The low salinity effect at high temperatures

Xie, Quan; Brady, Patrick V.; Pooryousefy, Ehsan; Zhou, Daiyu; Liu, Yongbing; Saeedi, Ali

doi:10.1016/j.fuel.2017.03.088

The low salinity effect at high temperatures

Journal Article · Wed Apr 05 00:00:00 EDT 2017 · Fuel

DOI:https://doi.org/10.1016/j.fuel.2017.03.088· OSTI ID:1369448

Xie, Quan ^[1]; Brady, Patrick V. ^[2]; Pooryousefy, Ehsan ^[3]; Zhou, Daiyu ^[4]; Liu, Yongbing ^[5]; Saeedi, Ali ^[3]

Curtin Univ., Western Australia (Australia); Southwest Petroleum Univ., Sichuan (China)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Curtin Univ., Western Australia (Australia)
PetroChina Tarim Oilfield Co., Xinjiang (China)
Southwest Petroleum Univ., Sichuan (China)

The mechanism(s) of low salinity water flooding (LSWF) must be better understood at high temperatures and pressures if the method is to be applied in high T/P kaolinite-bearing sandstone reservoirs. We measured contact angles between a sandstone and an oil (acid number, AN = 3.98 mg KOH/g, base number, BN = 1.3 mg KOH/g) from a reservoir in the Tarim Field in western China in the presence of various water chemistries. We examined the effect of aqueous ionic solutions (formation brine, 100X diluted formation brine, and softened water), temperature (60, 100 and 140 °C) and pressure (20, 30, 40, and 50 MPa) on the contact angle. We also measured the zeta potential of the oil/water and water/rock interfaces to calculate oil/brine/rock disjoining pressures. A surface complexation model was developed to interpret contact angle measurements and compared with DLVO theory predictions. Contact angles were greatest in formation water, followed by the softened water, and low salinity water at the same pressure and temperature. Contact angles increased slightly with temperature, whereas pressure had little effect. DLVO and surface complexation modelling predicted similar wettability trends and allow reasonably accurate interpretation of core-flood results. Water chemistry has a much larger impact on LSWF than reservoir temperature and pressure. As a result, low salinity water flooding should work in high temperature and high pressure kaolinite-bearing sandstone reservoirs.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1369448

Alternate ID(s):: OSTI ID: 1415659
OSTI ID: 1432215

Report Number(s):: SAND--2017-2399J; 651460

Journal Information:: Fuel, Journal Name: Fuel Journal Issue: C Vol. 200; ISSN 0016-2361

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Oil Contact Angles in a Water-Decane-Silicon Dioxide System: Effects of Surface Charge Xu, Shijing; Wang, Jingyao; Wu, Jiazhong Nanoscale Research Letters, Vol. 13, Issue 1 https://doi.org/10.1186/s11671-018-2521-6	journal	April 2018

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