Densities and excess molar volumes of binary mixtures containing propylene carbonate + chlorohydrocarbons at 298.15 K and atmospheric pressure
- Centro di Studio per la Fisica delle Macromolecule del CNR, Bologna (Italy)
- Univ. degli Studi, Bologna (Italy). Dipt. di Chemica
Densities and excess molar volumes, V{sub m}{sup E}, for binary mixtures containing propylene carbonate + 10 chlorohydrocarbons (dichloromethane, 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobuthane, 1,6-dichlorohexane, 1,10-dichlorodecane, 1,1,1-trichloroethane, 1,1,2,2-tetrachloroethane, trans-1,2-dichloroethene, and trichloroethene) have been measured at 298.15 K and at atmospheric pressure using an Anton Paar digital vibrating tube density meter. The results are fitted to the Redlich-Kister equation. The values of V{sub m}{sup E} for the mixtures containing dichloroalkanes show an increasing trend with the increase of the chain length and vary from a minimum of {minus}0.24 cm{sup 3}/mol for dichloromethane up to a maximum of +0.31 cm{sup 3}/mol for 1,10-dichlorodecane. The excess molar volumes for the other mixtures are negative over the entire range of composition. Results are qualitatively discussed in terms of molecular interactions.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 137002
- Journal Information:
- Journal of Chemical and Engineering Data, Journal Name: Journal of Chemical and Engineering Data Journal Issue: 6 Vol. 40; ISSN JCEAAX; ISSN 0021-9568
- Country of Publication:
- United States
- Language:
- English
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