Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Multi-layered proton-conducting electrolyte

Patent ·
OSTI ID:1366483
; ;
The present invention provides a multilayer anode/electrolyte assembly comprising a porous anode substrate and a layered solid electrolyte in contact therewith. The layered solid electrolyte includes a first dense layer of yttrium-doped barium zirconate (BZY), optionally including another metal besides Y, Ba, and Zr (e.g., a lanthanide metal such as Pr) on one surface thereof, a second dense layer of yttrium-doped barium cerate (BCY), and an interfacial layer between and contacting the BZY and BCY layers. The interfacial layer comprises a solid solution of the BZY and BCY electrolytes. The porous anode substrate comprises at least one porous ceramic material that is stable to carbon dioxide and water (e.g., porous BZY), as well as an electrically conductive metal and/or metal oxide (e.g., Ni, NiO, and the like).
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
Assignee:
UCHICAGO ARGONNE, LLC
Patent Number(s):
9,692,075
Application Number:
15/006,661
OSTI ID:
1366483
Country of Publication:
United States
Language:
English

References (4)

Sinteractive anodic powders improve densification and electrochemical properties of BaZr0.8Y0.2O3−δ electrolyte films for anode-supported solid oxide fuel cells journal January 2011
Fabrication and performance of BaCe0.8Y0.2O3−δ–BaZr0.8Y0.2O3−δ bilayer electrolyte for anode-supported solid oxide fuel cells journal March 2014
A Review of RedOx Cycling of Solid Oxide Fuel Cells Anode journal August 2012
Synthesis, stability and conductivity of BaCe0.8−xZrxY0.2O3−δ as electrolyte for proton conducting SOFC journal February 2012

Similar Records

Solid oxide fuel cells based on proton conducting electrolytes.
Conference · Sun Dec 31 23:00:00 EST 2006 · OSTI ID:972997
Electrolyte-electrode assembly for a combustible battery
Patent · Tue Oct 04 00:00:00 EDT 1977 · OSTI ID:6869193
Effect of Pd coating on hydrogen permeation of Ni-barium cerate mixed conductor.
Journal Article · Thu Feb 28 23:00:00 EST 2002 · Electrochem. Solid State Lett. · OSTI ID:949321

Related Subjects

25 ENERGY STORAGE