Electron-Scavenging Chemistry of Benzoquinone on TiO2(110)

Henderson, Michael A.; Shen, Mingmin

doi:10.1007/s11244-016-0707-7

Electron-Scavenging Chemistry of Benzoquinone on TiO2(110)

Journal Article · Mon Apr 03 04:00:00 EDT 2017 · Topics in Catalysis

DOI:https://doi.org/10.1007/s11244-016-0707-7· OSTI ID:1371974

Henderson, Michael A.; Shen, Mingmin

The chemistry of benzoquinone (BQ) on TiO2(110) was examined using temperature programmed desorption (TPD), electron energy loss spectroscopy (EELS) and Auger electron spectroscopy (AES). BQ adsorbs mostly molecularly on the clean surface, although EELS demonstrates that electrons from surface Ti3+ sites at oxygen vacancy sites (VO) are readily oxidized by the high electron scavenging ability of the molecule. In contrast, when the surface is covered with water, subsequently adsorbed BQ molecules that scavenge surface electrons also abstract H from surface OHbr groups to form hydroquinone (HQ), which desorbs at ~450 K. This work was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle. The research was performed using the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1371974

Report Number(s):: PNNL-SA-116760; 48287; KC0302010

Journal Information:: Topics in Catalysis, Journal Name: Topics in Catalysis Journal Issue: 6-7 Vol. 60; ISSN 1022-5528

Publisher:: Springer

Country of Publication:: United States

Language:: English

References (48)

On the photoelectron spectrum of p -benzoquinone Stanton, John F.; Sattelmeyer, Kurt W.; Gauss, Jürgen The Journal of Chemical Physics, Vol. 115, Issue 1 https://doi.org/10.1063/1.1381575	journal	July 2001
Investigation of the photodecomposition of phenol in near-UV-irradiated aqueous TiO2 suspensions. II. Effect of charge-trapping species on product distribution Ilisz, István; Dombi, András Applied Catalysis A: General, Vol. 180, Issue 1-2 https://doi.org/10.1016/S0926-860X(98)00375-5	journal	April 1999
Electron Transfer by Excited Benzoquinone Anions: Slow Rates for Two-Electron Transitions Zamadar, Matibur; Cook, Andrew R.; Lewandowska-Andralojc, Anna The Journal of Physical Chemistry A, Vol. 117, Issue 35 https://doi.org/10.1021/jp403113u	journal	August 2013
Photomineralisation of 4-chlorophenol sensitised by titanium dioxide: a study of the intermediates Mills, Andrew; Morris, Sian; Davies, Richard Journal of Photochemistry and Photobiology A: Chemistry, Vol. 70, Issue 2 https://doi.org/10.1016/1010-6030(93)85040-F	journal	February 1993
Self-cleaning titania films: an overview of direct, lateral and remote photo-oxidation processes Mills, Andrew; Hodgen, Stephanie; Lee, Soo Keun Research on Chemical Intermediates, Vol. 31, Issue 4-6 https://doi.org/10.1163/1568567053956644	journal	June 2005
UV-vis spectra of p-benzoquinone anion radical in solution by a TD-DFT/PCM approach Barone, Vincenzo; Improta, Roberto; Morelli, Giovanni Theoretical Chemistry Accounts, Vol. 118, Issue 1 https://doi.org/10.1007/s00214-007-0257-y	journal	February 2007
Electron affinities of benzo-, naphtho-, and anthraquinones determined from gas-phase equilibria measurements Heinis, Thomas.; Chowdhury, Swapan.; Scott, Susannah L. Journal of the American Chemical Society, Vol. 110, Issue 2 https://doi.org/10.1021/ja00210a015	journal	January 1988
An HREELS and TPD study of water on TiO2(110): the extent of molecular versus dissociative adsorption Henderson, Michael A. Surface Science, Vol. 355, Issue 1-3 https://doi.org/10.1016/0039-6028(95)01357-1	journal	June 1996
Tetraoxygen on Reduced TiO 2 ( 110 ) : Oxygen Adsorption and Reactions with Bridging Oxygen Vacancies Kimmel, Greg A.; Petrik, Nikolay G. Physical Review Letters, Vol. 100, Issue 19 https://doi.org/10.1103/PhysRevLett.100.196102	journal	May 2008
Correlation between Bonding Geometry and Band Gap States at Organic−Inorganic Interfaces: Catechol on Rutile TiO ₂ (110) Li, Shao-Chun; Wang, Jian-guo; Jacobson, Peter Journal of the American Chemical Society, Vol. 131, Issue 3 https://doi.org/10.1021/ja803595u	journal	January 2009
Interaction of Molecular Oxygen with the Vacuum-Annealed TiO ₂ (110) Surface: Molecular and Dissociative Channels Henderson, Michael A.; Epling, William S.; Perkins, Craig L. The Journal of Physical Chemistry B, Vol. 103, Issue 25 https://doi.org/10.1021/jp990655q	journal	June 1999
Temporary anion states of p-benzoquinone: shape and core-excited resonances Cheng, Hsiu-Yao; Huang, Yu-Shiuan Phys. Chem. Chem. Phys., Vol. 16, Issue 47 https://doi.org/10.1039/C4CP03353A	journal	January 2014
Resonance Raman and FTIR Spectra of Isotope-Labeled Reduced 1,4-Benzoquinone and Its Protonated Forms in Solutions Zhao, Xiaojie; Imahori, Hiroshi; Zhan, Chang-Guo The Journal of Physical Chemistry A, Vol. 101, Issue 4 https://doi.org/10.1021/jp962009m	journal	January 1997
A CNDO/S assessment of the electronic structure of p ‐benzoquinone and tetrafluoro‐ p ‐benzoquinone Bigelow, Richard W. The Journal of Chemical Physics, Vol. 68, Issue 11 https://doi.org/10.1063/1.435627	journal	June 1978
Photochemical Charge Transfer and Trapping at the Interface between an Organic Adlayer and an Oxide Semiconductor Henderson, Michael A.; White, J. Michael; Uetsuka, Hiroshi Journal of the American Chemical Society, Vol. 125, Issue 49 https://doi.org/10.1021/ja037764+	journal	November 2003
Electronic States and Spectra of p ‐Benzoquinone Trommsdorff, H. P. The Journal of Chemical Physics, Vol. 56, Issue 11 https://doi.org/10.1063/1.1677047	journal	June 1972
Photocatalytic Degradation of 4-Chlorophenol in Aerated Aqueous Titanium Dioxide Suspensions: A Kinetic and Mechanistic Study Theurich, J.; Lindner, M.; Bahnemann, D. W. Langmuir, Vol. 12, Issue 26 https://doi.org/10.1021/la960228t	journal	January 1996
Semiconductor-sensitized photodegradation of 4-chlorophenol in water Al-Sayyed, Ghassan; D'Oliveira, Jean-Christophe; Pichat, Pierre Journal of Photochemistry and Photobiology A: Chemistry, Vol. 58, Issue 1 https://doi.org/10.1016/1010-6030(91)87101-Z	journal	April 1991
Negative ion properties of p ‐benzoquinone: Electron affinity and compound states Cooper, C. D.; Naff, W. T.; Compton, R. N. The Journal of Chemical Physics, Vol. 63, Issue 6 https://doi.org/10.1063/1.431627	journal	September 1975
Role of Water in Methanol Photochemistry on Rutile TiO ₂ (110) Shen, Mingmin; Henderson, Michael A. The Journal of Physical Chemistry C, Vol. 116, Issue 35 https://doi.org/10.1021/jp3046774	journal	August 2012
Phenol destruction by photocatalysis on TiO2: an attempt to solve the reaction mechanism Sobczyński, Andrzej; Duczmal, Łukasz; Zmudziński, Wojciech Journal of Molecular Catalysis A: Chemical, Vol. 213, Issue 2 https://doi.org/10.1016/j.molcata.2003.12.006	journal	May 2004
Vibrational and electronic excitation in p-benzoquinone by electron impact Allan, Michael Chemical Physics, Vol. 84, Issue 2 https://doi.org/10.1016/0301-0104(84)85215-5	journal	February 1984
A surface science perspective on TiO2 photocatalysis Henderson, Michael A. Surface Science Reports, Vol. 66, Issue 6-7 https://doi.org/10.1016/j.surfrep.2011.01.001	journal	June 2011
Electron Traps and the Stark Effect on Hydroxylated Titania Photocatalysts Szczepankiewicz, Steven H.; Moss, John A.; Hoffmann, Michael R. The Journal of Physical Chemistry B, Vol. 106, Issue 31 https://doi.org/10.1021/jp020472v	journal	August 2002
Observation of two n-π singlet states in the single crystal absorption spectrum of p-benzoquinone and toluquinone Trommsdorff, H. P. Chemical Physics Letters, Vol. 10, Issue 2 https://doi.org/10.1016/0009-2614(71)80454-2	journal	July 1971
Role of Resonance Energy Transfer in Light Harvesting of Zinc Oxide-Based Dye-Sensitized Solar Cells Makhal, Abhinandan; Sarkar, Soumik; Bora, Tanujjal The Journal of Physical Chemistry C, Vol. 114, Issue 23 https://doi.org/10.1021/jp102042j	journal	May 2010
Electron attachment to p-benzoquinone and photodetachment from benzoquinone anion in nonpolar solvents Holroyd, R. A. The Journal of Physical Chemistry, Vol. 86, Issue 18 https://doi.org/10.1021/j100215a011	journal	September 1982
Benzene and toluene gas-phase photocatalytic degradation over H2O and HCL pretreated TiO2: by-products and mechanisms d'Hennezel, Olga; Pichat, Pierre; Ollis, David F. Journal of Photochemistry and Photobiology A: Chemistry, Vol. 118, Issue 3 https://doi.org/10.1016/S1010-6030(98)00366-9	journal	November 1998
Evidence for oxygen adatoms on TiO2(110) resulting from O2 dissociation at vacancy sites Epling, William S.; Peden, Charles H. F.; Henderson, Michael A. Surface Science, Vol. 412-413 https://doi.org/10.1016/S0039-6028(98)00446-4	journal	September 1998
Inter-relationship between Pt oxidation states on TiO2 and the photocatalytic mineralisation of organic matters Teoh, W.; Madler, L.; Amal, R. Journal of Catalysis, Vol. 251, Issue 2 https://doi.org/10.1016/j.jcat.2007.08.008	journal	October 2007
Influence of O2-induced surface roughening on the chemistry of water on TiO2(110) Zehr, R. T.; Henderson, M. A. Surface Science, Vol. 602, Issue 8 https://doi.org/10.1016/j.susc.2008.02.031	journal	April 2008
Excited and Ionized States of p -Benzoquinone and Its Anion Radical: SAC−CI Theoretical Study Honda, Yasushi; Hada, Masahiko; Ehara, Masahiro The Journal of Physical Chemistry A, Vol. 106, Issue 15 https://doi.org/10.1021/jp013166a	journal	April 2002
On the Electronic Structures and Electron Affinities of the m -Benzoquinone (BQ) Diradical and the o -, p -BQ Molecules: A Synergetic Photoelectron Spectroscopic and Theoretical Study Fu, Qiang; Yang, Jinlong; Wang, Xue-Bin The Journal of Physical Chemistry A, Vol. 115, Issue 15 https://doi.org/10.1021/jp1120542	journal	April 2011
The singlet nπ* states of para-benzoquinone Ter Horst, Gerard; Kommandeur, Jan Chemical Physics, Vol. 44, Issue 2 https://doi.org/10.1016/0301-0104(79)80126-3	journal	December 1979
Zeeman effect and singlet-triplet absorption spectrum of p-benzoquinone single crystals Trommsdorff, H. P. Chemical Physics Letters, Vol. 1, Issue 5 https://doi.org/10.1016/0009-2614(67)85053-X	journal	July 1967
Theoretical study of the electronic spectrum of p -benzoquinone Pou-Amérigo, Rosendo; Merchán, Manuela; Ortı́, Enrique The Journal of Chemical Physics, Vol. 110, Issue 19 https://doi.org/10.1063/1.478918	journal	May 1999
Characterization of the Active Surface Species Responsible for UV-Induced Desorption of O ₂ from the Rutile TiO ₂ (110) Surface Henderson, Michael A.; Shen, Mingmin; Wang, Zhi-Tao The Journal of Physical Chemistry C, Vol. 117, Issue 11 https://doi.org/10.1021/jp312161y	journal	March 2013
Reactions of p-Benzoquinone on TiO2(001) Single-Crystal Surfaces: Oligomerization and Polymerization by Reductive Coupling Idriss, H.; Barteau, M. A. Langmuir, Vol. 10, Issue 10 https://doi.org/10.1021/la00022a050	journal	October 1994
Insights into Photoexcited Electron Scavenging Processes on TiO ₂ Obtained from Studies of the Reaction of O ₂ with OH Groups Adsorbed at Electronic Defects on TiO ₂ (110) Henderson, Michael A.; Epling, William S.; Peden, Charles H. F. The Journal of Physical Chemistry B, Vol. 107, Issue 2 https://doi.org/10.1021/jp0262113	journal	January 2003
Synthesis of porous platinum-ion-doped titanium dioxide and the photocatalytic degradation of 4-chlorophenol under visible light irradiation Yamazaki, Suzuko; Fujiwara, Yuhei; Yabuno, Shinya Applied Catalysis B: Environmental, Vol. 121-122 https://doi.org/10.1016/j.apcatb.2012.03.026	journal	June 2012
The influence of crystallite size and crystallinity of anatase nanoparticles on the photo-degradation of phenol Wang, Xueqin; Sø, Lasse; Su, Ren Journal of Catalysis, Vol. 310 https://doi.org/10.1016/j.jcat.2013.04.022	journal	February 2014
Photoinduced reactivity of titanium dioxide Carp, O. Progress in Solid State Chemistry, Vol. 32, Issue 1-2 https://doi.org/10.1016/j.progsolidstchem.2004.08.001	journal	January 2004
Entropy changes and electron affinities from gas-phase electron-transfer equilibria: A- + B = A + B- Chowdhury, Swapan; Heinis, Thomas; Grimsrud, Eric P. The Journal of Physical Chemistry, Vol. 90, Issue 12 https://doi.org/10.1021/j100403a037	journal	June 1986
Photocatalytic activity and selectivity of titania colloids and particles prepared by the sol-gel technique: photooxidation of phenol and atrazine Pelizzetti, E.; Minero, C.; Borgarello, E. Langmuir, Vol. 9, Issue 11 https://doi.org/10.1021/la00035a043	journal	November 1993
Slow Surface Charge Trapping Kinetics on Irradiated TiO ₂ Szczepankiewicz, Steven H.; Moss, John A.; Hoffmann, Michael R. The Journal of Physical Chemistry B, Vol. 106, Issue 11 https://doi.org/10.1021/jp004244h	journal	March 2002
The surface science of titanium dioxide Diebold, Ulrike Surface Science Reports, Vol. 48, Issue 5-8 https://doi.org/10.1016/S0167-5729(02)00100-0	journal	January 2003
Remote Oxidation of Organic Compounds by UV-Irradiated TiO ₂ via the Gas Phase Tatsuma, Tetsu; Tachibana, Shin-ichiro; Fujishima, Akira The Journal of Physical Chemistry B, Vol. 105, Issue 29 https://doi.org/10.1021/jp011108j	journal	July 2001
Ce-doped TiO2 for photocatalytic degradation of chlorophenol Silva, Adrián M. T.; Silva, Cláudia G.; Dražić, Goran Catalysis Today, Vol. 144, Issue 1-2 https://doi.org/10.1016/j.cattod.2009.02.022	journal	June 2009

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