Two-dimensional fluorescence spectroscopy of uranium isotopes in femtosecond laser ablation plumes

Phillips, Mark C.; Brumfield, Brian E.; LaHaye, Nicole L.; Harilal, Sivanandan S.; Hartig, Kyle C.; Jovanovic, Igor

doi:10.1038/s41598-017-03865-9

Two-dimensional fluorescence spectroscopy of uranium isotopes in femtosecond laser ablation plumes

Journal Article · Mon Jun 19 04:00:00 EDT 2017 · Scientific Reports

DOI:https://doi.org/10.1038/s41598-017-03865-9· OSTI ID:1367385

Phillips, Mark C.; Brumfield, Brian E.; LaHaye, Nicole L.; Harilal, Sivanandan S.; Hartig, Kyle C.; Jovanovic, Igor

We demonstrate measurement of uranium isotopes in femtosecond laser ablation plumes using two-dimensional fluorescence spectroscopy (2DFS). The high-resolution, tunable CW-laser spectroscopy technique clearly distinguishes atomic absorption from 235U and 238U in natural and highly enriched uranium metal samples. We present analysis of spectral resolution and analytical performance of 2DFS as a function of ambient pressure. Simultaneous measurement using time-resolved absorption spectroscopy provides information on temporal dynamics of the laser ablation plume and saturation behavior of fluorescence signals. The rapid, non-contact measurement is promising for in-field, standoff measurements of uranium enrichment for nuclear safety and security applications.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1367385

Report Number(s):: PNNL-SA--123330; DN2001000

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 7; ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

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