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Sensor for Measuring Hydrogen Partial Pressure in Parabolic Trough Power Plant Expansion Tanks

Conference ·
DOI:https://doi.org/10.1063/1.4984331· OSTI ID:1372037

The National Renewable Energy Laboratory and Acciona Energy North America are working together to design and implement a process system that provides a permanent solution to the issue of hydrogen buildup at parabolic trough power plants. We are pursuing a method that selectively removes hydrogen from the expansion tanks that serve as reservoirs for the heat transfer fluid (HTF) that circulates in the collector field and power block components. Our modeling shows that removing hydrogen from the expansion tanks at a design rate reduces and maintains dissolved hydrogen in the circulating HTF to a selected target level. Our collaborative work consists of several tasks that are needed to advance this process concept to a development stage, where it is ready for implementation at a commercial power plant. Our main effort is to design and evaluate likely process-unit operations that remove hydrogen from the expansion tanks at a specified rate. Additionally, we designed and demonstrated a method and instrumentation to measure hydrogen partial pressure and concentration in the expansion-tank headspace gas. We measured hydrogen partial pressure in the headspace gas mixture using a palladium-alloy membrane, which is permeable exclusively to hydrogen. The membrane establishes a pure hydrogen gas phase that is in equilibrium with the hydrogen in the gas mixture. We designed and fabricated instrumentation, and demonstrated its effectiveness in measuring hydrogen partial pressures over a range of three orders of magnitude. Our goal is to install this instrument at the Nevada Solar One power plant and to demonstrate its effectiveness in measuring hydrogen levels in the expansion tanks under normal plant operating conditions.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S)
DOE Contract Number:
AC36-08GO28308
OSTI ID:
1372037
Report Number(s):
NREL/CP-5500-66800
Country of Publication:
United States
Language:
English

References (6)

High flux palladium–copper composite membranes for hydrogen separations journal May 2006
Hydrogen Membrane Separation Techniques journal February 2006
Palladium and palladium alloy membranes for hydrogen separation and production: History, fabrication strategies, and current performance journal May 2010
Techno-economic analysis of receiver replacement scenarios in a parabolic trough field
  • Röger, Marc; Lüpfert, Eckhard; Caron, Simon
  • SOLARPACES 2015: International Conference on Concentrating Solar Power and Chemical Energy Systems, AIP Conference Proceedings https://doi.org/10.1063/1.4949082
conference January 2016
Devlopment of palladium/ceramic membranes for hydrogen separation journal April 2011
Palladium–silver composite membranes by electroless plating technique journal June 1999

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