Tetraarylborate polymer networks as single-ion conducting solid electrolytes

Van Humbeck, Jeffrey F.; Aubrey, Michael L.; Alsbaiee, Alaaeddin; Ameloot, Rob; Coates, Geoffrey W.; Dichtel, William R.; Long, Jeffrey R.

doi:10.1039/c5sc02052b

Tetraarylborate polymer networks as single-ion conducting solid electrolytes

Journal Article · Thu Jan 01 04:00:00 EST 2015 · Chemical Science

DOI:https://doi.org/10.1039/c5sc02052b· OSTI ID:1370685

Van Humbeck, Jeffrey F. ^[1]; Aubrey, Michael L. ^[2]; Alsbaiee, Alaaeddin ^[3]; ^[4]; Coates, Geoffrey W. ^[3]; Dichtel, William R. ^[3]; Long, Jeffrey R. ^[5]

Department of Chemistry; Massachusetts Institute of Technology; Cambridge, USA 02139
Department of Chemistry; University of California; Berkeley, USA 94720-1462
Department of Chemistry and Chemical Biology; Baker Laboratory; Cornell University; Ithaca, USA 14853-1301
Centre for Surface Chemistry and Catalysis; University of Leuven; 3001 Leuven, Belgium
Department of Chemistry; University of California; Berkeley, USA 94720-1462; Division of Materials Sciences; Lawrence Berkeley National Laboratory

A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

DOE Contract Number:: SC0001015

OSTI ID:: 1370685

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 10 Vol. 6; ISSN 2041-6520

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (51)

Molecular Tectonics. Selective Exchange of Cations in Porous Anionic Hydrogen-Bonded Networks Built from Derivatives of Tetraphenylborate Malek, Nadia; Maris, Thierry; Simard, Michel Journal of the American Chemical Society, Vol. 127, Issue 16 https://doi.org/10.1021/ja042233m	journal	April 2005
A single-ion polymer electrolyte based on boronate for lithium ion batteries Zhu, Y. S.; Gao, X. W.; Wang, X. J. Electrochemistry Communications, Vol. 22 https://doi.org/10.1016/j.elecom.2012.05.022	journal	August 2012
An Anionic Microporous Polymer Network Prepared by the Polymerization of Weakly Coordinating Anions Fischer, Sabrina; Schmidt, Johannes; Strauch, Peter Angewandte Chemie International Edition, Vol. 52, Issue 46 https://doi.org/10.1002/anie.201303045	journal	October 2013
The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces Monroe, Charles; Newman, John Journal of The Electrochemical Society, Vol. 152, Issue 2 https://doi.org/10.1149/1.1850854	journal	January 2005
Electrochemical aspects of the generation of ramified metallic electrodeposits Chazalviel, J. -N. Physical Review A, Vol. 42, Issue 12 https://doi.org/10.1103/PhysRevA.42.7355	journal	December 1990
Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts Cheng, Fangyi; Chen, Jun Chemical Society Reviews, Vol. 41, Issue 6, p. 2172-2192 https://doi.org/10.1039/c1cs15228a	journal	January 2012
Influence of Solvating Plasticizer on Ion Conduction of Polysiloxane Single-Ion Conductors Choi, U. Hyeok; Liang, Siwei; O’Reilly, Michael V. Macromolecules, Vol. 47, Issue 9 https://doi.org/10.1021/ma500146v	journal	April 2014
Block copolymers in tomorrow's plastics Ruzette, Anne-Valérie; Leibler, Ludwik Nature Materials, Vol. 4, Issue 1 https://doi.org/10.1038/nmat1295	journal	January 2005
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
A new single-ion polymer electrolyte based on polyvinyl alcohol for lithium ion batteries Zhu, Y. S.; Wang, X. J.; Hou, Y. Y. Electrochimica Acta, Vol. 87 https://doi.org/10.1016/j.electacta.2012.08.114	journal	January 2013
Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brønsted Acid Groups Van Humbeck, Jeffrey F.; McDonald, Thomas M.; Jing, Xiaofei Journal of the American Chemical Society, Vol. 136, Issue 6, p. 2432-2440 https://doi.org/10.1021/ja4105478	journal	January 2014
Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries Padhi, A. K. Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194 https://doi.org/10.1149/1.1837571	journal	April 1997
Polymer Electrolytes Hallinan, Daniel T.; Balsara, Nitash P. Annual Review of Materials Research, Vol. 43, Issue 1 https://doi.org/10.1146/annurev-matsci-071312-121705	journal	July 2013
Review of gel-type polymer electrolytes for lithium-ion batteries Song, J. Y.; Wang, Y. Y.; Wan, C. C. Journal of Power Sources, Vol. 77, Issue 2, p. 183-197 https://doi.org/10.1016/S0378-7753(98)00193-1	journal	February 1999
Preparation of Potassium Alkynylaryltrifluoroborates from Haloaryltrifluoroborates via Sonogashira Coupling Reaction Kim, Dong-Su; Ham, Jungyeob Organic Letters, Vol. 12, Issue 5 https://doi.org/10.1021/ol100081v	journal	March 2010
Mechanical properties of metal-organic frameworks: An indentation study on epitaxial thin films Bundschuh, S.; Kraft, O.; Arslan, H. K. Applied Physics Letters, Vol. 101, Issue 10 https://doi.org/10.1063/1.4751286	journal	September 2012
Network formation mechanisms in conjugated microporous polymers Laybourn, Andrea; Dawson, Robert; Clowes, Rob Polym. Chem., Vol. 5, Issue 21 https://doi.org/10.1039/C4PY00647J	journal	January 2014
Microporous Poly(tri(4-ethynylphenyl)amine) Networks: Synthesis, Properties, and Atomistic Simulation Jiang, Jia-Xing; Trewin, Abbie; Su, Fabing Macromolecules, Vol. 42, Issue 7 https://doi.org/10.1021/ma802625d	journal	April 2009
Metal−Organic Frameworks Provide Large Negative Thermal Expansion Behavior Han, Sang Soo; Goddard, William A. The Journal of Physical Chemistry C, Vol. 111, Issue 42 https://doi.org/10.1021/jp075389s	journal	October 2007
Exploring polymeric lithium tartaric acid borate for thermally resistant polymer electrolyte of lithium batteries Wang, Xuejiang; Liu, Zhihong; Zhang, Chuanjian Electrochimica Acta, Vol. 92 https://doi.org/10.1016/j.electacta.2013.01.026	journal	March 2013
High Surface Area Networks from Tetrahedral Monomers: Metal-Catalyzed Coupling, Thermal Polymerization, and “Click” Chemistry Holst, James R.; Stöckel, Ev; Adams, Dave J. Macromolecules, Vol. 43, Issue 20 https://doi.org/10.1021/ma101677t	journal	October 2010
High surface area amorphous microporous poly(aryleneethynylene) networks using tetrahedral carbon- and silicon-centred monomers Stöckel, Ev; Wu, Xiaofeng; Trewin, Abbie Chemical Communications, Vol. 0, Issue 2, p. 212-214 https://doi.org/10.1039/B815044C	journal	January 2009
Conductivity and transference number measurements on polymer electrolytes Bruce, P. Solid State Ionics, Vol. 28-30 https://doi.org/10.1016/0167-2738(88)90304-9	journal	September 1988
Effects of Novel Boric Acid Esters on Ion Transport Properties of Lithium Salts in Nonaqueous Electrolyte Solutions and Polymer Electrolytes Tabata, Sei-ichiro; Hirakimoto, Takuro; Tokuda, Hiroyuki The Journal of Physical Chemistry B, Vol. 108, Issue 50 https://doi.org/10.1021/jp048370n	journal	December 2004
Synthesis and Characterization of Network Single Ion Conductors Based on Comb-Branched Polyepoxide Ethers and Lithium Bis(allylmalonato)borate Sun, Xiao-Guang; Kerr, John B. Macromolecules, Vol. 39, Issue 1 https://doi.org/10.1021/ma0507701	journal	January 2006
Recent findings and prospects in the field of pure metals as negative electrodes for Li-ion batteries Larcher, Dominique; Beattie, Shane; Morcrette, Mathieu Journal of Materials Chemistry, Vol. 17, Issue 36 https://doi.org/10.1039/b705421c	journal	January 2007
Synthesis and Characterization of Network Type Single Ion Conductors Sun, Xiao-Guang; Reeder, Craig L.; Kerr, John B. Macromolecules, Vol. 37, Issue 6 https://doi.org/10.1021/ma035690g	journal	March 2004
Differences between polymer/salt and single ion conductor solid polymer electrolytes Lin, Kan-Ju; Li, Katherine; Maranas, Janna K. RSC Adv., Vol. 3, Issue 5 https://doi.org/10.1039/C2RA21644B	journal	January 2013
Local and overall ionic conductivity in nanocrystalline CaF2 Puin, W. Solid State Ionics, Vol. 131, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00630-5	journal	June 2000
Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage/Separation Lu, Weigang; Yuan, Daqiang; Zhao, Dan Chemistry of Materials, Vol. 22, Issue 21, p. 5964-5972 https://doi.org/10.1021/cm1021068	journal	November 2010
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Onset of dendritic growth in lithium/polymer cells Rosso, M.; Gobron, T.; Brissot, C. Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00734-0	journal	July 2001
Review on gel polymer electrolytes for lithium batteries Manuel Stephan, A. European Polymer Journal, Vol. 42, Issue 1 https://doi.org/10.1016/j.eurpolymj.2005.09.017	journal	January 2006
Lithium Electrode Morphology during Cycling in Lithium Cells Yoshimatsu, Isamu Journal of The Electrochemical Society, Vol. 135, Issue 10 https://doi.org/10.1149/1.2095351	journal	January 1988
Pentafluorophenylboranes: from obscurity to applications Piers, Warren E.; Chivers, Tristram Chemical Society Reviews, Vol. 26, Issue 5 https://doi.org/10.1039/cs9972600345	journal	January 1997
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions Cabana, Jordi; Monconduit, Laure; Larcher, Dominique Advanced Materials, Vol. 22, Issue 35 https://doi.org/10.1002/adma.201000717	journal	August 2010
A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids Kinzel, Tom; Zhang, Yong; Buchwald, Stephen L. Journal of the American Chemical Society, Vol. 132, Issue 40, p. 14073-14075 https://doi.org/10.1021/ja1073799	journal	October 2010
Safety and reliability considerations for lithium batteries Levy, Samuel C. Journal of Power Sources, Vol. 68, Issue 1 https://doi.org/10.1016/S0378-7753(96)02622-5	journal	September 1997
Nanoionics: ion transport and electrochemical storage in confined systems Maier, J. Nature Materials, Vol. 4, Issue 11, p. 805-815 https://doi.org/10.1038/nmat1513	journal	November 2005
Ceramic and polymeric solid electrolytes for lithium-ion batteries Fergus, Jeffrey W. Journal of Power Sources, Vol. 195, Issue 15, p. 4554-4569 https://doi.org/10.1016/j.jpowsour.2010.01.076	journal	August 2010
Functional Materials for Rechargeable Batteries Cheng, Fangyi; Liang, Jing; Tao, Zhanliang Advanced Materials, Vol. 23, Issue 15 https://doi.org/10.1002/adma.201003587	journal	March 2011
Li-alloy based anode materials for Li secondary batteries Park, Cheol-Min; Kim, Jae-Hun; Kim, Hansu Chemical Society Reviews, Vol. 39, Issue 8, p. 3115-3141 https://doi.org/10.1039/b919877f	journal	January 2010
Resolution of the Modulus versus Adhesion Dilemma in Solid Polymer Electrolytes for Rechargeable Lithium Metal Batteries Stone, G. M.; Mullin, S. A.; Teran, A. A. Journal of The Electrochemical Society, Vol. 159, Issue 3 https://doi.org/10.1149/2.030203jes	journal	January 2012
Suppression of Lithium Dendrite Growth Using Cross-Linked Polyethylene/Poly(ethylene oxide) Electrolytes: A New Approach for Practical Lithium-Metal Polymer Batteries Khurana, Rachna; Schaefer, Jennifer L.; Archer, Lynden A. Journal of the American Chemical Society, Vol. 136, Issue 20 https://doi.org/10.1021/ja502133j	journal	May 2014
A porous diamond carbon framework: a new carbon allotrope with extremely high gas adsorption and mechanical properties Huang, Ling; Xiang, Zhonghua; Cao, Dapeng Journal of Materials Chemistry A, Vol. 1, Issue 12 https://doi.org/10.1039/c3ta10292k	journal	January 2013
Synthesis and Lithium Ion Conduction of Polysiloxane Single-Ion Conductors Containing Novel Weak-Binding Borates Liang, Siwei; Choi, U. Hyeok; Liu, Wenjuan Chemistry of Materials, Vol. 24, Issue 12 https://doi.org/10.1021/cm3005387	journal	June 2012
Novel Polyanionic Solid Electrolytes with Weak Coulomb Traps and Controllable Caps and Spacers Xu, Wu; Williams, Michael D.; Angell, C. Austen Chemistry of Materials, Vol. 14, Issue 1 https://doi.org/10.1021/cm010699n	journal	January 2002
Review on composite polymer electrolytes for lithium batteries Manuel Stephan, A.; Nahm, K. S. Polymer, Vol. 47, Issue 16 https://doi.org/10.1016/j.polymer.2006.05.069	journal	July 2006
Thermodynamic analysis on energy densities of batteries Zu, Chen-Xi; Li, Hong Energy & Environmental Science, Vol. 4, Issue 8 https://doi.org/10.1039/c0ee00777c	journal	January 2011
Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries Arora, Pankaj; White, Ralph E.; Doyle, Marc Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667 https://doi.org/10.1149/1.1838857	journal	January 1998
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001

Cited By (20)

Synthesis of tetraarylborates via tetralithio intermediates and the effect of polar functional groups and cations on their crystal structures Tomaszewski, Patryk; Wiszniewski, Marcin; Serwatowski, Janusz Dalton Transactions, Vol. 47, Issue 46 https://doi.org/10.1039/c8dt04068k	journal	January 2018
An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors Stassen, Ivo; Burtch, Nicholas; Talin, Alec Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/c7cs00122c	journal	January 2017
Ion Transport in Solvent-Free, Crosslinked, Single-Ion Conducting Polymer Electrolytes for Post-Lithium Ion Batteries Elmore, Clay; Seidler, Morgan; Ford, Hunter Batteries, Vol. 4, Issue 2 https://doi.org/10.3390/batteries4020028	journal	June 2018
A Metal–Organic Framework with Tetrahedral Aluminate Sites as a Single‐Ion Li ⁺ Solid Electrolyte Fischer, Sabrina; Roeser, Jérôme; Lin, Terri C. Angewandte Chemie International Edition, Vol. 57, Issue 51 https://doi.org/10.1002/anie.201808885	journal	December 2018
Metal- and covalent-organic frameworks as solid-state electrolytes for metal-ion batteries Miner, Elise M.; Dincă, Mircea Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2149 https://doi.org/10.1098/rsta.2018.0225	journal	July 2019
A Metal–Organic Framework with Tetrahedral Aluminate Sites as a Single‐Ion Li ⁺ Solid Electrolyte Fischer, Sabrina; Roeser, Jérôme; Lin, Terri C. Angewandte Chemie, Vol. 130, Issue 51 https://doi.org/10.1002/ange.201808885	journal	December 2018
Engineered Transport in Microporous Materials and Membranes for Clean Energy Technologies Li, Changyi; Meckler, Stephen M.; Smith, Zachary P. Advanced Materials, Vol. 30, Issue 8 https://doi.org/10.1002/adma.201704953	journal	January 2018
Efficient alkaloid capture from water using a charged porous organic polymer Zhang, Qing-Mei; Wang, Zhen; Cheng, Guang RSC Advances, Vol. 8, Issue 58 https://doi.org/10.1039/c8ra06499g	journal	January 2018
Block copolymers for supercapacitors, dielectric capacitors and batteries Liu, Tianyu; Liu, Guoliang Journal of Physics: Condensed Matter, Vol. 31, Issue 23 https://doi.org/10.1088/1361-648x/ab0d77	journal	March 2019
Ionic Covalent Organic Frameworks with Spiroborate Linkage Du, Ya; Yang, Haishen; Whiteley, Justin Michael Angewandte Chemie International Edition, Vol. 55, Issue 5 https://doi.org/10.1002/anie.201509014	journal	December 2015
A Single‐Ion Conducting Borate Network Polymer as a Viable Quasi‐Solid Electrolyte for Lithium Metal Batteries Shin, Dong‐Myeong; Bachman, Jonathan E.; Taylor, Mercedes K. Advanced Materials, Vol. 32, Issue 10 https://doi.org/10.1002/adma.201905771	journal	January 2020
Insight into fast ion migration kinetics of a new hybrid single Li-ion conductor based on aluminate complexes for solid-state Li-ion batteries Feng, Yancong; Tan, Rui; Zhao, Yan Nanoscale, Vol. 10, Issue 13 https://doi.org/10.1039/c8nr00573g	journal	January 2018
Ionic Covalent Organic Frameworks with Spiroborate Linkage Du, Ya; Yang, Haishen; Whiteley, Justin Michael Angewandte Chemie, Vol. 128, Issue 5 https://doi.org/10.1002/ange.201509014	journal	December 2015
Nanoporous ionic organic networks: from synthesis to materials applications Sun, Jian-Ke; Antonietti, Markus; Yuan, Jiayin Chemical Society Reviews, Vol. 45, Issue 23 https://doi.org/10.1039/c6cs00597g	journal	January 2016
Revisiting polymeric single lithium-ion conductors as an organic route for all-solid-state lithium ion and metal batteries Jeong, Kihun; Park, Sodam; Lee, Sang-Young Journal of Materials Chemistry A, Vol. 7, Issue 5 https://doi.org/10.1039/c8ta09056d	journal	January 2019
A promising bulky anion based lithium borate salt for lithium metal batteries Qiao, Lixin; Cui, Zili; Chen, Bingbing Chemical Science, Vol. 9, Issue 14 https://doi.org/10.1039/c8sc00041g	journal	January 2018
Anionic porous polymers with tunable structures and catalytic properties Zhao, Wuxue; Zhang, Fan; Yang, Lingyun Journal of Materials Chemistry A, Vol. 4, Issue 39 https://doi.org/10.1039/c6ta04917f	journal	January 2016
Trends and challenges for microporous polymers Chaoui, Nicolas; Trunk, Matthias; Dawson, Robert Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/c7cs00071e	journal	January 2017
A pre-synthetic strategy to construct single ion conductive covalent organic frameworks Li, Juan; Zhang, Fu-Qiang; Li, Falian Chemical Communications, Vol. 56, Issue 18 https://doi.org/10.1039/d0cc00454e	journal	January 2020
Ionic Porous Organic Polymers Based on Functionalized Tetraarylborates Tomaszewski, Patryk; Wiszniewski, Marcin; Gontarczyk, Krzysztof Polymers, Vol. 11, Issue 6 https://doi.org/10.3390/polym11061070	journal	June 2019

Similar Records

Tetraarylborate polymer networks as single-ion conducting solid electrolytes

Journal Article · Wed Dec 31 23:00:00 EST 2014 · Chemical Science · OSTI ID:1386094

Tetraarylborate polymer networks as single-ion conducting solid electrolytes

Journal Article · Sun Sep 13 20:00:00 EDT 2015 · Chemical Science · OSTI ID:1771814

Related Subjects

membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)

Tetraarylborate polymer networks as single-ion conducting solid electrolytes

Citation Formats

References (51)

Cited By (20)

Similar Records

Related Subjects