Quantum process tomography by 2D fluorescence spectroscopy

Pachón, Leonardo A.; Marcus, Andrew H.; Aspuru-Guzik, Alán

doi:10.1063/1.4919954

Quantum process tomography by 2D fluorescence spectroscopy

Journal Article · Mon May 18 00:00:00 EDT 2015 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4919954· OSTI ID:1370896

Pachón, Leonardo A. ^[1]; Marcus, Andrew H. ^[2]; ^[3]

Univ. de Antioquia UdeA, Medellín, (Colombia) Grupo de Física Atómica y Molecular, Inst. de Física, Facultad de Ciencias Exactas y Naturales; Harvard Univ., Cambridge, MA (United States). Dept. of Chemistry and Chemical Biology
Univ. of Oregon, Eugene, OR (United States). Dept. of Chemistry and Biochemistry, Oregon Center for Optics, and Inst. of Molecular Biology
Harvard Univ., Cambridge, MA (United States). Dept. of Chemistry and Chemical Biology

Reconstruction of the dynamics (quantum process tomography) of the single-exciton manifold in energy transfer systems is proposed here on the basis of two-dimensional fluorescence spectroscopy (2D-FS) with phase-modulation. The quantum-process-tomography protocol introduced here benefits from, e.g., the sensitivity enhancement ascribed to 2D-FS. Although the isotropically averaged spectroscopic signals depend on the quantum yield parameter Γ of the doubly excited-exciton manifold, it is shown that the reconstruction of the dynamics is insensitive to this parameter. Finally, applications to foundational and applied problems, as well as further extensions, are discussed.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC), Washington D.C. (United States). Center for Excitonics (CE)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0001088

OSTI ID:: 1370896

Alternate ID(s):: OSTI ID: 1228176
OSTI ID: 22415910

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 21 Vol. 142; ISSN JCPSA6; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Interplay between structural hierarchy and exciton diffusion in artificial light harvesting Kriete, Björn; Lüttig, Julian; Kunsel, Tenzin Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12345-9	journal	October 2019
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Secular vs. Non-secular Redfield Dynamics and Fano Coherences in Incoherent Excitation: An Experimental Proposal Dodin, Amro; Tscherbul, Timur; Alicki, Robert arXiv https://doi.org/10.48550/arxiv.1711.10074	text	January 2017

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Quantum process tomography by 2D fluorescence spectroscopy

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