Brittle Fracture of 2D MoSe2

Yang, Yingchao; Li, Xing; Wen, Minru; Hacopian, Emily; Chen, Weibing; Gong, Yongji; Zhang, Jing; Li, Bo; Zhou, Wu; Ajayan, Pulickel M.; Chen, Qing; Zhu, Ting; Lou, Jun

doi:10.1002/adma.201604201

Title: Brittle Fracture of 2D MoSe₂

Journal Article · Thu Nov 03 00:00:00 EDT 2016 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201604201· OSTI ID:1364321

Yang, Yingchao ^[1]; Li, Xing ^[2]; Wen, Minru ^[3]; Hacopian, Emily ^[1]; Chen, Weibing ^[1]; Gong, Yongji ^[1]; Zhang, Jing ^[1]; Li, Bo ^[1]; Zhou, Wu ^[4]; Ajayan, Pulickel M. ^[1]; Chen, Qing ^[5]; Zhu, Ting ^[6]; Lou, Jun ^[1]

Rice Univ., Houston, TX (United States). Dept. of Materials Science and NanoEngineering
Rice Univ., Houston, TX (United States). Dept. of Materials Science and NanoEngineering; Peking Univ., Beijing (China). Dept. of Electronics. Key Lab. for the Physics and Chemistry of Nanodevices
Tsinghua Univ., Beijing (China). Dept. of Physics; Georgia Inst. of Technology, Atlanta, GA (United States). Woodruff School of Mechanical Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Peking Univ., Beijing (China). Dept. of Electronics. Key Lab. for the Physics and Chemistry of Nanodevices
Georgia Inst. of Technology, Atlanta, GA (United States). Woodruff School of Mechanical Engineering

An in situ quantitative tensile testing platform is developed in this paper to enable the uniform in-plane loading of a freestanding membrane of 2D materials inside a scanning electron microscope. The in situ tensile testing reveals the brittle fracture of large-area MoSe₂ crystals and measures their fracture strength for the first time.

Cite

Export

Save

Research Organization:: Rice Univ., Houston, TX (United States); Georgia Institute of Technology, Atlanta, GA (United States); Peking Univ., Beijing (China); Tsinghua Univ., Beijing (China)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); US Air Force Office of Scientific Research (AFOSR); Welch Foundation (United States); National Science Foundation (NSF); National Natural Science Foundation of China (NSFC)

Contributing Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

DOE Contract Number:: FG02-13ER46967; FA9550-14-1-0628; C-1716; DMR-1410331; 11528407

OSTI ID:: 1364321

Journal Information:: Advanced Materials, Vol. 29, Issue 2; ISSN 0935-9648

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (31)

Stretching and Breaking of Ultrathin MoS ₂ Bertolazzi, Simone; Brivio, Jacopo; Kis, Andras ACS Nano, Vol. 5, Issue 12 https://doi.org/10.1021/nn203879f	journal	November 2011
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Ultra-strength materials Zhu, Ting; Li, Ju Progress in Materials Science, Vol. 55, Issue 7 https://doi.org/10.1016/j.pmatsci.2010.04.001	journal	September 2010
Comparative Fracture Toughness of Multilayer Graphenes and Boronitrenes Wei, Xianlong; Xiao, Si; Li, Faxin Nano Letters, Vol. 15, Issue 1 https://doi.org/10.1021/nl5042066	journal	December 2014
Thermally Driven Crossover from Indirect toward Direct Bandgap in 2D Semiconductors: MoSe₂ versus MoS₂ Tongay, Sefaattin; Zhou, Jian; Ataca, Can Nano Letters, Vol. 12, Issue 11, p. 5576-5580 https://doi.org/10.1021/nl302584w	journal	October 2012
Heterostructures of transition metal dichalcogenides Amin, B.; Singh, N.; Schwingenschlögl, U. Physical Review B, Vol. 92, Issue 7 https://doi.org/10.1103/PhysRevB.92.075439	journal	August 2015
Piezoelectricity of single-atomic-layer MoS2 for energy conversion and piezotronics Wu, Wenzhuo; Wang, Lei; Li, Yilei Nature, Vol. 514, Issue 7523 https://doi.org/10.1038/nature13792	journal	October 2014
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Photoluminescence quenching in gold - MoS2 hybrid nanoflakes Bhanu, Udai; Islam, Muhammad R.; Tetard, Laurene Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep05575	journal	July 2014
2D Transition-Metal-Dichalcogenide-Nanosheet-Based Composites for Photocatalytic and Electrocatalytic Hydrogen Evolution Reactions Lu, Qipeng; Yu, Yifu; Ma, Qinglang Advanced Materials, Vol. 28, Issue 10 https://doi.org/10.1002/adma.201503270	journal	December 2015
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Mechanical Properties of Monolayer Graphene Oxide Suk, Ji Won; Piner, Richard D.; An, Jinho ACS Nano, Vol. 4, Issue 11 https://doi.org/10.1021/nn101781v	journal	October 2010
In Situ Fabrication of Vertical Multilayered MoS ₂ /Si Homotype Heterojunction for High-Speed Visible-Near-Infrared Photodetectors Zhang, Yan; Yu, Yongqiang; Mi, Longfei Small, Vol. 12, Issue 8 https://doi.org/10.1002/smll.201502923	journal	January 2016
Polycrystalline graphene and other two-dimensional materials Yazyev, Oleg V.; Chen, Yong P. Nature Nanotechnology, Vol. 9, Issue 10 https://doi.org/10.1038/nnano.2014.166	journal	August 2014
Chemical Vapor Deposition Growth of Crystalline Monolayer MoSe₂ Wang, Xingli; Gong, Yongji; Shi, Gang ACS Nano, Vol. 8, Issue 5, p. 5125-5131 https://doi.org/10.1021/nn501175k	journal	April 2014
Exfoliated 2D Transition Metal Disulfides for Enhanced Electrocatalysis of Oxygen Evolution Reaction in Acidic Medium Wu, Jingjie; Liu, Mingjie; Chatterjee, Kuntal Advanced Materials Interfaces, Vol. 3, Issue 9 https://doi.org/10.1002/admi.201500669	journal	February 2016
Self-Passivating Edge Reconstructions of Graphene Koskinen, Pekka; Malola, Sami; Häkkinen, Hannu Physical Review Letters, Vol. 101, Issue 11 https://doi.org/10.1103/PhysRevLett.101.115502	journal	September 2008
Phonon softening and direct to indirect band gap crossover in strained single-layer MoSe $_{2}$ Horzum, S.; Sahin, H.; Cahangirov, S. Physical Review B, Vol. 87, Issue 12 https://doi.org/10.1103/PhysRevB.87.125415	journal	March 2013
Ultrasensitive photodetectors based on monolayer MoS2 Lopez-Sanchez, Oriol; Lembke, Dominik; Kayci, Metin Nature Nanotechnology, Vol. 8, Issue 7 https://doi.org/10.1038/nnano.2013.100	journal	June 2013
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets Chhowalla, Manish; Shin, Hyeon Suk; Eda, Goki Nature Chemistry, Vol. 5, Issue 4, p. 263-275 https://doi.org/10.1038/nchem.1589	journal	April 2013
Large Scale Growth and Characterization of Atomic Hexagonal Boron Nitride Layers Song, Li; Ci, Lijie; Lu, Hao Nano Letters, Vol. 10, Issue 8, p. 3209-3215 https://doi.org/10.1021/nl1022139	journal	August 2010
Toughness and strength of nanocrystalline graphene Shekhawat, Ashivni; Ritchie, Robert O. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10546	journal	January 2016
Elastic Properties of Freely Suspended MoS ₂ Nanosheets Castellanos-Gomez, Andres; Poot, Menno; Steele, Gary A. Advanced Materials, Vol. 24, Issue 6 https://doi.org/10.1002/adma.201103965	journal	January 2012
Fracture of Brittle Solids Lawn, Brian Cambridge Solid State Science Series https://doi.org/10.1017/CBO9780511623127	book	January 2010
Wafer-Scale, Homogeneous MoS ₂ Layers on Plastic Substrates for Flexible Visible-Light Photodetectors Lim, Yi Rang; Song, Wooseok; Han, Jin Kyu Advanced Materials, Vol. 28, Issue 25 https://doi.org/10.1002/adma.201600606	journal	April 2016
Single-layer MoS₂ transistors Radisavljevic, B.; Radenovic, A.; Brivio, J. Nature Nanotechnology, Vol. 6, Issue 3, p. 147-150 https://doi.org/10.1038/nnano.2010.279	journal	January 2011
High Performance Multilayer MoS₂Transistors with Scandium Contacts Das, Saptarshi; Chen, Hong-Yan; Penumatcha, Ashish Verma Nano Letters, Vol. 13, Issue 1, p. 100-105 https://doi.org/10.1021/nl303583v	journal	December 2012
Atomically thin p–n junctions with van der Waals heterointerfaces Lee, Chul-Ho; Lee, Gwan-Hyoung; van der Zande, Arend M. Nature Nanotechnology, Vol. 9, Issue 9 https://doi.org/10.1038/nnano.2014.150	journal	August 2014
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Lee, C.; Wei, X.; Kysar, J. W. Science, Vol. 321, Issue 5887, p. 385-388 https://doi.org/10.1126/science.1157996	journal	July 2008
First-principles investigation of the bulk and low-index surfaces of $Mo {Se}_{2}$ Mirhosseini, Hossein; Roma, Guido; Kiss, Janos Physical Review B, Vol. 89, Issue 20 https://doi.org/10.1103/PhysRevB.89.205301	journal	May 2014
Fracture toughness of graphene Zhang, Peng; Ma, Lulu; Fan, Feifei Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4782	journal	April 2014

Similar Records

Fracture and fatigue of thin crystalline SrTiO₃ membranes

Journal Article · Mon Aug 02 00:00:00 EDT 2021 · Applied Physics Letters · OSTI ID:1364321

Harbola, Varun; Xu, Ruijuan; Crossley, Samuel; +2 more

The MoSeS dynamic omnigami paradigm for smart shape and composition programmable 2D materials

Journal Article · Fri Nov 15 00:00:00 EST 2019 · Nature Communications · OSTI ID:1364321

Berry, Joel; Ristić, Simeon; Zhou, Songsong; +2 more

Mechanical Characterization of Stacked Single-Crystal of Polyethylene and Monolayer MoSe₂

Journal Article · Wed Jun 15 00:00:00 EDT 2022 · Advanced Functional Materials · OSTI ID:1364321

Zhou, Dong; Feng, Gang; Khosla, Henna; +2 more

Related Subjects

36 MATERIALS SCIENCE
elastic modulus
fracture strength
in situ nanomechanical testing
MoSe2

Title: Brittle Fracture of 2D MoSe2

Citation Formats

References (31)

Similar Records

Related Subjects

Title: Brittle Fracture of 2D MoSe₂