Chemically Crushed Wood Cellulose Fiber towards High-Performance Sodium-Ion Batteries

Shen, Fei; Zhu, Hongli; Luo, Wei; Wan, Jiayu; Zhou, Lihui; Dai, Jiaqi; Zhao, Bin; Han, Xiaogang; Fu, Kun; Hu, Liangbing

doi:10.1021/acsami.5b07583

Chemically Crushed Wood Cellulose Fiber towards High-Performance Sodium-Ion Batteries

Journal Article · Mon Oct 05 00:00:00 EDT 2015 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.5b07583· OSTI ID:1370727

Shen, Fei ^[1]; Zhu, Hongli ^[1]; Luo, Wei ^[1]; Wan, Jiayu ^[1]; Zhou, Lihui ^[1]; Dai, Jiaqi ^[1]; Zhao, Bin ^[1]; Han, Xiaogang ^[1]; Fu, Kun ^[1]; Hu, Liangbing ^[1]

Univ. of Maryland, College Park, MD (United States)

Carbon materials have attracted great interest as an anode for sodium-ion batteries (SIBs) due to their high performance and low cost. Furthermore, we studied natural wood fiber derived hard carbon anodes for SIBs considering the abundance and low cost of wood. We discovered that a thermal carbonization of wood fiber led to a porous carbon with a high specific surface area of 586 m² g^–1, while a pretreatment with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) could effectively decrease it to 126 m² g^–1. When evaluating them as anodes for SIBs, we observed that the low surface area carbon resulted in a high initial Coulombic efficiency of 72% compared to 25% of the high surface area carbon. More importantly, the low surface area carbon exhibits an excellent cycling stability that a desodiation capacity of 196 mAh g^–1 can be delivered over 200 cycles at a current density of 100 mA g^–1, indicating a promising anode for low-cost SIBs.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)

Sponsoring Organization:: Department of Defense (DOD); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0001160

OSTI ID:: 1370727

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 41 Vol. 7; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Chemically Crushed Wood Cellulose Fiber towards High-Performance Sodium-Ion Batteries

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