Phosphonate-Derivatized Porphyrins for Photoelectrochemical Applications

Nayak, Animesh; Roy, Subhangi; Sherman, Benjamin D.; Alibabaei, Leila; Lapides, Alexander M.; Brennaman, M. Kyle; Wee, Kyung-Ryang; Meyer, Thomas J.

doi:10.1021/acsami.5b10587

Phosphonate-Derivatized Porphyrins for Photoelectrochemical Applications

Journal Article · Wed Jan 20 00:00:00 EST 2016 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.5b10587· OSTI ID:1371162

Nayak, Animesh ^[1]; Roy, Subhangi ^[1]; Sherman, Benjamin D. ^[1]; Alibabaei, Leila ^[1]; Lapides, Alexander M. ^[1]; Brennaman, M. Kyle ^[1]; Wee, Kyung-Ryang ^[1]; Meyer, Thomas J. ^[1]

Univ. of North Carolina, Chapel Hill, NC (United States)

A series of phosphonate-derivatized, high redox potential porphyrins with mesityl, pentafluorophenyl, and heptafluoropropyl meso-substituents were synthesized by acid-catalyzed condensation reactions. Ground and excited state redox potentials in the series were varied systematically with the electron-donating or electron-accepting nature of the meso-substitutents. Here, the extent of excitation and injection by porphyrin singlet excited states surface-bound to SnO₂/TiO₂ core/shell metal oxide nanoparticle films varies with the excited state reduction potential, E°'(P+/P*). Furthermore, with the mesityl-substituted porphyrin, high current density and sustained photocurrents are observed at pH 7 with the addition of the electron transfer donor hydroquinone.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Solar Fuels (UNC EFRC)

Sponsoring Organization:: Department of Defense (DoD); National Defense Science & Engineering Graduate Fellowship (NDSEG) Program; National Science Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0001011

OSTI ID:: 1371162

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 6 Vol. 8; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Phosphonate-Derivatized Porphyrins for Photoelectrochemical Applications

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