Molecular characterization of organic content of soot along the centerline of a coflow diffusion flame

Cain, Jeremy; Laskin, Alexander; Kholghy, Mohammad Reza; Thomson, Murray J.; Wang, Hai

doi:10.1039/c4cp03330b

Title: Molecular characterization of organic content of soot along the centerline of a coflow diffusion flame

Journal Article · Wed Jan 01 00:00:00 EST 2014 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/c4cp03330b· OSTI ID:1369838

Cain, Jeremy ^[1]; Laskin, Alexander ^[2]; Kholghy, Mohammad Reza ^[3]; Thomson, Murray J. ^[3]; Wang, Hai ^[4]

University of Dayton Research Institute; Dayton, USA
William R. Wiley Environmental Molecular Sciences Laboratory; Pacific Northwest National Laboratory; Richland, USA
Department of Mechanical and Industrial Engineering; University of Toronto; Toronto, Canada
Department of Mechanical Engineering; Stanford University; Stanford, USA

HR-MS speciation of young soot produced in a coflow diffusion flame reveal an array of ‘aliphatic’ and ‘aromatic’ C_xH_yO_zconstituents.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Combustion Energy Frontier Research Center (CEFRC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001198

OSTI ID:: 1369838

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 16, Issue 47; Related Information: CEFRC partners with Princeton University (lead); Argonne National Laboratory; University of Connecticut; Cornell University; Massachusetts Institute of Technology; University of Minnesota; Sandia National Laboratories; University of Southern California; Stanford University; University of Wisconsin, Madison; ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (55)

A numerical and experimental study of soot formation in a laminar coflow diffusion flame of a Jet A-1 surrogate Saffaripour, M.; Kholghy, M.; Dworkin, S. B. Proceedings of the Combustion Institute, Vol. 34, Issue 1 https://doi.org/10.1016/j.proci.2012.06.176	journal	January 2013
Aliphatic C–H and oxygenated surface functional groups of diesel in-cylinder soot: Characterizations and impact on soot oxidation behavior Wang, Lin; Song, Chonglin; Song, Jinou Proceedings of the Combustion Institute, Vol. 34, Issue 2 https://doi.org/10.1016/j.proci.2012.07.052	journal	January 2013
Experimental investigation and detailed modeling of soot aggregate formation and size distribution in laminar coflow diffusion flames of Jet A-1, a synthetic kerosene, and n-decane Saffaripour, Meghdad; Veshkini, Armin; Kholghy, Mohammadreza Combustion and Flame, Vol. 161, Issue 3 https://doi.org/10.1016/j.combustflame.2013.10.016	journal	March 2014
FT-IR and 1H NMR characterization of the products of an ethylene inverse diffusion flame Santamaria, A.; Mondragon, F.; Molina, A. Combustion and Flame, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.combustflame.2006.04.008	journal	July 2006
Direct observation of the evolution of the soot carbonization process in an acetylene diffusion flame via real-time aerosol mass spectrometry Reilly, P. T. A.; Gieray, R. A.; Whitten, W. B. Combustion and Flame, Vol. 122, Issue 1-2 https://doi.org/10.1016/S0010-2180(00)00105-X	journal	July 2000
Higher-Order Mass Defect Analysis for Mass Spectra of Complex Organic Mixtures Roach, Patrick J.; Laskin, Julia; Laskin, Alexander Analytical Chemistry, Vol. 83, Issue 12 https://doi.org/10.1021/ac200654j	journal	June 2011
An Experimental Comparison of the Sooting Behavior of Synthetic Jet Fuels Saffaripour, Meghdad; Zabeti, Parham; Kholghy, Mohammadreza Energy & Fuels, Vol. 25, Issue 12 https://doi.org/10.1021/ef201219v	journal	December 2011
High-Resolution Desorption Electrospray Ionization Mass Spectrometry for Chemical Characterization of Organic Aerosols Laskin, Julia; Laskin, Alexander; Roach, Patrick J. Analytical Chemistry, Vol. 82, Issue 5 https://doi.org/10.1021/ac902801f	journal	March 2010
Imaging Nanocarbon Materials: Soot Particles in Flames are Not Structurally Homogeneous Schenk, Marina; Lieb, Sydnie; Vieker, Henning ChemPhysChem, Vol. 14, Issue 14 https://doi.org/10.1002/cphc.201300581	journal	August 2013
Average structural analysis of the extractable material of young soot gathered in an ethylene inverse diffusion flame Santamaría, Alexander; Mondragón, Fanor; Quiñónez, Wiston Fuel, Vol. 86, Issue 12-13 https://doi.org/10.1016/j.fuel.2006.12.002	journal	August 2007
Chemical and morphological characterization of soot and soot precursors generated in an inverse diffusion flame with aromatic and aliphatic fuels Santamaria, Alexander; Yang, Nancy; Eddings, Eric Combustion and Flame, Vol. 157, Issue 1 https://doi.org/10.1016/j.combustflame.2009.09.016	journal	January 2010
Numerical modelling of soot formation and oxidation in laminar coflow non-smoking and smoking ethylene diffusion flames Liu, Fengshan; Guo, Hongsheng; Smallwood, Gregory Combustion Theory and Modelling, Vol. 7, Issue 2 https://doi.org/10.1088/1364-7830/7/2/305	journal	June 2003
Chemical Characterization of Crude Petroleum Using Nanospray Desorption Electrospray Ionization Coupled with High-Resolution Mass Spectrometry Eckert, Peter A.; Roach, Patrick J.; Laskin, Alexander Analytical Chemistry, Vol. 84, Issue 3, p. 1517-1525 https://doi.org/10.1021/ac202801g	journal	January 2012
Organosulfates in Humic-like Substance Fraction Isolated from Aerosols at Seven Locations in East Asia: A Study by Ultra-High-Resolution Mass Spectrometry Lin, Peng; Yu, Jian Zhen; Engling, Guenter Environmental Science & Technology, Vol. 46, Issue 24 https://doi.org/10.1021/es303570v	journal	December 2012
Morphology of nascent soot in ethylene flames Schenk, Marina; Lieb, Sydnie; Vieker, Henning Proceedings of the Combustion Institute, Vol. 35, Issue 2 https://doi.org/10.1016/j.proci.2014.05.009	journal	January 2015
Formation mechanism for polycyclic aromatic hydrocarbons in methane flames Siegmann, K.; Sattler, K. The Journal of Chemical Physics, Vol. 112, Issue 2 https://doi.org/10.1063/1.480648	journal	January 2000
Nano organic carbon and soot in turbulent non-premixed ethylene flames D’Anna, Andrea; Commodo, Mario; Violi, Santo Proceedings of the Combustion Institute, Vol. 31, Issue 1 https://doi.org/10.1016/j.proci.2006.07.062	journal	January 2007
On evolution of particle size distribution functions of incipient soot in premixed ethylene–oxygen–argon flames Abid, Aamir D.; Heinz, Nicholas; Tolmachoff, Erik D. Combustion and Flame, Vol. 154, Issue 4 https://doi.org/10.1016/j.combustflame.2008.06.009	journal	September 2008
Evidence of aliphatics in nascent soot particles in premixed ethylene flames Cain, Jeremy P.; Camacho, Joaquin; Phares, Denis J. Proceedings of the Combustion Institute, Vol. 33, Issue 1 https://doi.org/10.1016/j.proci.2010.06.164	journal	January 2011
Soot formation in a laminar diffusion flame Kent, J. H.; Jander, H.; Wagner, H. Gg. Symposium (International) on Combustion, Vol. 18, Issue 1 https://doi.org/10.1016/S0082-0784(81)80116-6	journal	January 1981
Simultaneous measurements of soot volume fraction and particle size / microstructure in flames using a thermophoretic sampling technique Köylü, Ü. Ö.; McEnally, C. S.; Rosner, D. E. Combustion and Flame, Vol. 110, Issue 4 https://doi.org/10.1016/S0010-2180(97)00089-8	journal	September 1997
Chemical species associated with the early stage of soot growth in a laminar premixed ethylene–oxygen–argon flame Öktem, Berk; Tolocka, Michael P.; Zhao, Bin Combustion and Flame, Vol. 142, Issue 4 https://doi.org/10.1016/j.combustflame.2005.03.016	journal	September 2005
Quinoid redox cycling as a mechanism for sustained free radical generation by inhaled airborne particulate matter Squadrito, Giuseppe L.; Cueto, Rafael; Dellinger, Barry Free Radical Biology and Medicine, Vol. 31, Issue 9 https://doi.org/10.1016/S0891-5849(01)00703-1	journal	November 2001
Nanospray desorption electrospray ionization: an ambient method for liquid-extraction surface sampling in mass spectrometry Roach, Patrick J.; Laskin, Julia; Laskin, Alexander The Analyst, Vol. 135, Issue 9 https://doi.org/10.1039/c0an00312c	journal	January 2010
A comparative study of nanoparticles in premixed flames by scanning mobility particle sizer, small angle neutron scattering, and transmission electron microscopy Zhao, Bin; Uchikawa, Kei; Wang, Hai Proceedings of the Combustion Institute, Vol. 31, Issue 1 https://doi.org/10.1016/j.proci.2006.08.064	journal	January 2007
Formation of nascent soot and other condensed-phase materials in flames Wang, Hai Proceedings of the Combustion Institute, Vol. 33, Issue 1 https://doi.org/10.1016/j.proci.2010.09.009	journal	January 2011
The existence of young soot in the exhaust of inverse diffusion flames Blevins, Linda G.; Fletcher, Robert A.; Benner, Bruce A. Proceedings of the Combustion Institute, Vol. 29, Issue 2 https://doi.org/10.1016/S1540-7489(02)80283-8	journal	January 2002
Molecular Characterization of Organic Aerosols Using Nanospray-Desorption/Electrospray Ionization-Mass Spectrometry ^† Roach, Patrick J.; Laskin, Julia; Laskin, Alexander Analytical Chemistry, Vol. 82, Issue 19 https://doi.org/10.1021/ac101449p	journal	October 2010
Soot formation in combustion processes Glassman, Irvin Symposium (International) on Combustion, Vol. 22, Issue 1 https://doi.org/10.1016/S0082-0784(89)80036-0	journal	January 1989
Generation of CO and smoke during underventilated combustion Léonard, S.; Mulholland, G. W.; Puri, R. Combustion and Flame, Vol. 98, Issue 1-2 https://doi.org/10.1016/0010-2180(94)90195-3	journal	July 1994
Computational and experimental study of soot formation in a coflow, laminar diffusion flame Smooke, M.; Mcenally, C.; Pfefferle, L. Combustion and Flame, Vol. 117, Issue 1-2 https://doi.org/10.1016/S0010-2180(98)00096-0	journal	April 1999
The evolution of soot morphology in a laminar coflow diffusion flame of a surrogate for Jet A-1 Kholghy, Mohammadreza; Saffaripour, Meghdad; Yip, Christopher Combustion and Flame, Vol. 160, Issue 10 https://doi.org/10.1016/j.combustflame.2013.04.008	journal	October 2013
Near-threshold photoionization mass spectra of combustion-generated high-molecular-weight soot precursors Skeen, Scott A.; Michelsen, Hope A.; Wilson, Kevin R. Journal of Aerosol Science, Vol. 58 https://doi.org/10.1016/j.jaerosci.2012.12.008	journal	April 2013
Formation and stabilization of persistent free radicals Dellinger, Barry; Lomnicki, Slawomir; Khachatryan, Lavrent Proceedings of the Combustion Institute, Vol. 31, Issue 1 https://doi.org/10.1016/j.proci.2006.07.172	journal	January 2007
Sooting Structure in a Laminar Diffusion Flame Haynes, B. S.; Wagner, H. Gg. Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 84, Issue 5 https://doi.org/10.1002/bbpc.19800840514	journal	May 1980
Micro-FTIR study of soot chemical composition—evidence of aliphatic hydrocarbons on nascent soot surfaces Cain, Jeremy P.; Gassman, Paul L.; Wang, Hai Physical Chemistry Chemical Physics, Vol. 12, Issue 20 https://doi.org/10.1039/b924344e	journal	January 2010
High-temperature stabilities of hydrocarbons Stein, Stephen E.; Fahr, A. The Journal of Physical Chemistry, Vol. 89, Issue 17 https://doi.org/10.1021/j100263a027	journal	August 1985
Soot particle measurements in diffusion flames Santoro, R. J.; Semerjian, H. G.; Dobbins, R. A. Combustion and Flame, Vol. 51 https://doi.org/10.1016/0010-2180(83)90099-8	journal	January 1983
The evolution of soot precursor particles in a diffusion flame Dobbins, R. A.; Fletcher, R. A.; Chang, H. -C. Combustion and Flame, Vol. 115, Issue 3 https://doi.org/10.1016/S0010-2180(98)00010-8	journal	November 1998
Detailed modeling of soot particle nucleation and growth Frenklach, Michael; Wang, Hai Symposium (International) on Combustion, Vol. 23, Issue 1 https://doi.org/10.1016/S0082-0784(06)80426-1	journal	January 1991
Application of an enhanced PAH growth model to soot formation in a laminar coflow ethylene/air diffusion flame Dworkin, Seth B.; Zhang, Qingan; Thomson, Murray J. Combustion and Flame, Vol. 158, Issue 9 https://doi.org/10.1016/j.combustflame.2011.01.013	journal	September 2011
Computational and experimental study of soot formation in a coflow, laminar ethylene diffusion flame McEnally, C. S.; Schaffer, A. M.; Long, M. B. Symposium (International) on Combustion, Vol. 27, Issue 1 https://doi.org/10.1016/S0082-0784(98)80557-2	journal	January 1998
Nano-organic carbon and soot particle measurements in a laminar ethylene diffusion flame D’Anna, A.; Rolando, A.; Allouis, C. Proceedings of the Combustion Institute, Vol. 30, Issue 1 https://doi.org/10.1016/j.proci.2004.08.276	journal	January 2005
Elemental Carbon-Based Method for Monitoring Occupational Exposures to Particulate Diesel Exhaust Birch, M. E.; Cary, R. A. Aerosol Science and Technology, Vol. 25, Issue 3 https://doi.org/10.1080/02786829608965393	journal	January 1996
Characterization of flame-generated C10 to C160 polycyclic aromatic hydrocarbons by atmospheric-pressure chemical ionization mass spectrometry with liquid introduction via heated nebulizer interface Lafleur, Arthur L.; Taghizadeh, Koli; Howard, Jack B. Journal of the American Society for Mass Spectrometry, Vol. 7, Issue 3 https://doi.org/10.1016/1044-0305(95)00651-6	journal	March 1996
Weakly Bound Carbon−Carbon Bonds in Acenaphthene Derivatives and Hexaphenylethane Dames, Enoch; Sirjean, Baptiste; Wang, Hai The Journal of Physical Chemistry A, Vol. 114, Issue 2 https://doi.org/10.1021/jp909662m	journal	January 2010
Laser microprobe analysis of soot precursor particles and carbonaceous soot Dobbins, R. A.; Fletcher, R. A.; Lu, W. Combustion and Flame, Vol. 100, Issue 1-2 https://doi.org/10.1016/0010-2180(94)00047-V	journal	January 1995
Mass Spectrometry of Particles Formed in a Deuterated Ethene Diffusion Flame Fletcher, R. A.; Dobbins, R. A.; Chang, H. -C. Analytical Chemistry, Vol. 70, Issue 13 https://doi.org/10.1021/ac971293q	journal	July 1998
Reactive Dimerization: A New PAH Growth Mechanism in Flames Siegmann, K.; Hepp, H.; Sattler, K. Combustion Science and Technology, Vol. 109, Issue 1-6 https://doi.org/10.1080/00102209508951900	journal	November 1995
Hydrocarbon Nanoparticles Formed in Flames and Diesel Engines Dobbins, Richard A. Aerosol Science and Technology, Vol. 41, Issue 5 https://doi.org/10.1080/02786820701225820	journal	April 2007
Detailed modeling of soot formation in laminar premixed ethylene flames at a pressure of 10 bar Kazakov, Andrei; Wang, Hai; Frenklach, Michael Combustion and Flame, Vol. 100, Issue 1-2 https://doi.org/10.1016/0010-2180(94)00086-8	journal	January 1995
Compositional Space Boundaries for Organic Compounds Lobodin, Vladislav V.; Marshall, Alan G.; Hsu, Chang Samuel Analytical Chemistry, Vol. 84, Issue 7 https://doi.org/10.1021/ac300244f	journal	March 2012
Soot measurements in laminar ethylene diffusion flames Kent, J. H.; Wagner, H. Gg. Combustion and Flame, Vol. 47 https://doi.org/10.1016/0010-2180(82)90088-8	journal	January 1982
A study of the effects of the ester moiety on soot formation and species concentrations in a laminar coflow diffusion flame of a surrogate for B100 biodiesel Kholghy, Mohammad Reza; Weingarten, Jason; Thomson, Murray John Proceedings of the Combustion Institute, Vol. 35, Issue 1 https://doi.org/10.1016/j.proci.2014.07.019	journal	January 2015
Molecular chemistry of organic aerosols through the application of high resolution mass spectrometry Nizkorodov, Sergey A.; Laskin, Julia; Laskin, Alexander Physical Chemistry Chemical Physics, Vol. 13, Issue 9 https://doi.org/10.1039/c0cp02032j	journal	January 2011

Similar Records

Molecular Characterization of Organic Content of Soot along the Centerline of a Coflow Diffusion Flame

Journal Article · Wed Oct 29 00:00:00 EDT 2014 · Physical Chemistry Chemical Physics. PCCP, 16(47):25862 - 25875 · OSTI ID:1369838

Cain, Jeremy P.; Laskin, Alexander; Kholghy, Mohammad Reza; +2 more

A numerical study of soot aggregate formation in a laminar coflow diffusion flame

Journal Article · Sun Mar 15 00:00:00 EDT 2009 · Combustion and Flame · OSTI ID:1369838

Zhang, Q; Thomson, M J; Guo, H; +2 more

Detection of Aliphatically Bridged Multi-Core Polycyclic Aromatic Hydrocarbons in Sooting Flames with Atmospheric-Sampling High-Resolution Tandem Mass Spectrometry

Journal Article · Mon Nov 12 00:00:00 EST 2018 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory · OSTI ID:1369838

Adamson, B. D.; Skeen, S. A.; Ahmed, M.; +1 more

Title: Molecular characterization of organic content of soot along the centerline of a coflow diffusion flame

Citation Formats

References (55)

Similar Records

Related Subjects