Formation of metal clusters in halloysite clay nanotubes

Vinokurov, Vladimir A.; Stavitskaya, Anna V.; Chudakov, Yaroslav A.; Ivanov, Evgenii V.; Shrestha, Lok Kumar; Ariga, Katsuhiko; Darrat, Yusuf A.; Lvov, Yuri M.

doi:10.1080/14686996.2016.1278352

Title: Formation of metal clusters in halloysite clay nanotubes

Journal Article · Thu Feb 16 00:00:00 EST 2017 · Science and Technology of Advanced Materials

DOI:https://doi.org/10.1080/14686996.2016.1278352· OSTI ID:1510107

Vinokurov, Vladimir A. ^[1]; Stavitskaya, Anna V. ^[1]; Chudakov, Yaroslav A. ^[1]; Ivanov, Evgenii V. ^[1]; Shrestha, Lok Kumar ^[2]; Ariga, Katsuhiko ^[2]; Darrat, Yusuf A. ^[3]; Lvov, Yuri M. ^[3]

Department of Physical and Colloid Chemistry, I. Gubkin Russian State University of Oil and Gas, Moscow, Russia
WPI-MANA, National Institute for Materials Science, Tsukuba, Japan
Institute for Micromanufacturing, Louisiana Tech University, Ruston, LA, USA

We developed ceramic core-shell materials based on abundant halloysite clay nanotubes with enhanced heavy metal ions loading through Schiff base binding. These clay tubes are formed by rolling alumosilicate sheets and have diameter of c.50 nm, a lumen of 15 nm and length ~1 μm. This allowed for synthesis of metal nanoparticles at the selected position: (1) on the outer surface seeding 3-5 nm metal particles on the tubes; (2) inside the tube’s central lumen resulting in 10-12 nm diameter metal cores shelled with ceramic wall; and (3) smaller metal nanoparticles intercalated in the tube’s wall allowing up to 9 wt% of Ru, and Ag loading. These composite materials have high surface area providing a good support for catalytic nanoparticles, and can also be used for sorption of metal ions from aqueous solutions.

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Research Organization:: Louisiana Tech Univ., Ruston, LA (United States)

Sponsoring Organization:: USDOE Office of Science (SC); Russian Science Foundation

Grant/Contract Number:: SC0012432; 14-19-01045

OSTI ID:: 1510107

Alternate ID(s):: OSTI ID: 1367146

Journal Information:: Science and Technology of Advanced Materials, Journal Name: Science and Technology of Advanced Materials Vol. 18 Journal Issue: 1; ISSN 1468-6996

Publisher:: Informa UK LimitedCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 97 works

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Photoactive nanoarchitectures based on clays incorporating TiO 2 and ZnO nanoparticles Ruiz-Hitzky, Eduardo; Aranda, Pilar; Akkari, Marwa Beilstein Journal of Nanotechnology, Vol. 10 https://doi.org/10.3762/bjnano.10.114	journal	January 2019
Nanoarchitectonics for Hybrid and Related Materials for Bio-Oriented Applications Ariga, Katsuhiko; Leong, David Tai; Mori, Taizo Advanced Functional Materials, Vol. 28, Issue 27 https://doi.org/10.1002/adfm.201702905	journal	September 2017
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Formation of metal clusters in halloysite clay nanotubes Vinokurov, Vladimir A.; Stavitskaya, Anna V.; Chudakov, Yaroslav A. https://doi.org/10.6084/m9.figshare.4530932 The current record is supplemented by this dataset	dataset	January 2017
Formation of metal clusters in halloysite clay nanotubes [Supplemental Data] Vinokurov, Vladimir; Stavitskaya, Anna; Chudakov, Yaroslav https://doi.org/10.6084/m9.figshare.4530932.v1 The current record is supplemented by this dataset	dataset	January 2017