Electrochemical reduction of CO 2 to synthesis gas with controlled CO/H 2 ratios

doi:10.1039/C7EE00071E

Title: Electrochemical reduction of CO ₂ to synthesis gas with controlled CO/H ₂ ratios

Authors:

Sheng, Wenchao; Kattel, Shyam; Yao, Siyu; Yan, Binhang; Liang, Zhixiu; Hawxhurst, Christopher J.; Wu, Qiyuan;

Publication Date:: 2017-01-01

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Org.:: DOE - BASIC ENERGY SCIENCES

OSTI Identifier:: 1368310

Resource Type:: Journal Article

Journal Name:: Energy & Environmental Science

Additional Journal Information:: Journal Volume: 10; Journal Issue: 5; Journal ID: ISSN 1754-5692

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: ENGLISH

Citation Formats


                    Sheng, Wenchao, Kattel, Shyam, Yao, Siyu, Yan, Binhang, Liang, Zhixiu, Hawxhurst, Christopher J., Wu, Qiyuan, and Chen, Jingguang G. Electrochemical reduction of CO 2 to synthesis gas with controlled CO/H 2 ratios.  United States: N. p., 2017. 
        Web.  doi:10.1039/C7EE00071E.

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                    Sheng, Wenchao, Kattel, Shyam, Yao, Siyu, Yan, Binhang, Liang, Zhixiu, Hawxhurst, Christopher J., Wu, Qiyuan, & Chen, Jingguang G. Electrochemical reduction of CO 2 to synthesis gas with controlled CO/H 2 ratios.  United States.  doi:10.1039/C7EE00071E.

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                    Sheng, Wenchao, Kattel, Shyam, Yao, Siyu, Yan, Binhang, Liang, Zhixiu, Hawxhurst, Christopher J., Wu, Qiyuan, and Chen, Jingguang G. Sun .  
        "Electrochemical reduction of CO 2 to synthesis gas with controlled CO/H 2 ratios".  United States.  doi:10.1039/C7EE00071E.

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@article{osti_1368310,

  title        = {Electrochemical reduction of CO 2 to synthesis gas with controlled CO/H 2 ratios},

  author       = {Sheng, Wenchao and Kattel, Shyam and Yao, Siyu and Yan, Binhang and Liang, Zhixiu and Hawxhurst, Christopher J. and Wu, Qiyuan and Chen, Jingguang G.},

  abstractNote = {},

  doi          = {10.1039/C7EE00071E},

  journal      = {Energy & Environmental Science},

  issn         = {1754-5692},

  number       = 5,

  volume       = 10,

  place        = {United States},

  year         = {2017},

  month        = {1}

}

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Journal Article:

DOI: 10.1039/C7EE00071E

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Works referenced in this record:

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Title: Electrochemical reduction of CO 2 to synthesis gas with controlled CO/H 2 ratios

Citation Formats

L -edge x-ray-absorption systematics of the noble metals Rh, Pd, and Ag and the main-group metals In and Sn: A study of the unoccupied density of states in 4 d elements journal, February 1985

Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces journal, January 2013

Size effects on the hydrogen storage properties of nanostructured metal hydrides: A review journal, January 2007

Projector augmented-wave method journal, December 1994

Single catalyst electrocatalytic reduction of CO 2 in water to H 2 +CO syngas mixtures with water oxidation to O 2 journal, January 2014

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal, July 1996

Exceptional Size-Dependent Activity Enhancement in the Electroreduction of CO 2 over Au Nanoparticles journal, November 2014

Investigation of Hydrogen Adsorption and Absorption in Palladium Thin Films journal, January 2004

Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media journal, August 1994

Special points for Brillouin-zone integrations journal, June 1976

Temperature- and Pressure-Dependent Hydrogen Concentration in Supported PdH x Nanoparticles by Pd K-Edge X-ray Absorption Spectroscopy journal, May 2014

Electrochemical reduction of carbon dioxide under high pressure on various electrodes in an aqueous electrolyte journal, July 1995

Ab initio molecular dynamics for open-shell transition metals journal, November 1993

Amino acid modified copper electrodes for the enhanced selective electroreduction of carbon dioxide towards hydrocarbons journal, January 2016

Hydride phase formation in carbon supported palladium nanoparticle electrodes investigated using in situ EXAFS and XRD journal, January 2003

Pd-Catalyzed Electrohydrogenation of Carbon Dioxide to Formate: High Mass Activity at Low Overpotential and Identification of the Deactivation Pathway journal, April 2015

Reactions of synthesis gas journal, September 1996

Inhomogeneous Electron Gas journal, November 1964

Accurate and simple analytic representation of the electron-gas correlation energy journal, June 1992

Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO 2 to CO journal, October 2013

Active and Selective Conversion of CO 2 to CO on Ultrathin Au Nanowires journal, November 2014

Hydrogen in palladium and palladium alloys journal, June 1996

Trends in the Exchange Current for Hydrogen Evolution journal, January 2005

Density functional theory in surface chemistry and catalysis journal, January 2011

Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode journal, November 2004

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces journal, January 2012

Synthesis of 1 nm Pd Nanoparticles in a Microfluidic Reactor: Insights from in Situ X-ray Absorption Fine Structure Spectroscopy and Small-Angle X-ray Scattering journal, May 2015

Size-Dependent Electrocatalytic Reduction of CO 2 over Pd Nanoparticles journal, March 2015

Electrochemical Reduction of Carbon Dioxide on Various Metal Electrodes in Low-Temperature Aqueous KHCO3 Media journal, January 1990

Band-structure approach to the x-ray spectra of metals journal, April 1984

Self-Consistent Equations Including Exchange and Correlation Effects journal, November 1965

Nanosize Effects on Hydrogen Storage in Palladium journal, March 2008

Title: Electrochemical reduction of CO ₂ to synthesis gas with controlled CO/H ₂ ratios

L -edge x-ray-absorption systematics of the noble metals Rh, Pd, and Ag and the main-group metals In and Sn: A study of the unoccupied density of states in 4 d elements
journal, February 1985

Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces
journal, January 2013

Size effects on the hydrogen storage properties of nanostructured metal hydrides: A review
journal, January 2007

Projector augmented-wave method
journal, December 1994

Single catalyst electrocatalytic reduction of CO ₂ in water to H ₂ +CO syngas mixtures with water oxidation to O ₂
journal, January 2014

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996

Exceptional Size-Dependent Activity Enhancement in the Electroreduction of CO ₂ over Au Nanoparticles
journal, November 2014

Investigation of Hydrogen Adsorption and Absorption in Palladium Thin Films
journal, January 2004

Electrocatalytic process of CO selectivity in electrochemical reduction of CO₂ at metal electrodes in aqueous media
journal, August 1994

Special points for Brillouin-zone integrations
journal, June 1976

Temperature- and Pressure-Dependent Hydrogen Concentration in Supported PdH _x Nanoparticles by Pd K-Edge X-ray Absorption Spectroscopy
journal, May 2014

Electrochemical reduction of carbon dioxide under high pressure on various electrodes in an aqueous electrolyte
journal, July 1995

Ab initio molecular dynamics for open-shell transition metals
journal, November 1993

Amino acid modified copper electrodes for the enhanced selective electroreduction of carbon dioxide towards hydrocarbons
journal, January 2016

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journal, January 2003

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Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO ₂ to CO
journal, October 2013

Active and Selective Conversion of CO ₂ to CO on Ultrathin Au Nanowires
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Hydrogen in palladium and palladium alloys
journal, June 1996

Trends in the Exchange Current for Hydrogen Evolution
journal, January 2005

Density functional theory in surface chemistry and catalysis
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Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
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New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
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Synthesis of 1 nm Pd Nanoparticles in a Microfluidic Reactor: Insights from in Situ X-ray Absorption Fine Structure Spectroscopy and Small-Angle X-ray Scattering
journal, May 2015

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journal, March 2015

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journal, January 1990

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journal, April 1984

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965

Nanosize Effects on Hydrogen Storage in Palladium
journal, March 2008