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In Situ Analysis of Gas Generation in Lithium-Ion Batteries with Different Carbonate-Based Electrolytes

Journal Article · · ACS Applied Materials and Interfaces
 [1];  [2];  [1];  [2];  [1];  [3];  [3];  [1];  [2];  [2]
  1. Beijing Inst. of Technology, Beijing (China)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
  3. Beijing Inst. of Technology, Beijing (China); Collaborative Innovation Center of Electric Vehicles in Beijing (China)
+ Show Author Affiliations
Gas generation in lithium-ion batteries is one of the critical issues limiting their safety performance and lifetime. In this work, a set of 900 mAh pouch cells were applied to systematically compare the composition of gases generated from a serial of carbonate-based composite electrolytes, using a self-designed gas analyzing system. Here among electrolytes used in this work, the composite γ-butyrolactone/ethyl methyl carbonate (GBL/EMC) exhibited remarkably less gassing because of the electrochemical stability of the GBL, which makes it a promising electrolyte for battery with advanced safety and lifetime.
Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES)
Sponsoring Organization:
State Scholarship Fund of the China Scholarship Council; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1370834
Alternate ID(s):
OSTI ID: 1238784
Journal Information:
ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 41 Vol. 7; ISSN 1944-8244
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

References (22)

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Cited By (6)

In situ analytical techniques for battery interface analysis journal January 2018
Reductive reactions via excess Li in mixture electrolytes of Li ion batteries: an ab initio molecular dynamics study journal January 2019
A study on the interfacial stability of the cathode/polycarbonate interface: implication of overcharge and transition metal redox journal January 2018
Predicting adhesive sealing life of Li-ion pouch cell using a fusion method considering time-varying dependence journal December 2019
The Role of Electrolyte in the First-Cycle Transformations of LiNi 0.6 Mn 0.2 Co 0.2 O 2 journal January 2019
In Situ Stress Measurement Techniques on Li-ion Battery Electrodes: A Review journal April 2017

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Related Subjects

25 ENERGY STORAGE
batteries
carbonate electrolytes
charge transport
density function theory
electrochemical cells
electrolytes
energy storage (including batteries and capacitors)
gas generation
inorganic carbon compounds
lithium ion battery
materials and chemistry by design
organic reactions
pouch cells
synthesis (novel materials)