Vertically Oriented and Interpenetrating CuSe Nanosheet Films with Open Channels for Flexible All-Solid-State Supercapacitors

Li, Lingzhi; Gong, Jiangfeng; Liu, Chunyan; Tian, Yazhou; Han, Min; Wang, Qianjin; Hong, Xihao; Ding, Qingping; Zhu, Weihua; Bao, Jianchun

doi:10.1021/acsomega.6b00535

Vertically Oriented and Interpenetrating CuSe Nanosheet Films with Open Channels for Flexible All-Solid-State Supercapacitors

Journal Article · Wed Mar 22 00:00:00 EDT 2017 · ACS Omega

DOI:https://doi.org/10.1021/acsomega.6b00535· OSTI ID:1368042

Li, Lingzhi ^[1]; Gong, Jiangfeng ^[1]; Liu, Chunyan ^[2]; Tian, Yazhou ^[1]; Han, Min ^[3]; Wang, Qianjin ^[4]; Hong, Xihao ^[4]; Ding, Qingping ^[5]; Zhu, Weihua ^[1]; Bao, Jianchun ^[2]

Hohai Univ., Nanjing (China)
Nanjing Normal Univ. (China)
Nanjing Normal Univ. (China); Nanjing Univ. (China)
Nanjing Univ. (China)
Ames Lab., Ames, IA (United States)

As a p-type multifunctional semiconductor, CuSe nanostructures show great promise in optoelectronic, sensing, and photocatalytic fields. Although great progress has been achieved, controllable synthesis of CuSe nanosheets (NSs) with a desirable spacial orientation and open frameworks remains a challenge, and their use in supercapacitors (SCs) has not been explored. Herein, a highly vertically oriented and interpenetrating CuSe NS film with open channels is deposited on an Au-coated polyethylene terephthalate substrate. Such CuSe NS films exhibit high specific capacitance (209 F g–1) and can be used as a carbon black- and binder-free electrode to construct flexible, symmetric all-solid-state SCs, using polyvinyl alcohol–LiCl gel as the solid electrolyte. A device fabricated with such CuSe NS films exhibits high volumetric specific capacitance (30.17 mF cm–3), good cycling stability, excellent flexibility, and desirable mechanical stability. The excellent performance of such devices results from the vertically oriented and interpenetrating configuration of CuSe NS building blocks, which can increase the available surface and facilitate the diffusion of electrolyte ions. Moreover, as a prototype for application, three such solid devices in series can be used to light up a red light-emitting diode.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1368042

Report Number(s):: IS--J-9285

Journal Information:: ACS Omega, Journal Name: ACS Omega Journal Issue: 3 Vol. 2; ISSN 2470-1343

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (53)

Large-Scale Synthesis of Long Crystalline Cu _2-x Se Nanowire Bundles by Water-Evaporation-Induced Self-Assembly and Their Application in Gas Sensing Xu, Jun; Zhang, Weixin; Yang, Zeheng Advanced Functional Materials, Vol. 19, Issue 11 https://doi.org/10.1002/adfm.200801430	journal	June 2009
Advanced Asymmetric Supercapacitors Based on Ni(OH)2/Graphene and Porous Graphene Electrodes with High Energy Density Yan, Jun; Fan, Zhuangjun; Sun, Wei Advanced Functional Materials, Vol. 22, Issue 12 https://doi.org/10.1002/adfm.201102839	journal	March 2012
Fully Solution‐Processed Conductive Films Based on Colloidal Copper Selenide Nanosheets for Flexible Electronics Vikulov, Sergey; Di Stasio, Francesco; Ceseracciu, Luca Advanced Functional Materials, Vol. 26, Issue 21 https://doi.org/10.1002/adfm.201600124	journal	April 2016
Advanced Materials for Energy Storage Liu, Chang; Li, Feng; Ma, Lai-Peng Advanced Materials, Vol. 22, Issue 8 https://doi.org/10.1002/adma.200903328	journal	February 2010
All-Graphene Core-Sheath Microfibers for All-Solid-State, Stretchable Fibriform Supercapacitors and Wearable Electronic Textiles Meng, Yuning; Zhao, Yang; Hu, Chuangang Advanced Materials, Vol. 25, Issue 16 https://doi.org/10.1002/adma.201300132	journal	March 2013
Co(OH) ₂ @PANI Hybrid Nanosheets with 3D Networks as High‐Performance Electrocatalysts for Hydrogen Evolution Reaction Feng, Jin‐Xian; Ding, Liang‐Xin; Ye, Sheng‐Hua Advanced Materials, Vol. 31, Issue 51 https://doi.org/10.1002/adma.201904101	journal	December 2019
Two-Dimensional CuSe Nanosheets with Microscale Lateral Size: Synthesis and Template-Assisted Phase Transformation Wu, Xue-Jun; Huang, Xiao; Liu, Juqing Angewandte Chemie, Vol. 126, Issue 20 https://doi.org/10.1002/ange.201311309	journal	April 2014
Superior Electrical Conductivity in Hydrogenated Layered Ternary Chalcogenide Nanosheets for Flexible All-Solid-State Supercapacitors Hu, Xin; Shao, Wei; Hang, Xudong Angewandte Chemie International Edition, Vol. 55, Issue 19 https://doi.org/10.1002/anie.201600029	journal	April 2016
Direct Laser-Patterned Micro-Supercapacitors from Paintable MoS ₂ Films Cao, Liujun; Yang, Shubin; Gao, Wei Small, Vol. 9, Issue 17 https://doi.org/10.1002/smll.201203164	journal	April 2013
Facile synthesis of 3-D composites of MnO2 nanorods and holey graphene oxide for supercapacitors Wang, Lixin; Deng, Da; Salley, Steven O. Journal of Materials Science, Vol. 50, Issue 19 https://doi.org/10.1007/s10853-015-9169-8	journal	June 2015
Synthesis of macro-mesoporous carbon materials and hollow core/mesoporous shell carbon spheres as supercapacitors Chen, Aibing; Yu, Yifeng; Li, Yuetong Journal of Materials Science, Vol. 51, Issue 9 https://doi.org/10.1007/s10853-016-9774-1	journal	February 2016
Inkjet printing of single-walled carbon nanotube/RuO2 nanowire supercapacitors on cloth fabrics and flexible substrates Chen, Pochiang; Chen, Haitian; Qiu, Jing Nano Research, Vol. 3, Issue 8 https://doi.org/10.1007/s12274-010-0020-x	journal	July 2010
Designing two dimensional nanoarchitectured MoS2 sheets grown on Mo foil as a binder free electrode for supercapacitors Krishnamoorthy, Karthikeyan; Veerasubramani, Ganesh Kumar; Pazhamalai, Parthiban Electrochimica Acta, Vol. 190 https://doi.org/10.1016/j.electacta.2015.12.148	journal	February 2016
Optical spectroscopy, optical conductivity, dielectric properties and new methods for determining the gap states of CuSe thin films Sakr, G. B.; Yahia, I. S.; Fadel, M. Journal of Alloys and Compounds, Vol. 507, Issue 2 https://doi.org/10.1016/j.jallcom.2010.08.022	journal	October 2010
Cathodic deposition of Ni(OH)2 and Co(OH)2 for asymmetric supercapacitors: Importance of the electrochemical reversibility of redox couples Hu, Chi-Chang; Chen, Jia-Cing; Chang, Kuo-Hsin Journal of Power Sources, Vol. 221 https://doi.org/10.1016/j.jpowsour.2012.07.111	journal	January 2013
Materials and fabrication of electrode scaffolds for deposition of MnO2 and their true performance in supercapacitors Cao, Jianyun; Li, Xiaohong; Wang, Yaming Journal of Power Sources, Vol. 293 https://doi.org/10.1016/j.jpowsour.2015.05.115	journal	October 2015
Carbon/carbon nanotube-supported RuO2 nanoparticles with a hollow interior as excellent electrode materials for supercapacitors Wang, Pengfei; Xu, Yuxing; Liu, Hui Nano Energy, Vol. 15 https://doi.org/10.1016/j.nanoen.2015.04.006	journal	July 2015
Engineering of MnO2-based nanocomposites for high-performance supercapacitors Wang, Jian-Gan; Kang, Feiyu; Wei, Bingqing Progress in Materials Science, Vol. 74 https://doi.org/10.1016/j.pmatsci.2015.04.003	journal	October 2015
Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: A review Abioye, Adekunle Moshood; Ani, Farid Nasir Renewable and Sustainable Energy Reviews, Vol. 52 https://doi.org/10.1016/j.rser.2015.07.129	journal	December 2015
Metal Ions Mediated Morphology and Phase Transformation of Chalcogenide Semiconductor: From CuClSe ₂ Microribbon to CuSe Nanosheet Liu, Yong-Qiang; Wu, Hao-Di; Zhao, Yu Langmuir, Vol. 31, Issue 17 https://doi.org/10.1021/acs.langmuir.5b00373	journal	April 2015
Three-Dimensional Network of N-Doped Carbon Ultrathin Nanosheets with Closely Packed Mesopores: Controllable Synthesis and Application in Electrochemical Energy Storage Zhu, Shan; Li, Jiajun; Ma, Liying ACS Applied Materials & Interfaces, Vol. 8, Issue 18 https://doi.org/10.1021/acsami.6b02386	journal	April 2016
Study on Thermal Evolution of the CuSe Phase in Nanoparticle-Based Absorber Layers for Solution-Processed Chalcopyrite Photovoltaic Devices Seo, Yeong-Hui; Lee, Byung-Seok; Jo, Yejin ACS Applied Materials & Interfaces, Vol. 5, Issue 15 https://doi.org/10.1021/am401735a	journal	July 2013
Synthesis and Characterization of Hexagonal CuSe Nanotubes by Templating against Trigonal Se Nanotubes Zhang, Sheng-Yi; Fang, Chun-Xia; Tian, Yu-Peng Crystal Growth & Design, Vol. 6, Issue 12 https://doi.org/10.1021/cg0604430	journal	October 2006
A Facile and Template-Free Hydrothermal Synthesis of Mn ₃ O ₄ Nanorods on Graphene Sheets for Supercapacitor Electrodes with Long Cycle Stability Lee, Jeong Woo; Hall, Anthony S.; Kim, Jong-Duk Chemistry of Materials, Vol. 24, Issue 6 https://doi.org/10.1021/cm203697w	journal	March 2012
Metallic Few-Layered VS ₂ Ultrathin Nanosheets: High Two-Dimensional Conductivity for In-Plane Supercapacitors Feng, Jun; Sun, Xu; Wu, Changzheng Journal of the American Chemical Society, Vol. 133, Issue 44 https://doi.org/10.1021/ja207176c	journal	November 2011
Facile Microwave-Assisted Synthesis of Multiphase CuInSe ₂ Nanoparticles and Role of Secondary CuSe Phase on Photovoltaic Device Performance Seo, Yeong-Hui; Lee, Byung-Seok; Jo, Yejin The Journal of Physical Chemistry C, Vol. 117, Issue 19 https://doi.org/10.1021/jp310434j	journal	May 2013
Printable Thin Film Supercapacitors Using Single-Walled Carbon Nanotubes Kaempgen, Martti; Chan, Candace K.; Ma, J. Nano Letters, Vol. 9, Issue 5, p. 1872-1876 https://doi.org/10.1021/nl8038579	journal	May 2009
Two-Dimensional Tin Selenide Nanostructures for Flexible All-Solid-State Supercapacitors Zhang, Chunli; Yin, Huanhuan; Han, Min ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn5004315	journal	March 2014
Hierarchical MnMoO4/CoMoO4 heterostructured nanowires with enhanced supercapacitor performance Mai, Li-Qiang; Yang, Fan; Zhao, Yun-Long Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1387	journal	July 2011
Scalable synthesis of hierarchically structured carbon nanotube–graphene fibres for capacitive energy storage Yu, Dingshan; Goh, Kunli; Wang, Hong Nature Nanotechnology, Vol. 9, Issue 7 https://doi.org/10.1038/nnano.2014.93	journal	May 2014
Facile Microwave-Assisted Synthesis of Klockmannite CuSe Nanosheets and Their Exceptional Electrical Properties Liu, Yong-Qiang; Wang, Feng-Xia; Xiao, Yan Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep05998	journal	August 2014
Microwave-assisted elemental direct reaction route to nanocrystalline copper chalcogenides CuSe and Cu2TeElectronic supplementary information (ESI) available: XPS spectra of the products. See http://www.rsc.org/suppdata/jm/b2/b205558a/ Zhang, Yong; Qiao, Zheng-Ping; Chen, Xiao-Ming Journal of Materials Chemistry, Vol. 12, Issue 9 https://doi.org/10.1039/b205558a	journal	August 2002
Thin film CdSe/CuSe photovoltaic on a flexible single walled carbon nanotube substrate Hamilton, Christopher E.; Flood, Dennis J.; Barron, Andrew R. Physical Chemistry Chemical Physics, Vol. 15, Issue 11 https://doi.org/10.1039/c3cp50435b	journal	January 2013
Hydrothermal synthesis of hexagonal CuSe nanoflakes with excellent sunlight-driven photocatalytic activity Gu, Yanjie; Su, Yanjie; Chen, Da CrystEngComm, Vol. 16, Issue 39 https://doi.org/10.1039/c4ce01470g	journal	January 2014
Three-dimensional graphene materials: preparation, structures and application in supercapacitors Cao, Xiehong; Yin, Zongyou; Zhang, Hua Energy Environ. Sci., Vol. 7, Issue 6 https://doi.org/10.1039/c4ee00050a	journal	January 2014
Directly deposited MoS ₂ thin film electrodes for high performance supercapacitors Choudhary, Nitin; Patel, Mumukshu; Ho, Yee-Hsien Journal of Materials Chemistry A, Vol. 3, Issue 47 https://doi.org/10.1039/c5ta08095a	journal	January 2015
Carbon-Based Supercapacitors Produced by Activation of Graphene Zhu, Y.; Murali, S.; Stoller, M. D. Science, Vol. 332, Issue 6037, p. 1537-1541 https://doi.org/10.1126/science.1200770	journal	May 2011
Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage Bonaccorso, Francesco; Colombo, Luigi; Yu, Guihua Science, Vol. 347, Issue 6217 https://doi.org/10.1126/science.1246501	journal	January 2015
A Three-Dimensional Carbon Nanotube/Graphene Sandwich and Its Application as Electrode in Supercapacitors Fan, Zhuangjun; Yan, Jun; Zhi, Linjie Advanced Materials, Vol. 22, Issue 33, p. 3723-3728 https://doi.org/10.1002/adma.201001029	journal	August 2010
Flexible Energy-Storage Devices: Design Consideration and Recent Progress Wang, Xianfu; Lu, Xihong; Liu, Bin Advanced Materials, Vol. 26, Issue 28 https://doi.org/10.1002/adma.201400910	journal	June 2014
Co(OH) ₂ @PANI Hybrid Nanosheets with 3D Networks as High-Performance Electrocatalysts for Hydrogen Evolution Reaction Feng, Jin-Xian; Ding, Liang-Xin; Ye, Sheng-Hua Advanced Materials, Vol. 27, Issue 44 https://doi.org/10.1002/adma.201503187	journal	October 2015
Superior Electrical Conductivity in Hydrogenated Layered Ternary Chalcogenide Nanosheets for Flexible All-Solid-State Supercapacitors Hu, Xin; Shao, Wei; Hang, Xudong Angewandte Chemie, Vol. 128, Issue 19 https://doi.org/10.1002/ange.201600029	journal	April 2016
Two-Dimensional CuSe Nanosheets with Microscale Lateral Size: Synthesis and Template-Assisted Phase Transformation Wu, Xue-Jun; Huang, Xiao; Liu, Juqing Angewandte Chemie International Edition https://doi.org/10.1002/anie.201311309	journal	April 2014
Hybrid α-Fe 2 O 3 @NiO heterostructures for flexible and high performance supercapacitor electrodes and visible light driven photocatalysts Jiao, Yang; Liu, Yang; Yin, Bosi Nano Energy, Vol. 10 https://doi.org/10.1016/j.nanoen.2014.09.002	journal	November 2014
Three-dimensional ultrathin Ni(OH)2 nanosheets grown on nickel foam for high-performance supercapacitors Xiong, Xunhui; Ding, Dong; Chen, Dongchang Nano Energy, Vol. 11 https://doi.org/10.1016/j.nanoen.2014.10.029	journal	January 2015
Self-Assembled Graphene/Carbon Nanotube Hybrid Films for Supercapacitors Yu, Dingshan; Dai, Liming The Journal of Physical Chemistry Letters, Vol. 1, Issue 2 https://doi.org/10.1021/jz9003137	journal	December 2009
Solvothermal synthesis of CoS2–graphene nanocomposite material for high-performance supercapacitors Wang, Bei; Park, Jinsoo; Su, Dawei Journal of Materials Chemistry, Vol. 22, Issue 31 https://doi.org/10.1039/c2jm31214j	journal	January 2012
Cobalt phosphite microarchitectures assembled by ultralong nanoribbons and their application as effective electrochemical capacitor electrode materials Pang, Huan; Liu, Yuanying; Li, Juan Nanoscale, Vol. 5, Issue 2 https://doi.org/10.1039/c2nr32597g	journal	January 2013
All-solid-state flexible thin-film supercapacitors with high electrochemical performance based on a two-dimensional V2O5·H2O/graphene composite Bao, Jian; Zhang, Xiaodong; Bai, Liangfei Journal of Materials Chemistry A, Vol. 2, Issue 28 https://doi.org/10.1039/c3ta15293f	journal	January 2014
The highly enhanced performance of lamellar WS2 nanosheet electrodes upon intercalation of single-walled carbon nanotubes for supercapacitors and lithium ions batteries Liu, Yu; Wang, Wei; Huang, Hubiao Chemical Communications, Vol. 50, Issue 34 https://doi.org/10.1039/c4cc01622j	journal	January 2014
Flexible solid-state supercapacitors: design, fabrication and applications Lu, Xihong; Yu, Minghao; Wang, Gongming Energy & Environmental Science, Vol. 7, Issue 7 https://doi.org/10.1039/c4ee00960f	journal	January 2014
Carbon cladded TiO ₂ nanotubes: fabrication and use in 3D-RuO ₂ based supercapacitors Gao, Zhi-Da; Zhu, Xu; Li, Ya-Hang Chemical Communications, Vol. 51, Issue 36 https://doi.org/10.1039/c5cc00728c	journal	January 2015
Monolithic Carbide-Derived Carbon Films for Micro-Supercapacitors Chmiola, J.; Largeot, C.; Taberna, P. L. Science, Vol. 328, Issue 5977 https://doi.org/10.1126/science.1184126	journal	April 2010

Cited By (4)

Recent Advances in Metal Chalcogenides (MX; X = S, Se) Nanostructures for Electrochemical Supercapacitor Applications: A Brief Review Theerthagiri, Jayaraman; Karuppasamy, K.; Durai, Govindarajan Nanomaterials, Vol. 8, Issue 4 https://doi.org/10.3390/nano8040256	journal	April 2018
Evaporation‐Induced Vertical Alignment Enabling Directional Ion Transport in a 2D‐Nanosheet‐Based Battery Electrode Zhu, Yue; Ju, Zhengyu; Zhang, Xiao Advanced Materials, Vol. 32, Issue 10 https://doi.org/10.1002/adma.201907941	journal	January 2020
Towards flexible solid-state supercapacitors for smart and wearable electronics Dubal, Deepak P.; Chodankar, Nilesh R.; Kim, Do-Heyoung Chemical Society Reviews, Vol. 47, Issue 6 https://doi.org/10.1039/c7cs00505a	journal	January 2018
Synthesis of a 3D free standing crystalline NiSe _x matrix for electrochemical energy storage applications Dinara, Syed Mukulika; Samantara, Aneeya K.; Das, Jiban K. Dalton Transactions, Vol. 48, Issue 45 https://doi.org/10.1039/c9dt03150b	journal	January 2019

Similar Records

High-Performance Flexible All-Solid-State Asymmetric Supercapacitors Based on Vertically Aligned CuSe@Co(OH)₂ Nanosheet Arrays

Journal Article · Wed Jan 03 23:00:00 EST 2018 · Journal of Physical Chemistry. C · OSTI ID:1427731

Vertically-aligned Mn(OH)₂ nanosheet films for flexible all-solid-state electrochemical supercapacitors

Journal Article · Mon Aug 28 00:00:00 EDT 2017 · Journal of Materials Science Materials in Electronics · OSTI ID:1409844

Vacuum-Assisted Low-Temperature Synthesis of Reduced Graphene Oxide Thin-Film Electrodes for High-Performance Transparent and Flexible All-Solid-State Supercapacitors

Journal Article · Mon Mar 12 00:00:00 EDT 2018 · ACS Applied Materials and Interfaces · OSTI ID:1502607

Related Subjects

36 MATERIALS SCIENCE

Vertically Oriented and Interpenetrating CuSe Nanosheet Films with Open Channels for Flexible All-Solid-State Supercapacitors

Citation Formats

References (53)

Cited By (4)

Similar Records

Related Subjects