Generalizable, Electroless, Template-Assisted Synthesis and Electrocatalytic Mechanistic Understanding of Perovskite LaNiO3 Nanorods as Viable, Supportless Oxygen Evolution Reaction Catalysts in Alkaline Media

McBean, Coray L.; Liu, Haiqing; Scofield, Megan E.; Li, Luyao; Wang, Lei; Bernstein, Ashley; Wong, Stanislaus S.

doi:10.1021/acsami.7b06855

Title: Generalizable, Electroless, Template-Assisted Synthesis and Electrocatalytic Mechanistic Understanding of Perovskite LaNiO₃ Nanorods as Viable, Supportless Oxygen Evolution Reaction Catalysts in Alkaline Media

Journal Article · Mon Jul 17 00:00:00 EDT 2017 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.7b06855· OSTI ID:1371491

McBean, Coray L. ^[1]; Liu, Haiqing ^[1]; Scofield, Megan E. ^[1]; Li, Luyao ^[1];

^[1]; Bernstein, Ashley ^[1];

^[2]

Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400, United States
Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400, United States, Condensed Matter Physics and Materials Sciences Division, Brookhaven National Laboratory, Building 480, Upton, New York 11973, United States

We present that the oxygen evolution reaction (OER) is a key reaction for water electrolysis cells and air-powered battery applications. However, conventional metal oxide catalysts, used for high-performing OER, tend to incorporate comparatively expensive and less abundant precious metals such as Ru and Ir, and, moreover, suffer from poor stability. To attempt to mitigate for all of these issues, we have prepared one-dimensional (1D) OER-active perovskite nanorods using a unique, simple, generalizable, and robust method. Significantly, our work demonstrates the feasibility of a novel electroless, seedless, surfactant-free, wet solution-based protocol for fabricating “high aspect ratio” LaNiO₃ and LaMnO₃ nanostructures. As the main focus of our demonstration of principle, we prepared as-synthesized LaNiO₃ rods and correlated the various temperatures at which these materials were annealed with their resulting OER performance. In addition, we observed generally better OER performance for samples prepared with lower annealing temperatures. Specifically, when annealed at 600 °C, in the absence of a conventional conductive carbon support, our as-synthesized LaNiO₃ rods not only evinced (i) a reasonable level of activity toward OER but also displayed (ii) an improved stability, as demonstrated by chronoamperometric measurements, especially when compared with a control sample of commercially available (and more expensive) RuO₂.

View Journal Article

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1371491

Alternate ID(s):: OSTI ID: 1376134

Report Number(s):: BNL-114070-2017-JA

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 46 works

Citation information provided by
Web of Science

References (70)

Co3O4 nanocrystals on single-walled carbon nanotubes as a highly efficient oxygen-evolving catalyst Wu, Jian; Xue, Yan; Yan, Xin Nano Research, Vol. 5, Issue 8 https://doi.org/10.1007/s12274-012-0237-y	journal	July 2012
Silver decorated LaMnO3 nanorod/graphene composite electrocatalysts as reversible metal-air battery electrodes Hu, Jie; Liu, Qiunan; Shi, Lina Applied Surface Science, Vol. 402 https://doi.org/10.1016/j.apsusc.2017.01.060	journal	April 2017
Synthesis of nanocrystalline conducting composite oxides based on a non-ion selective combined complexing process for functional applications Zhou, Wei; Shao, Zongping; Jin, Wanqin Journal of Alloys and Compounds, Vol. 426, Issue 1-2 https://doi.org/10.1016/j.jallcom.2006.02.029	journal	December 2006
Thermodynamic explanation of the universal correlation between oxygen evolution activity and corrosion of oxide catalysts Binninger, Tobias; Mohamed, Rhiyaad; Waltar, Kay Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep12167	journal	July 2015
On Activity and Stability of Rhombohedral LaNiO3 Catalyst towards ORR and OER in Alkaline Electrolyte Sakthivel, M.; Bhandari, S.; Drillet, J. -F. ECS Electrochemistry Letters, Vol. 4, Issue 6 https://doi.org/10.1149/2.0081506eel	journal	January 2015
Highly Active, Nonprecious Metal Perovskite Electrocatalysts for Bifunctional Metal–Air Battery Electrodes Hardin, William G.; Slanac, Daniel A.; Wang, Xiqing The Journal of Physical Chemistry Letters, Vol. 4, Issue 8 https://doi.org/10.1021/jz400595z	journal	March 2013
Phase evolution of perovskite LaNiO ₃ nanofibers for supercapacitor application and p-type gas sensing properties of LaOCl–NiO composite nanofibers Hwang, Do Kyung; Kim, Soohyun; Lee, Jong-Heun J. Mater. Chem., Vol. 21, Issue 6 https://doi.org/10.1039/C0JM02256J	journal	January 2011
Highly Enhanced Electrocatalytic Oxygen Reduction Performance Observed in Bimetallic Palladium-Based Nanowires Prepared under Ambient, Surfactantless Conditions Koenigsmann, Christopher; Sutter, Eli; Chiesa, Thomas A. Nano Letters, Vol. 12, Issue 4, p. 2013-2020 https://doi.org/10.1021/nl300033e	journal	January 2012
Optical conductivity of ${LaNiO}_{3}$ : Coherent transport and correlation driven mass enhancement Ouellette, Daniel G.; Lee, SungBin; Son, Junwoo Physical Review B, Vol. 82, Issue 16 https://doi.org/10.1103/PhysRevB.82.165112	journal	October 2010
Oxygen deficiency, vacancy clustering and ionic transport in (La,Sr)CoO3−δ Tsipis, E. V.; Naumovich, E. N.; Patrakeev, M. V. Solid State Ionics, Vol. 192, Issue 1 https://doi.org/10.1016/j.ssi.2010.03.029	journal	June 2011
Oxygen vacancy induced metal-insulator transition in LaNiO3 Misra, Debolina; Kundu, Tarun Kumar The European Physical Journal B, Vol. 89, Issue 1 https://doi.org/10.1140/epjb/e2015-60714-0	journal	January 2016
Porous Perovskite LaNiO3 Nanocubes as Cathode Catalysts for Li-O2 Batteries with Low Charge Potential Zhang, Jian; Zhao, Yubao; Zhao, Xiao Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06005	journal	August 2014
Evidence of oxygen-vacancy-induced ferromagnetic order in single crystal Mn-doped SrTiO ₃ Middey, Srimanta; Meneghini, Carlo; Ray, Sugata Applied Physics Letters, Vol. 101, Issue 4 https://doi.org/10.1063/1.4738785	journal	July 2012
Rational design of the electrode morphology for oxygen evolution – enhancing the performance for catalytic water oxidation Zeradjanin, Aleksandar R.; Topalov, Angel A.; Van Overmeere, Quentin RSC Advances, Vol. 4, Issue 19 https://doi.org/10.1039/c3ra45998e	journal	January 2014
Pt nanoparticles residing in the pores of porous LaNiO3 nanocubes as high-efficiency electrocatalyst for direct methanol fuel cells Yu, Nan; Kuai, Long; Wang, Qing Nanoscale, Vol. 4, Issue 17 https://doi.org/10.1039/c2nr31055d	journal	January 2012
Investigation of a “Two‐State” Tafel Phenomenon for the Oxygen Evolution Reaction on an Amorphous Ni‐Co Alloy Lian, K. K.; Kirk, D. W.; Thorpe, S. J. Journal of The Electrochemical Society, Vol. 142, Issue 11 https://doi.org/10.1149/1.2048402	journal	November 1995
Epitaxial growth and surface metallic nature of LaNiO3 thin films Tsubouchi, K.; Ohkubo, I.; Kumigashira, H. Applied Physics Letters, Vol. 92, Issue 26 https://doi.org/10.1063/1.2955534	journal	June 2008
Design Insights for Tuning the Electrocatalytic Activity of Perovskite Oxides for the Oxygen Evolution Reaction Malkhandi, S.; Trinh, P.; Manohar, Aswin K. The Journal of Physical Chemistry C, Vol. 119, Issue 15 https://doi.org/10.1021/jp512722x	journal	April 2015
Enhanced Susceptibility in $L {NiO}_{3}$ Perovskites ( $L {= L a, P r, N d, N d}_{0.5} {Sm}_{0.5}$ ) Zhou, J. -S.; Goodenough, J. B.; Dabrowski, B. Physical Review Letters, Vol. 84, Issue 3 https://doi.org/10.1103/PhysRevLett.84.526	journal	January 2000
Electro-optics of perovskite solar cells Lin, Qianqian; Armin, Ardalan; Nagiri, Ravi Chandra Raju Nature Photonics, Vol. 9, Issue 2 https://doi.org/10.1038/nphoton.2014.284	journal	December 2014
One-dimensional nanostructures: fabrication, characterisation and applications Weber, Jessica; Singhal, Rahul; Zekri, Souhail International Materials Reviews, Vol. 53, Issue 4 https://doi.org/10.1179/174328008X348183	journal	July 2008
A New Family of Perovskite Catalysts for Oxygen-Evolution Reaction in Alkaline Media: BaNiO ₃ and BaNi _0.83 O _2.5 Lee, Jin Goo; Hwang, Jeemin; Hwang, Ho Jung Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.6b00036	journal	March 2016
Physicochemical and electrocatalytic properties of LaNiO3 prepared by a low-temperature route for anode application in alkaline water electrolysis Singh, R. N.; Jain, A. N.; Tiwari, S. K. Journal of Applied Electrochemistry, Vol. 25, Issue 12 https://doi.org/10.1007/BF00242541	journal	December 1995
Hollandite Structure K _{x ≈0.25} IrO ₂ Catalyst with Highly Efficient Oxygen Evolution Reaction Sun, Wei; Song, Ya; Gong, Xue-Qing ACS Applied Materials & Interfaces, Vol. 8, Issue 1 https://doi.org/10.1021/acsami.5b10159	journal	December 2015
Vacancy defects and monopole dynamics in oxygen-deficient pyrochlores Sala, G.; Gutmann, M. J.; Prabhakaran, D. Nature Materials, Vol. 13, Issue 5 https://doi.org/10.1038/nmat3924	journal	April 2014
Microstructures of lanthanum nickel oxide particles with crystal facets synthesized in molten chlorides Ueno, Shintaro; Sakamoto, Yasunao; Taguchi, Hiroya Journal of the Ceramic Society of Japan, Vol. 123, Issue 1437 https://doi.org/10.2109/jcersj2.123.351	journal	January 2015
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles Suntivich, J.; May, K. J.; Gasteiger, H. A. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1212858	journal	October 2011
Electrocatalytic Measurement Methodology of Oxide Catalysts Using a Thin-Film Rotating Disk Electrode Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki Journal of The Electrochemical Society, Vol. 157, Issue 8 https://doi.org/10.1149/1.3456630	journal	January 2010
High-performance non-spinel cobalt–manganese mixed oxide-based bifunctional electrocatalysts for rechargeable zinc–air batteries Liu, Xien; Park, Minjoon; Kim, Min Gyu Nano Energy, Vol. 20 https://doi.org/10.1016/j.nanoen.2015.11.030	journal	February 2016
Sodium hypochlorite and its use as an endodontic irrigant Clarkson, Roger M.; Moule, Alex J. Australian Dental Journal, Vol. 43, Issue 3 https://doi.org/10.1111/j.1834-7819.1998.tb00173.x	journal	August 1998
Effect of conductive LaNiO3 electrode on the structural and ferroelectric properties of Bi3.25La0.75Ti3O12 films Jain, M.; Kang, B. S.; Jia, Q. X. Applied Physics Letters, Vol. 89, Issue 24 https://doi.org/10.1063/1.2404949	journal	December 2006
Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst Yang, Hong Bin; Miao, Jianwei; Hung, Sung-Fu Science Advances, Vol. 2, Issue 4 https://doi.org/10.1126/sciadv.1501122	journal	April 2016
Transport properties and metal–insulator transition in oxygen deficient LaNiO ₃ : a density functional theory study Misra, D.; Kundu, T. K. Materials Research Express, Vol. 3, Issue 9 https://doi.org/10.1088/2053-1591/3/9/095701	journal	September 2016
Ultrathin Nanowires-A Materials Chemistry Perspective Cademartiri, Ludovico; Ozin, Geoffrey A. Advanced Materials, Vol. 21, Issue 9 https://doi.org/10.1002/adma.200801836	journal	March 2009
Ambient Surfactantless Synthesis, Growth Mechanism, and Size-Dependent Electrocatalytic Behavior of High-Quality, Single Crystalline Palladium Nanowires Koenigsmann, Christopher; Santulli, Alexander C.; Sutter, Eli ACS Nano, Vol. 5, Issue 9, p. 7471-7487 https://doi.org/10.1021/nn202434r	journal	September 2011
Growth of nanowires Wang, N.; Cai, Y.; Zhang, R. Q. Materials Science and Engineering: R: Reports, Vol. 60, Issue 1-6, p. 1-51 https://doi.org/10.1016/j.mser.2008.01.001	journal	March 2008
Synthesis, characterization and electrochemical performance of battery grade NiOOH Pan, J.; Sun, Y.; Wan, P. Electrochemistry Communications, Vol. 7, Issue 8 https://doi.org/10.1016/j.elecom.2005.05.004	journal	August 2005
Strongly coupled thermal and chemical expansion in the perovskite oxide system Sr(Ti,Fe)O _3−α Perry, Nicola H.; Kim, Jae Jin; Bishop, Sean R. Journal of Materials Chemistry A, Vol. 3, Issue 7 https://doi.org/10.1039/C4TA05247A	journal	January 2015
First-principles study of oxygen-deficient ${LaNiO}_{3}$ structures Malashevich, Andrei; Ismail-Beigi, Sohrab Physical Review B, Vol. 92, Issue 14 https://doi.org/10.1103/PhysRevB.92.144102	journal	October 2015
Insulating-layer formation of metallic LaNiO ₃ on Nb-doped SrTiO ₃ substrate Yoo, Hyang Keun; Chang, Young Jun; Moreschini, Luca Applied Physics Letters, Vol. 106, Issue 12 https://doi.org/10.1063/1.4916225	journal	March 2015
Oxygen Vacancy Enhanced Photocatalytic Activity of Pervoskite SrTiO ₃ Tan, Huaqiao; Zhao, Zhao; Zhu, Wan-bin ACS Applied Materials & Interfaces, Vol. 6, Issue 21 https://doi.org/10.1021/am5051907	journal	October 2014
Graphene-Co3O4 nanocomposite as electrocatalyst with high performance for oxygen evolution reaction Zhao, Yufei; Chen, Shuangqiang; Sun, Bing Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep07629	journal	January 2015
Electrocatalysts for oxygen evolution in advanced water electrolysis Balej, J. International Journal of Hydrogen Energy, Vol. 10, Issue 2 https://doi.org/10.1016/0360-3199(85)90041-2	journal	January 1985
Enhancing Bi-functional Electrocatalytic Activity of Perovskite by Temperature Shock: A Case Study of LaNiO _3−δ Zhou, Wei; Sunarso, Jaka The Journal of Physical Chemistry Letters, Vol. 4, Issue 17 https://doi.org/10.1021/jz401169n	journal	August 2013
Structural and dielectric properties of substituted barium titanate ceramics for capacitor applications Sharma, Preeti; Kumar, Parveen; Kundu, R. S. Ceramics International, Vol. 41, Issue 10 https://doi.org/10.1016/j.ceramint.2015.07.131	journal	December 2015
Pulsed laser deposition of epitaxial LaNiO3 thin films on buffered Si(100) Sánchez, F. Thin Solid Films, Vol. 384, Issue 2 https://doi.org/10.1016/S0040-6090(00)01876-9	journal	March 2001
Lanthanide Aluminates as Dielectrics for Non-Volatile Memory Applications: Material Aspects Adelmann, C.; Swerts, J.; Richard, O. Journal of The Electrochemical Society, Vol. 158, Issue 8 https://doi.org/10.1149/1.3596557	journal	January 2011
Effect of Crystallinity of β - and β _bc -Nickel Hydroxide Samples on Chemical Cycling Thimmasandra Narayan, Ramesh Indian Journal of Materials Science, Vol. 2015 https://doi.org/10.1155/2015/820193	journal	July 2015
Highly active Co-doped LaMnO 3 perovskite oxide and N-doped carbon nanotube hybrid bi-functional catalyst for rechargeable zinc–air batteries Lee, Dong Un; Park, Moon Gyu; Park, Hey Woong Electrochemistry Communications, Vol. 60 https://doi.org/10.1016/j.elecom.2015.08.001	journal	November 2015
One-Dimensional Nanostructures: Synthesis, Characterization, and Applications Xia, Y.; Yang, P.; Sun, Y. Advanced Materials, Vol. 15, Issue 5, p. 353-389 https://doi.org/10.1002/adma.200390087	journal	March 2003
Tuning the Electrocatalytic Activity of Perovskites through Active Site Variation and Support Interactions Hardin, William G.; Mefford, J. Tyler; Slanac, Daniel A. Chemistry of Materials, Vol. 26, Issue 11 https://doi.org/10.1021/cm403785q	journal	June 2014
Temperature-Dependent Polarization in Field-Effect Transport and Photovoltaic Measurements of Methylammonium Lead Iodide Labram, John G.; Fabini, Douglas H.; Perry, Erin E. The Journal of Physical Chemistry Letters, Vol. 6, Issue 18 https://doi.org/10.1021/acs.jpclett.5b01669	journal	August 2015
Integrating NiCo Alloys with Their Oxides as Efficient Bifunctional Cathode Catalysts for Rechargeable Zinc-Air Batteries Liu, Xien; Park, Minjoon; Kim, Min Gyu Angewandte Chemie International Edition, Vol. 54, Issue 33 https://doi.org/10.1002/anie.201503612	journal	June 2015
LaNiO3/NiO hollow nanofibers with mesoporous wall: a significant improvement in NiO electrodes for supercapacitors Hu, Liu; Deng, Yafeng; Liang, Kun Journal of Solid State Electrochemistry, Vol. 19, Issue 3 https://doi.org/10.1007/s10008-014-2641-6	journal	October 2014
The thermal transformation from lanthanum hydroxide to lanthanum hydroxide oxide Neumann, A.; Walter, D. Thermochimica Acta, Vol. 445, Issue 2 https://doi.org/10.1016/j.tca.2005.06.013	journal	June 2006
A Universal and Facile Way for the Development of Superior Bifunctional Electrocatalysts for Oxygen Reduction and Evolution Reactions Utilizing the Synergistic Effect Zhu, Yinlong; Su, Chao; Xu, Xiaomin Chemistry - A European Journal, Vol. 20, Issue 47 https://doi.org/10.1002/chem.201403192	journal	September 2014
Hollow spherical La0.8Sr0.2MnO3 perovskite oxide with enhanced catalytic activities for the oxygen reduction reaction Lu, Fanliang; Sui, Jing; Su, Jianmin Journal of Power Sources, Vol. 271 https://doi.org/10.1016/j.jpowsour.2014.07.160	journal	December 2014
Phase transition and thermal depolarization of double perovskite modified low sintering temperature PbTiO 3 piezoelectric ceramics Huang, Haining; An, Zhao; Huang, Pangfeng Journal of the European Ceramic Society, Vol. 36, Issue 3 https://doi.org/10.1016/j.jeurceramsoc.2015.11.014	journal	February 2016
Oxygen Evolution Reaction Electrocatalysis on Transition Metal Oxides and (Oxy)hydroxides: Activity Trends and Design Principles Burke, Michaela S.; Enman, Lisa J.; Batchellor, Adam S. Chemistry of Materials, Vol. 27, Issue 22 https://doi.org/10.1021/acs.chemmater.5b03148	journal	October 2015
Probing oxygen reduction and oxygen evolution reactions on bifunctional non-precious metal catalysts for metal–air batteries Thippani, Thirupathi; Mandal, Sudip; Wang, Guanxiong RSC Advances, Vol. 6, Issue 75 https://doi.org/10.1039/C6RA13414A	journal	January 2016
Ambient Synthesis of High-Quality Ruthenium Nanowires and the Morphology-Dependent Electrocatalytic Performance of Platinum-Decorated Ruthenium Nanowires and Nanoparticles in the Methanol Oxidation Reaction Koenigsmann, Christopher; Semple, Dara Bobb; Sutter, Eli ACS Applied Materials & Interfaces, Vol. 5, Issue 12 https://doi.org/10.1021/am4007462	journal	June 2013
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis Hong, Wesley T.; Risch, Marcel; Stoerzinger, Kelsey A. Energy & Environmental Science, Vol. 8, Issue 5 https://doi.org/10.1039/C4EE03869J	journal	January 2015
Pd-Pt Bimetallic Nanodendrites with High Activity for Oxygen Reduction Lim, B.; Jiang, M.; Camargo, P. H. C. Science, Vol. 324, Issue 5932, p. 1302-1305 https://doi.org/10.1126/science.1170377	journal	May 2009
Structural effects of LaNiO3 as electrocatalyst for the oxygen reduction reaction Retuerto, María; Pereira, Amaru González; Pérez-Alonso, Francisco J. Applied Catalysis B: Environmental, Vol. 203 https://doi.org/10.1016/j.apcatb.2016.10.016	journal	April 2017
In situ formation of oxygen vacancy in perovskite Sr0.95Ti0.8Nb0.1M0.1O3 (M = Mn, Cr) toward efficient carbon dioxide electrolysis Zhang, Jun; Xie, Kui; Wei, Haoshan Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep07082	journal	November 2014
Electronic and crystal structure of fully strained ${LaNiO}_{3}$ films Dobin, A. Yu.; Nikolaev, K. R.; Krivorotov, I. N. Physical Review B, Vol. 68, Issue 11 https://doi.org/10.1103/PhysRevB.68.113408	journal	September 2003
A Fundamental Relationship between Reaction Mechanism and Stability in Metal Oxide Catalysts for Oxygen Evolution Rong, Xi; Parolin, Jules; Kolpak, Alexie M. ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b02432	journal	January 2016
Characterization of Electrochemically Prepared γ‐NiOOH by XPS Mansour, A. N.; Melendres, C. A. Surface Science Spectra, Vol. 3, Issue 3 https://doi.org/10.1116/1.1247756	journal	July 1994
Structure and water oxidation activity of 3 d metal oxides: Structure and water oxidation activity Li, Ye-Fei; Liu, Zhi-Pan Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 6, Issue 1 https://doi.org/10.1002/wcms.1236	journal	December 2015
Lattice expansion upon reduction of perovskite-type LaMnO3 with oxygen-deficit nonstoichiometry Miyoshi, S. Solid State Ionics, Vol. 161, Issue 3-4 https://doi.org/10.1016/S0167-2738(03)00281-9	journal	August 2003

Similar Records

Tuning oxygen electrocatalysis via strain on LaNiO₃(001)

Journal Article · Mon Oct 15 00:00:00 EDT 2018 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1371491

Yuk, Simuck F.; Cooper, Valentino R.

Dynamic Lattice Oxygen Participation on Perovskite LaNiO₃ during Oxygen Evolution Reaction

Journal Article · Mon Jun 08 00:00:00 EDT 2020 · Journal of Physical Chemistry. C · OSTI ID:1371491

Liu, Jishan; Jia, Endong; Stoerzinger, Kelsey A.; +9 more

Tuning electrochemically driven surface transformation in atomically flat LaNiO₃ thin films for enhanced water electrolysis

Journal Article · Mon Jan 11 00:00:00 EST 2021 · Nature Materials · OSTI ID:1371491

Baeumer, Christoph; Li, Jiang; Lu, Qiyang; +16 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
catalysis
electrochemistry
oxygen evolution reaction
perovskite
template synthesis

Title: Generalizable, Electroless, Template-Assisted Synthesis and Electrocatalytic Mechanistic Understanding of Perovskite LaNiO3 Nanorods as Viable, Supportless Oxygen Evolution Reaction Catalysts in Alkaline Media

Citation Formats

References (70)

Similar Records

Related Subjects

Title: Generalizable, Electroless, Template-Assisted Synthesis and Electrocatalytic Mechanistic Understanding of Perovskite LaNiO₃ Nanorods as Viable, Supportless Oxygen Evolution Reaction Catalysts in Alkaline Media