Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia

de Sa, Suzane S.; Palm, Brett B.; Campuzano-Jost, Pedro; Day, Douglas A.; Newburn, Matthew K.; Hu, Weiwei; Isaacman-VanWertz, Gabriel; Yee, Lindsay D.; Thalman, Ryan; Brito, Joel; Carbone, Samara; Artaxo, Paulo; Goldstein, Allen H.; Manzi, Antonio O.; Souza, Rodrigo A. F.; Mei, Fan; Shilling, John E.; Springston, Stephen R.; Wang, Jian; Surratt, Jason D.; Alexander, M. Lizabeth; Jimenez, Jose L.; Martin, Scot T.

doi:10.5194/acp-17-6611-2017

Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia

Journal Article · Tue Jun 06 00:00:00 EDT 2017 · Atmospheric Chemistry and Physics (Online)

DOI:https://doi.org/10.5194/acp-17-6611-2017· OSTI ID:1363989

de Sa, Suzane S. ^[1]; Palm, Brett B. ^[2]; ^[2]; Day, Douglas A. ^[2]; Newburn, Matthew K. ^[3]; Hu, Weiwei ^[2]; ^[4]; Yee, Lindsay D. ^[5]; Thalman, Ryan ^[6]; ^[7]; Carbone, Samara ^[8]; ^[8]; Goldstein, Allen H. ^[5]; Manzi, Antonio O. ^[9]; Souza, Rodrigo A. F. ^[10]; Mei, Fan ^[3]; Shilling, John E. ^[3]; Springston, Stephen R. ^[6]; ^[6]; Surratt, Jason D. ^[11] more »

Harvard Univ., Cambridge, MA (United States)
Univ. of Colorado, Boulder, CO (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Univ. of California, Berkeley, CA (United States); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Univ. of California, Berkeley, CA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. de Sao Paulo, Sao Paulo (Brazil); Univ. Blaise Pascal, Aubiere (France)
Univ. de Sao Paulo, Sao Paulo (Brazil)
Instituto Nacional de Pesquisas da Amazonia, Amazonas (Brazil)
Univ. do Estado do Amazonas, Amazonas (Brazil)
The Univ. of North Carolina, Chapel Hill, NC (United States)

The atmospheric chemistry of isoprene contributes to the production of a substantial mass fraction of the particulate matter (PM) over tropical forests. Isoprene epoxydiols (IEPOX) produced in the gas phase by the oxidation of isoprene under HO₂-dominant conditions are subsequently taken up by particles, thereby leading to production of secondary organic PM. The present study investigates possible perturbations to this pathway by urban pollution. The measurement site in central Amazonia was located 4 to 6 h downwind of Manaus, Brazil. Measurements took place from February through March 2014 of the wet season, as part of the GoAmazon2014/5 experiment. Mass spectra of organic PM collected with an Aerodyne Aerosol Mass Spectrometer were analyzed by positive-matrix factorization. One resolved statistical factor ("IEPOX-SOA factor") was associated with PM production by the IEPOX pathway. The IEPOX-SOA factor loadings correlated with independently measured mass concentrations of tracers of IEPOX-derived PM, namely C₅-alkene triols and 2-methyltetrols (R = 0.96 and 0.78, respectively). The factor loading, as well as the ratio f of the loading to organic PM mass concentration, decreased under polluted compared to background conditions. For an increase in NOy concentration from 0.5 to 2 ppb, the factor loading and f decreased by two to three fold. Overall, sulfate concentration explained 37 % of the variability in the factor loading. After segregation of factor loading into subsets based on NOy concentration, the sulfate concentration explained up to 75 % of the variability. Considering both factors, the data sets show that the suppressing effects of increased NO concentrations dominated over the enhancing effects of higher sulfate concentrations. Furthermore, the pollution from Manaus elevated NOy concentrations more significantly than sulfate concentrations relative to background conditions. In this light, increased emissions of nitrogen oxides, as anticipated for some scenarios of Amazonian economic development, could significantly alter pathways of PM production that presently prevail over the tropical forest, implying changes to air quality and regional climate.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1363989

Report Number(s):: PNNL-SA--125341; KP1701000

Journal Information:: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Journal Issue: 11 Vol. 17; ISSN 1680-7324

Publisher:: European Geosciences UnionCopyright Statement

Country of Publication:: United States

Language:: English

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Isoprene chemistry in pristine and polluted Amazon environments: Eulerian and Lagrangian model frameworks and the strong bearing they have on our understanding of surface ozone and predictions of rainforest exposure to this priority pollutant Levine, J. G.; MacKenzie, A. R.; Squire, O. J. Atmospheric Chemistry and Physics Discussions, Vol. 15, Issue 17 https://doi.org/10.5194/acpd-15-24251-2015	journal	January 2015
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The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions Guenther, A. B.; Jiang, X.; Heald, C. L. Geoscientific Model Development, Vol. 5, Issue 6 https://doi.org/10.5194/gmd-5-1471-2012	journal	January 2012

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Ground-based observation of clusters and nucleation-mode particles in the Amazon Wimmer, Daniela; Buenrostro Mazon, Stephany; Manninen, Hanna Elina Atmospheric Chemistry and Physics, Vol. 18, Issue 17 https://doi.org/10.5194/acp-18-13245-2018	journal	January 2018
Aircraft-based observations of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) in the tropical upper troposphere over the Amazon region Schulz, Christiane; Schneider, Johannes; Amorim Holanda, Bruna Atmospheric Chemistry and Physics, Vol. 18, Issue 20 https://doi.org/10.5194/acp-18-14979-2018	journal	January 2018
Chemical composition of ultrafine aerosol particles in central Amazonia during the wet season Glicker, Hayley S.; Lawler, Michael J.; Ortega, John Atmospheric Chemistry and Physics, Vol. 19, Issue 20 https://doi.org/10.5194/acp-19-13053-2019	journal	January 2019
Mixing states of Amazon basin aerosol particles transported over long distances using transmission electron microscopy Adachi, Kouji; Oshima, Naga; Gong, Zhaoheng Atmospheric Chemistry and Physics, Vol. 20, Issue 20 https://doi.org/10.5194/acp-20-11923-2020	journal	January 2020
Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A Mouchel-Vallon, Camille; Lee-Taylor, Julia; Hodzic, Alma Atmospheric Chemistry and Physics, Vol. 20, Issue 10 https://doi.org/10.5194/acp-20-5995-2020	journal	May 2020
Limited formation of isoprene epoxydiols-derived secondary organic aerosol under NO _x -rich environments in Eastern China : LIMITED FORMATION OF IEPOX-SOA Zhang, Yunjiang; Tang, Lili; Sun, Yele Geophysical Research Letters https://doi.org/10.1002/2016gl072368	journal	January 2017
Regional Similarities and NO _x ‐Related Increases in Biogenic Secondary Organic Aerosol in Summertime Southeastern United States Liu, Jun; Russell, Lynn M.; Ruggeri, Giulia Journal of Geophysical Research: Atmospheres, Vol. 123, Issue 18 https://doi.org/10.1029/2018jd028491	journal	September 2018
Urban pollution greatly enhances formation of natural aerosols over the Amazon rainforest Shrivastava, Manish; Andreae, Meinrat O.; Artaxo, Paulo Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08909-4	journal	March 2019
Development of a hydrophilic interaction liquid chromatography (HILIC) method for the chemical characterization of water-soluble isoprene epoxydiol (IEPOX)-derived secondary organic aerosol Cui, Tianqu; Zeng, Zhexi; dos Santos, Erickson O. Environmental Science: Processes & Impacts, Vol. 20, Issue 11 https://doi.org/10.1039/c8em00308d	journal	January 2018
Organosulfates in aerosols downwind of an urban region in central Amazon Glasius, Marianne; Bering, Mads S.; Yee, Lindsay D. Environmental Science: Processes & Impacts, Vol. 20, Issue 11 https://doi.org/10.1039/c8em00413g	journal	January 2018
Evaluation of the new capture vaporizer for aerosol mass spectrometers (AMS) through field studies of inorganic species Hu, Weiwei; Campuzano-Jost, Pedro; Day, Douglas A. Aerosol Science and Technology, Vol. 51, Issue 6 https://doi.org/10.1080/02786826.2017.1296104	journal	February 2017
CCN activity and organic hygroscopicity of aerosols downwind of an urban region in central Amazonia: seasonal and diel variations and impact of anthropogenic emissions Thalman, Ryan; de Sá, Suzane S.; Palm, Brett B. Atmospheric Chemistry and Physics, Vol. 17, Issue 19 https://doi.org/10.5194/acp-17-11779-2017	journal	January 2017
Anthropogenic influences on the physical state of submicron particulate matter over a tropical forest Bateman, Adam P.; Gong, Zhaoheng; Harder, Tristan H. Atmospheric Chemistry and Physics, Vol. 17, Issue 3 https://doi.org/10.5194/acp-17-1759-2017	journal	January 2017
Contributions of mobile, stationary and biogenic sources to air pollution in the Amazon rainforest: a numerical study with the WRF-Chem model Abou Rafee, Sameh A.; Martins, Leila D.; Kawashima, Ana B. Atmospheric Chemistry and Physics, Vol. 17, Issue 12 https://doi.org/10.5194/acp-17-7977-2017	journal	January 2017
Multi-year statistical and modeling analysis of submicrometer aerosol number size distributions at a rain forest site in Amazonia Varanda Rizzo, Luciana; Roldin, Pontus; Brito, Joel Atmospheric Chemistry and Physics, Vol. 18, Issue 14 https://doi.org/10.5194/acp-18-10255-2018	journal	January 2018
Observations of sesquiterpenes and their oxidation products in central Amazonia during the wet and dry seasons Yee, Lindsay D.; Isaacman-VanWertz, Gabriel; Wernis, Rebecca A. Atmospheric Chemistry and Physics, Vol. 18, Issue 14 https://doi.org/10.5194/acp-18-10433-2018	journal	January 2018
Aircraft observations of the chemical composition and aging of aerosol in the Manaus urban plume during GoAmazon 2014/5 Shilling, John E.; Pekour, Mikhail S.; Fortner, Edward C. Atmospheric Chemistry and Physics, Vol. 18, Issue 14 https://doi.org/10.5194/acp-18-10773-2018	journal	January 2018
Urban influence on the concentration and composition of submicron particulate matter in central Amazonia de Sá, Suzane S.; Palm, Brett B.; Campuzano-Jost, Pedro Atmospheric Chemistry and Physics, Vol. 18, Issue 16 https://doi.org/10.5194/acp-18-12185-2018	journal	January 2018
Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia Palm, Brett B.; de Sá, Suzane S.; Day, Douglas A. Atmospheric Chemistry and Physics, Vol. 18, Issue 1 https://doi.org/10.5194/acp-18-467-2018	journal	January 2018
Assessing the role of anthropogenic and biogenic sources on PM₁ over southern West Africa using aircraft measurements Brito, Joel; Freney, Evelyn; Dominutti, Pamela Atmospheric Chemistry and Physics, Vol. 18, Issue 2 https://doi.org/10.5194/acp-18-757-2018	journal	January 2018
Contributions of biomass-burning, urban, and biogenic emissions to the concentrations and light-absorbing properties of particulate matter in central Amazonia during the dry season de Sá, Suzane S.; Rizzo, Luciana V.; Palm, Brett B. Atmospheric Chemistry and Physics, Vol. 19, Issue 12 https://doi.org/10.5194/acp-19-7973-2019	journal	January 2019
Assessing the role of anthropogenic and biogenic sources on PM₁ over southern West Africa using aircraft measurements Brito, Joel; Freney, Evelyn; Dominutti, Pamela Karlsruhe https://doi.org/10.5445/ir/1000079354	text	January 2018
Evaluation of the new capture vaporizer for aerosol mass spectrometers (AMS) through field studies of inorganic species Hu, Weiwei; Campuzano-Jost, Pedro; Day, Douglas A. Taylor & Francis https://doi.org/10.6084/m9.figshare.4736371	text	January 2017
Evaluation of the new capture vaporizer for aerosol mass spectrometers (AMS) through field studies of inorganic species Hu, Weiwei; Campuzano-Jost, Pedro; Day, Douglas A. Taylor & Francis https://doi.org/10.6084/m9.figshare.4736371.v1	text	January 2017

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