skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Unexpected significant increase in bulk conductivity of a dielectric arising from charge injection

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4990677· OSTI ID:1543836

Charge injection is a common phenomenon in heterostructures or devices containing metal-insulator interfaces under a voltage bias ranging from dielectric capacitors to electroluminescent and lasing devices. It is generally believed that charge injection only significantly increases the conductivity near the interfacial region or in capacitors with very thin dielectric layers. In this work, the impact of charge injection on bulk conductivity of a 0.5 mm thick Fe-doped SrTiO3 single crystal is investigated with a combination of experimental impedance measurements and computational modelling. As a result, it is found that the interfacial charge injection may increase the predicted bulk conductivity of a dielectric by more than one order of magnitude as a consequence of Schottky barrier height lowering.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1543836
Alternate ID(s):
OSTI ID: 1367362
Journal Information:
Applied Physics Letters, Vol. 110, Issue 26; ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 11 works
Citation information provided by
Web of Science

References (35)

dc Electrical Degradation of Perovskite-Type Titanates: III, A Model of the Mechanism journal June 1990
Interface Properties of Dielectric Oxides journal January 2016
Barrier height at ( Ba , Sr ) TiO 3 / Pt interfaces studied by photoemission journal May 2008
dc Electrical Degradation of Perovskite-Type Titanates: II, Single Crystals journal June 1990
Applications of Modern Ferroelectrics journal February 2007
Partial Conductivities in SrTiO 3 : Bulk Polarization Experiments, Oxygen Concentration Cell Measurements, and Defect-Chemical Modeling journal December 1995
Determination of Schottky barrier profile at Pt/SrTiO 3 :Nb junction by x-ray photoemission journal December 2012
Double‐carrier injection and recombination in insulators, including diffusion effects journal October 1984
Defect chemistry and resistance degradation in Fe-doped SrTiO3 single crystal journal April 2016
High temperature transport properties at metal/SrTiO3 interfaces journal June 1999
Charge injection in SrTiO3 thin films journal May 1997
Statistics of the Recombinations of Holes and Electrons journal September 1952
Impedance Spectroscopy book January 2005
Grain boundaries in dielectric and mixed-conducting ceramics journal February 2000
Voltage-Dependent Bulk Resistivity of SrTiO 3 :Mg Ceramics journal June 2014
The relation of electrical conductivity profiles and modulus data using the example of STO:Fe single crystals: A path to improve the model of resistance degradation journal September 2016
Mobility-Dependent Charge Injection into an Organic Semiconductor journal April 2001
Intrinsic energy band alignment of functional oxides: Intrinsic energy band alignment of functional oxides journal March 2014
Time Evolution of the Potential Distribution in Earth Alkaline Titanates under de Voltage Stress journal December 1988
Science and technology of thin films and interfacial layers in ferroelectric and high-dielectric constant heterostructures and application to devices journal September 2006
Electrochemical Boundary Conditions for Resistance Degradation of Doped Alkaline-Earth Titanates journal December 1989
Microscopic View of Charge Injection in an Organic Semiconductor journal September 2004
Field-effect electroluminescence in silicon nanocrystals journal January 2005
Electroceramics: Characterization by Impedance Spectroscopy journal March 1990
Hall mobility of undoped n-type conducting strontium titanate single crystals between 19 K and 1373 K journal October 1995
High-efficiency quantum-dot light-emitting devices with enhanced charge injection journal April 2013
Electronic-transport behavior in single-crystalline Ba 0.03 Sr 0.97 TiO 3 journal November 1986
Space-Charge Conduction in Solids journal December 1966
Theory of conduction and breakdown in perovskite thin films journal November 1992
Nonstoichiometry in SrTiO[sub 3] journal January 1981
Low-Temperature Ionic Conductivity of an Acceptor-Doped Perovskite: I. Impedance of Single-Crystal SrTiO 3 journal June 2016
Electron-Hole Recombination in Germanium journal July 1952
Carrier Generation and Recombination in P-N Junctions and P-N Junction Characteristics journal September 1957
A nanocomposite ultraviolet photodetector based on interfacial trap-controlled charge injection journal November 2012
Finite-size versus interface-proximity effects in thin-film epitaxial SrTiO 3 journal June 2014

Cited By (6)

Determination of electrical properties of degraded mixed ionic conductors: Impedance studies with applied dc voltage journal December 2017
0.6ST-0.4NBT thin film with low level Mn doping as a lead-free ferroelectric capacitor with high energy storage performance journal February 2018
Conductivity of iron‐doped strontium titanate in the quenched and degraded states journal December 2018
Local structural changes due to the electric field‐induced migration of oxygen vacancies at Fe‐doped SrTiO 3 interfaces journal January 2019
Computational modeling of grain boundary electrostatic effect in polycrystalline SrTiO 3 thin film journal January 2019
Determination of electrical properties of degraded mixed ionic conductors: Impedance studies with applied dc voltage text January 2021