez-Joaristi, Alberto Chemical Communications, Vol. 47, Issue 30 https://doi.org/10.1039/c1cc12213d	journal	January 2011
Studies on the Mechanism of the Toxic Action of Organic Halogen Compounds Hirade, Junkichiro; Ninomiya, Akira The Journal of Biochemistry, Vol. 37, Issue 1 https://doi.org/10.1093/oxfordjournals.jbchem.a126178	journal	June 1950
Cationic Covalent Organic Frameworks: A Simple Platform of Anionic Exchange for Porosity Tuning and Proton Conduction Ma, Heping; Liu, Bailing; Li, Bin Journal of the American Chemical Society, Vol. 138, Issue 18 https://doi.org/10.1021/jacs.5b13490	journal	April 2016
Location of Protons in Anhydrous Keggin Heteropolyacids H ₃ PMo ₁₂ O ₄₀ and H ₃ PW ₁₂ O ₄₀ by ¹ H{ ³¹ P}/ ³¹ P{ ¹ H} REDOR NMR and DFT Quantum Chemical Calculations Ganapathy, S.; Fournier, M.; Paul, J. F. Journal of the American Chemical Society, Vol. 124, Issue 26 https://doi.org/10.1021/ja017848n	journal	July 2002
Rational design of efficient electrode–electrolyte interfaces for solid-state energy storage using ion soft landing Prabhakaran, Venkateshkumar; Mehdi, B. Layla; Ditto, Jeffrey J. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11399	journal	April 2016
Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions Kozhevnikov, Ivan V. Chemical Reviews, Vol. 98, Issue 1 https://doi.org/10.1021/cr960400y	journal	February 1998
Synthesis, characterization and catalytic evaluation of H 3 PW 12 O 40 included in acrylic acid/acrylamide polymer for the selective oxidation of sulfides Frenzel, R.; Morales, D.; Romanelli, G. Journal of Molecular Catalysis A: Chemical, Vol. 420 https://doi.org/10.1016/j.molcata.2016.01.026	journal	August 2016
Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67 Salomon, William; Roch-Marchal, Catherine; Mialane, Pierre Chemical Communications, Vol. 51, Issue 14 https://doi.org/10.1039/C4CC09986A	journal	January 2015
A study of the decomposition behaviour of 12-tungstophosphate heteropolyacid in solution Zhu, Zhirong; Tain, Ruan; Rhodes, Colin Canadian Journal of Chemistry, Vol. 81, Issue 10 https://doi.org/10.1139/v03-129	journal	October 2003

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36 MATERIALS SCIENCE
NU-1000
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Title: Adsorption of a catalytically accessible polyoxometalate in a mesoporous channel-type metal–organic framework

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