Unraveling the Nature of Sites Active toward Hydrogen Peroxide Reduction in Fe-N-C Catalysts

Choi, Chang Hyuck; Choi, Won Seok; Kasian, Olga; Mechler, Anna K.; Sougrati, Moulay Tahar; Brüller, Sebastian; Strickland, Kara; Jia, Qingying; Mukerjee, Sanjeev; Mayrhofer, Karl J. J.; Jaouen, Frédéric

doi:10.1002/anie.201704356

Title: Unraveling the Nature of Sites Active toward Hydrogen Peroxide Reduction in Fe-N-C Catalysts

Journal Article · Fri Jun 23 00:00:00 EDT 2017 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201704356· OSTI ID:1369319

^[1]; Choi, Won Seok ^[2]; Kasian, Olga ^[2];

^[3];

^[4]; Brüller, Sebastian ^[4]; Strickland, Kara ^[5]; Jia, Qingying ^[6]; Mukerjee, Sanjeev ^[6];

^[7];

^[4]

School of Materials Science and Engineering, Gwangju Institute of Science and Technology, Gwangju 61005 Republic of Korea
Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Strasse 1 40237 Düsseldorf Germany
Université de Montpellier, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon 34095 Montpellier France, Max Planck Institute for Chemical Energy Conversion, Stiftstraße 34-36 45470 Mülheim a.d. Ruhr Germany
Université de Montpellier, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon 34095 Montpellier France
Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Strasse 1 40237 Düsseldorf Germany, Department of Chemistry and Chemical Biology, Northeastern University, Boston MA 02115 USA
Department of Chemistry and Chemical Biology, Northeastern University, Boston MA 02115 USA
Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Strasse 1 40237 Düsseldorf Germany, Helmholtz-Institute Erlangen-Nürnberg for Renewable Energy Forschungszentrum, Jülich Germany, Department of Chemical and Biological Engineering, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3 91058 Erlangen Germany

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0000459

OSTI ID:: 1369319

Alternate ID(s):: OSTI ID: 1369321

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Vol. 56 Journal Issue: 30; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: Germany

Language:: English

Citation Metrics:

Cited by: 165 works

Citation information provided by
Web of Science

References (38)

Ordered mesoporous porphyrinic carbons with very high electrocatalytic activity for the oxygen reduction reaction Cheon, Jae Yeong; Kim, Taeyoung; Choi, YongMan Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02715	journal	September 2013
Molecular Oxygen Reduction in PEM Fuel Cell Conditions: ToF-SIMS Analysis of Co-Based Electrocatalysts Lefèvre, M.; Dodelet, J. P.; Bertrand, P. The Journal of Physical Chemistry B, Vol. 109, Issue 35, p. 16718-16724 https://doi.org/10.1021/jp0529265	journal	September 2005
A mechanistic study of 4-aminoantipyrine and iron derived non-platinum group metal catalyst on the oxygen reduction reaction Robson, Michael H.; Serov, Alexey; Artyushkova, Kateryna Electrochimica Acta, Vol. 90, p. 656-665 https://doi.org/10.1016/j.electacta.2012.11.025	journal	February 2013
Stability of Fe-N-C Catalysts in Acidic Medium Studied by Operando Spectroscopy Choi, Chang Hyuck; Baldizzone, Claudio; Grote, Jan-Philipp Angewandte Chemie, Vol. 127, Issue 43 https://doi.org/10.1002/ange.201504903	journal	August 2015
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa Nature Materials, Vol. 14, Issue 9 https://doi.org/10.1038/nmat4367	journal	August 2015
Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron-Ligand Coordination Strength Tian, Juan; Morozan, Adina; Sougrati, Moulay Tahar Angewandte Chemie, Vol. 125, Issue 27 https://doi.org/10.1002/ange.201303025	journal	May 2013
Probing active sites in iron-based catalysts for oxygen electro-reduction: A temperature-dependent 57 Fe Mössbauer spectroscopy study Sougrati, Moulay Tahar; Goellner, Vincent; Schuppert, Anna K. Catalysis Today, Vol. 262 https://doi.org/10.1016/j.cattod.2015.10.017	journal	March 2016
A metal–organic framework-derived bifunctional oxygen electrocatalyst Xia, Bao Yu; Yan, Ya; Li, Nan Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.6	journal	January 2016
Minimizing Operando Demetallation of Fe-N-C Electrocatalysts in Acidic Medium Choi, Chang Hyuck; Baldizzone, Claudio; Polymeros, George ACS Catalysis, Vol. 6, Issue 5 https://doi.org/10.1021/acscatal.6b00643	journal	April 2016
Elucidating Oxygen Reduction Active Sites in Pyrolyzed Metal–Nitrogen Coordinated Non-Precious-Metal Electrocatalyst Systems Tylus, Urszula; Jia, Qingying; Strickland, Kara The Journal of Physical Chemistry C, Vol. 118, Issue 17 https://doi.org/10.1021/jp500781v	journal	April 2014
Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction Li, Jingkun; Ghoshal, Shraboni; Liang, Wentao Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE01160H	journal	January 2016
N-doped carbon nanomaterials are durable catalysts for oxygen reduction reaction in acidic fuel cells Shui, Jianglan; Wang, Min; Du, Feng Science Advances, Vol. 1, Issue 1 https://doi.org/10.1126/sciadv.1400129	journal	February 2015
Degradation by Hydrogen Peroxide of Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction Goellner, Vincent; Armel, Vanessa; Zitolo, Andrea Journal of The Electrochemical Society, Vol. 162, Issue 6 https://doi.org/10.1149/2.1091506jes	journal	January 2015
Activity Descriptor Identification for Oxygen Reduction on Nonprecious Electrocatalysts: Linking Surface Science to Coordination Chemistry Ramaswamy, Nagappan; Tylus, Urszula; Jia, Qingying Journal of the American Chemical Society, Vol. 135, Issue 41 https://doi.org/10.1021/ja405149m	journal	October 2013
On the Role of Metals in Nitrogen-Doped Carbon Electrocatalysts for Oxygen Reduction Masa, Justus; Xia, Wei; Muhler, Martin Angewandte Chemie International Edition, Vol. 54, Issue 35 https://doi.org/10.1002/anie.201500569	journal	July 2015
Correlations between Mass Activity and Physicochemical Properties of Fe/N/C Catalysts for the ORR in PEM Fuel Cell via ⁵⁷ Fe Mössbauer Spectroscopy and Other Techniques Kramm, Ulrike I.; Lefèvre, Michel; Larouche, Nicholas Journal of the American Chemical Society, Vol. 136, Issue 3 https://doi.org/10.1021/ja410076f	journal	January 2014
Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis Cui, Chunhua; Gan, Lin; Heggen, Marc Nature Materials, Vol. 12, Issue 8 https://doi.org/10.1038/nmat3668	journal	June 2013
A class of non-precious metal composite catalysts for fuel cells Bashyam, Rajesh; Zelenay, Piotr Nature, Vol. 443, Issue 7107 https://doi.org/10.1038/nature05118	journal	September 2006
Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination Strickland, Kara; Miner, Elise; Jia, Qingying Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8343	journal	June 2015
A dual-metal–organic-framework derived electrocatalyst for oxygen reduction Guan, Bu Yuan; Yu, Le; (David) Lou, Xiong Wen Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE02171A	journal	January 2016
An Fe–N–C hybrid electrocatalyst derived from a bimetal–organic framework for efficient oxygen reduction Liu, Teng; Zhao, Pingping; Hua, Xing Journal of Materials Chemistry A, Vol. 4, Issue 29 https://doi.org/10.1039/C6TA03265F	journal	January 2016
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt Wu, G.; More, K. L.; Johnston, C. M. Science, Vol. 332, Issue 6028, p. 443-447 https://doi.org/10.1126/science.1200832	journal	April 2011
Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron-Ligand Coordination Strength Tian, Juan; Morozan, Adina; Sougrati, Moulay Tahar Angewandte Chemie International Edition, Vol. 52, Issue 27 https://doi.org/10.1002/anie.201303025	journal	May 2013
Stability of Fe-N-C Catalysts in Acidic Medium Studied by Operando Spectroscopy Choi, Chang Hyuck; Baldizzone, Claudio; Grote, Jan-Philipp Angewandte Chemie International Edition, Vol. 54, Issue 43 https://doi.org/10.1002/anie.201504903	journal	August 2015
Bifunctional Oxygen Reduction Reaction Mechanism on Non-Platinum Catalysts Derived from Pyrolyzed Porphyrins Olson, Tim S.; Pylypenko, Svitlana; Fulghum, Julia E. Journal of The Electrochemical Society, Vol. 157, Issue 1 https://doi.org/10.1149/1.3248003	journal	January 2010
Identification of carbon-encapsulated iron nanoparticles as active species in non-precious metal oxygen reduction catalysts Varnell, Jason A.; Tse, Edmund C. M.; Schulz, Charles E. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12582	journal	August 2016
Chemistry of Multitudinous Active Sites for Oxygen Reduction Reaction in Transition Metal–Nitrogen–Carbon Electrocatalysts Artyushkova, Kateryna; Serov, Alexey; Rojas-Carbonell, Santiago The Journal of Physical Chemistry C, Vol. 119, Issue 46 https://doi.org/10.1021/acs.jpcc.5b07653	journal	November 2015
Quantifying the density and utilization of active sites in non-precious metal oxygen electroreduction catalysts Sahraie, Nastaran Ranjbar; Kramm, Ulrike I.; Steinberg, Julian Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9618	journal	October 2015
On an Easy Way To Prepare Metal–Nitrogen Doped Carbon with Exclusive Presence of MeN ₄ -type Sites Active for the ORR Kramm, Ulrike I.; Herrmann-Geppert, Iris; Behrends, Jan Journal of the American Chemical Society, Vol. 138, Issue 2 https://doi.org/10.1021/jacs.5b11015	journal	January 2016
Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1427	journal	August 2011
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric Science, Vol. 324, Issue 5923, p. 71-74 https://doi.org/10.1126/science.1170051	journal	April 2009
Is iron involved in the lack of stability of Fe/N/C electrocatalysts used to reduce oxygen at the cathode of PEM fuel cells? Zhang, Gaixia; Chenitz, Régis; Lefèvre, Michel Nano Energy, Vol. 29 https://doi.org/10.1016/j.nanoen.2016.02.038	journal	November 2016
Über die Rolle von Metallen in Elektrokatalysatoren auf Basis von stickstoffdotiertem Kohlenstoff für die Sauerstoffreduktion Masa, Justus; Xia, Wei; Muhler, Martin Angewandte Chemie, Vol. 127, Issue 35 https://doi.org/10.1002/ange.201500569	journal	July 2015
Mechanistic studies of oxygen reduction on Fe-PEI derived non-PGM electrocatalysts Serov, Alexey; Tylus, Urszula; Artyushkova, Kateryna Applied Catalysis B: Environmental, Vol. 150-151 https://doi.org/10.1016/j.apcatb.2013.12.009	journal	May 2014
Cross-Laboratory Experimental Study of Non-Noble-Metal Electrocatalysts for the Oxygen Reduction Reaction Jaouen, Frédéric; Herranz, Juan; Lefèvre, Michel ACS Applied Materials & Interfaces, Vol. 1, Issue 8, p. 1623-1639 https://doi.org/10.1021/am900219g	journal	July 2009
Determination of Iron Active Sites in Pyrolyzed Iron-Based Catalysts for the Oxygen Reduction Reaction Li, Wenmu; Wu, Jason; Higgins, Drew C. ACS Catalysis, Vol. 2, Issue 12 https://doi.org/10.1021/cs300579b	journal	November 2012
Experimental Observation of Redox-Induced Fe–N Switching Behavior as a Determinant Role for Oxygen Reduction Activity Jia, Qingying; Ramaswamy, Nagappan; Hafiz, Hasnain ACS Nano, Vol. 9, Issue 12 https://doi.org/10.1021/acsnano.5b05984	journal	October 2015
Mechanistic Discussion of the Oxygen Reduction Reaction at Nitrogen-Doped Carbon Nanotubes Wiggins-Camacho, Jaclyn D.; Stevenson, Keith J. The Journal of Physical Chemistry C, Vol. 115, Issue 40 https://doi.org/10.1021/jp205336w	journal	September 2011

Similar Records

Unraveling the Nature of Sites Active toward Hydrogen Peroxide Reduction in Fe-N-C Catalysts

Journal Article · Fri Jun 23 00:00:00 EDT 2017 · Angewandte Chemie (International Edition) · OSTI ID:1369319

Choi, Chang Hyuck; Choi, Won Seok; Kasian, Olga; +8 more

Unraveling the Nature of Sites Active toward Hydrogen Peroxide Reduction in Fe-N-C Catalysts

Journal Article · Fri Jun 23 00:00:00 EDT 2017 · Angewandte Chemie · OSTI ID:1369319

Choi, Chang Hyuck; Choi, Won Seok; Kasian, Olga; +8 more

Covalent Organic Framework (COF) Derived Ni–N–C Catalysts for Electrochemical CO ₂ Reduction: Unraveling Fundamental Kinetic and Structural Parameters of the Active Sites

Journal Article · Mon Jan 31 00:00:00 EST 2022 · Angewandte Chemie (International Edition) · OSTI ID:1369319

Li, Changxia; Ju, Wen; Vijay, Sudarshan; +15 more

Title: Unraveling the Nature of Sites Active toward Hydrogen Peroxide Reduction in Fe-N-C Catalysts

Citation Formats

References (38)

Similar Records

Related Subjects