Multi-component Fe–Ni hydroxide nanocatalyst for oxygen evolution and methanol oxidation reactions under alkaline conditions

Candelaria, Stephanie L.; Bedford, Nicholas M.; Woehl, Taylor J.; Rentz, Nikki S.; Showalter, Allison R.; Pylypenko, Svitlana; Bunker, Bruce A.; Lee, Sungsik; Reinhart, Benjamin; Ren, Yang; Ertem, S. Piril; Coughlin, E. Bryan; Sather, Nicholas A.; Horan, James L.; Herring, Andrew M.; Greenlee, Lauren F.

doi:10.1021/acscatal.6b02552

Title: Multi-component Fe–Ni hydroxide nanocatalyst for oxygen evolution and methanol oxidation reactions under alkaline conditions

Journal Article · Tue Nov 29 00:00:00 EST 2016 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.6b02552· OSTI ID:1363813

Candelaria, Stephanie L. ^[1]; Bedford, Nicholas M. ^[1]; Woehl, Taylor J. ^[1]; Rentz, Nikki S. ^[1]; Showalter, Allison R. ^[2]; Pylypenko, Svitlana ^[3]; Bunker, Bruce A. ^[2]; Lee, Sungsik ^[4]; Reinhart, Benjamin ^[4]; Ren, Yang ^[4]; Ertem, S. Piril ^[5]; Coughlin, E. Bryan ^[5]; Sather, Nicholas A. ^[6]; Horan, James L. ^[3];

^[3];

^[7]

National Institute of Standard and Technology, Boulder, CO (United States)
Univ. of Notre Dame, Notre Dame, IN (United States)
Colorado School of Mines, Golden, CO (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of Massachusetts, Amherst, MA (United States)
Colorado School of Mines, Golden, CO (United States); Northwestern Univ., Evanston, IL (United States)
National Institute of Standard and Technology, Boulder, CO (United States); Univ. of Arkansas, Fayetteville, AR (United States)

Here, iron-incorporated nickel-based materials show promise as catalysts for the oxygen evolution reac-tion (OER) half-reaction of water electrolysis. Nickel has also exhibited high catalytic activity for methanol oxidation, particularly when in the form of a bimetallic catalyst. In this work, bimetallic iron-nickel nanoparticles were synthesized using a multi-step procedure in water under ambient conditions. When compared to monometallic iron and nickel nanoparticles, Fe-Ni nanoparticles show enhanced catalytic activity for both OER and methanol oxidation under alkaline conditions. At 1 mA/cm², the overpotential for monometallic iron and nickel nanoparticles was 421 mV and 476 mV, respectively, while the bimetallic Fe-Ni nanoparticles had a greatly reduced overpotential of 256 mV. At 10 mA/cm², bimetallic Fe-Ni nanoparticles had an overpotential of 311 mV. Spec-troscopy characterization suggests that the primary phase of nickel in Fe-Ni nanoparticles is the more disordered alpha phase of nickel hydroxide.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Institute of Standards and Technology (NIST); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES); U.S. Army Research Laboratory, U.S. Army Research Office (ARO)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1363813

Journal Information:: ACS Catalysis, Vol. 7, Issue 1; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 126 works

Citation information provided by
Web of Science

References (107)

Sustainable Hydrogen Production Turner, J. A. Science, Vol. 305, Issue 5686 https://doi.org/10.1126/science.1103197	journal	August 2004
Will Solar-Driven Water-Splitting Devices See the Light of Day? McKone, James R.; Lewis, Nathan S.; Gray, Harry B. Chemistry of Materials, Vol. 26, Issue 1 https://doi.org/10.1021/cm4021518	journal	September 2013
Hydrogen Production From Water Electrolysis: Current Status and Future Trends Ursua, Alfredo; Gandia, Luis M.; Sanchis, Pablo Proceedings of the IEEE, Vol. 100, Issue 2 https://doi.org/10.1109/JPROC.2011.2156750	journal	February 2012
Solar Water Splitting Cells Walter, Michael G.; Warren, Emily L.; McKone, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473 https://doi.org/10.1021/cr1002326	journal	November 2010
Precise oxygen evolution catalysts: Status and opportunities Trotochaud, Lena; Boettcher, Shannon W. Scripta Materialia, Vol. 74 https://doi.org/10.1016/j.scriptamat.2013.07.019	journal	March 2014
Detonator of the population explosion Smil, Vaclav Nature, Vol. 400, Issue 6743 https://doi.org/10.1038/22672	journal	July 1999
Towards a carbon independent and CO ₂ -free electrochemical membrane process for NH ₃ synthesis Kugler, K.; Ohs, B.; Scholz, M. Phys. Chem. Chem. Phys., Vol. 16, Issue 13 https://doi.org/10.1039/c4cp00173g	journal	January 2014
Chemical looping of metal nitride catalysts: low-pressure ammonia synthesis for energy storage Michalsky, R.; Avram, A. M.; Peterson, B. A. Chemical Science, Vol. 6, Issue 7 https://doi.org/10.1039/C5SC00789E	journal	January 2015
Synthesis of ammonia directly from wet air at intermediate temperature Lan, Rong; Alkhazmi, Khaled A.; Amar, Ibrahim A. Applied Catalysis B: Environmental, Vol. 152-153 https://doi.org/10.1016/j.apcatb.2014.01.037	journal	June 2014
Persistent growth of CO2 emissions and implications for reaching climate targets Friedlingstein, P.; Andrew, R. M.; Rogelj, J. Nature Geoscience, Vol. 7, Issue 10 https://doi.org/10.1038/ngeo2248	journal	September 2014
Exploring global changes in nitrogen and phosphorus cycles in agriculture induced by livestock production over the 1900-2050 period Bouwman, L.; Goldewijk, K. K.; Van Der Hoek, K. W. Proceedings of the National Academy of Sciences, Vol. 110, Issue 52 https://doi.org/10.1073/pnas.1012878108	journal	May 2011
On the use of ammonia electrolysis for hydrogen production Vitse, Frédéric; Cooper, Matt; Botte, Gerardine G. Journal of Power Sources, Vol. 142, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2004.09.043	journal	March 2005
Electrolysis of liquid ammonia for hydrogen generation Little, Daniel J.; Smith, III, Milton R.; Hamann, Thomas W. Energy & Environmental Science, Vol. 8, Issue 9 https://doi.org/10.1039/C5EE01840D	journal	January 2015
Ammonia as a Suitable Fuel for Fuel Cells Lan, Rong; Tao, Shanwen Frontiers in Energy Research, Vol. 2 https://doi.org/10.3389/fenrg.2014.00035	journal	August 2014
A mini review of NiFe-based materials as highly active oxygen evolution reaction electrocatalysts Gong, Ming; Dai, Hongjie Nano Research, Vol. 8, Issue 1 https://doi.org/10.1007/s12274-014-0591-z	journal	November 2014
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis Hong, Wesley T.; Risch, Marcel; Stoerzinger, Kelsey A. Energy & Environmental Science, Vol. 8, Issue 5 https://doi.org/10.1039/C4EE03869J	journal	January 2015
Surface Oxidation of Stainless Steel: Oxygen Evolution Electrocatalysts with High Catalytic Activity Schäfer, Helmut; Beladi-Mousavi, Seyyed Mohsen; Walder, Lorenz ACS Catalysis, Vol. 5, Issue 4 https://doi.org/10.1021/acscatal.5b00221	journal	March 2015
Ultrathin Two-Dimensional Free-Standing Sandwiched NiFe/C for High-Efficiency Oxygen Evolution Reaction Feng, Yangyang; Zhang, Huijuan; Zhang, Yan ACS Applied Materials & Interfaces, Vol. 7, Issue 17 https://doi.org/10.1021/acsami.5b01467	journal	April 2015
Nonstoichiometric Oxides as Low-Cost and Highly-Efficient Oxygen Reduction/Evolution Catalysts for Low-Temperature Electrochemical Devices Chen, Dengjie; Chen, Chi; Baiyee, Zarah Medina Chemical Reviews, Vol. 115, Issue 18 https://doi.org/10.1021/acs.chemrev.5b00073	journal	August 2015
Electrocatalysis by oxides — Attempt at a unifying approach Trasatti, Sergio Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 111, Issue 1 https://doi.org/10.1016/S0022-0728(80)80084-2	journal	July 1980
Synthesis and Activities of Rutile IrO ₂ and RuO ₂ Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions Lee, Youngmin; Suntivich, Jin; May, Kevin J. The Journal of Physical Chemistry Letters, Vol. 3, Issue 3 https://doi.org/10.1021/jz2016507	journal	January 2012
Oxygen Evolution Reaction Electrocatalysis on Transition Metal Oxides and (Oxy)hydroxides: Activity Trends and Design Principles Burke, Michaela S.; Enman, Lisa J.; Batchellor, Adam S. Chemistry of Materials, Vol. 27, Issue 22 https://doi.org/10.1021/acs.chemmater.5b03148	journal	October 2015
Revised Oxygen Evolution Reaction Activity Trends for First-Row Transition-Metal (Oxy)hydroxides in Alkaline Media Burke, Michaela S.; Zou, Shihui; Enman, Lisa J. The Journal of Physical Chemistry Letters, Vol. 6, Issue 18 https://doi.org/10.1021/acs.jpclett.5b01650	journal	August 2015
Coordination tuning of cobalt phosphates towards efficient water oxidation catalyst Kim, Hyunah; Park, Jimin; Park, Inchul Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9253	journal	September 2015
Nature of Activated Manganese Oxide for Oxygen Evolution Huynh, Michael; Shi, Chenyang; Billinge, Simon J. L. Journal of the American Chemical Society, Vol. 137, Issue 47 https://doi.org/10.1021/jacs.5b06382	journal	November 2015
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja407115p	journal	October 2013
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
Contributions to activity enhancement via Fe incorporation in Ni-(oxy)hydroxide/borate catalysts for near-neutral pH oxygen evolution Smith, Adam M.; Trotochaud, Lena; Burke, Michaela S. Chemical Communications, Vol. 51, Issue 25 https://doi.org/10.1039/C4CC08670H	journal	January 2015
Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting Friebel, Daniel; Louie, Mary W.; Bajdich, Michal Journal of the American Chemical Society, Vol. 137, Issue 3 https://doi.org/10.1021/ja511559d	journal	January 2015
Effects of Fe Electrolyte Impurities on Ni(OH) ₂ /NiOOH Structure and Oxygen Evolution Activity Klaus, Shannon; Cai, Yun; Louie, Mary W. The Journal of Physical Chemistry C, Vol. 119, Issue 13 https://doi.org/10.1021/acs.jpcc.5b00105	journal	March 2015
An Investigation of Thin-Film Ni–Fe Oxide Catalysts for the Electrochemical Evolution of Oxygen Louie, Mary W.; Bell, Alexis T. Journal of the American Chemical Society, Vol. 135, Issue 33 https://doi.org/10.1021/ja405351s	journal	August 2013
Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation Trotochaud, Lena; Young, Samantha L.; Ranney, James K. Journal of the American Chemical Society, Vol. 136, Issue 18 https://doi.org/10.1021/ja502379c	journal	April 2014
The Catalysis of the Oxygen Evolution Reaction by Iron Impurities in Thin Film Nickel Oxide Electrodes Corrigan, Dennis A. Journal of The Electrochemical Society, Vol. 134, Issue 2 https://doi.org/10.1149/1.2100463	journal	January 1987
Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution Trotochaud, Lena; Ranney, James K.; Williams, Kerisha N. Journal of the American Chemical Society, Vol. 134, Issue 41 https://doi.org/10.1021/ja307507a	journal	October 2012
Characteristics of the Synthesis of Methanol Using Biomass-Derived Syngas Yin, Xiuli; Leung, Dennis Y. C.; Chang, Jie Energy & Fuels, Vol. 19, Issue 1 https://doi.org/10.1021/ef0498622	journal	January 2005
Methanol and hydrogen from biomass for transportation Williams, Robert H.; Larson, Eric D.; Katofsky, Ryan E. Energy for Sustainable Development, Vol. 1, Issue 5 https://doi.org/10.1016/S0973-0826(08)60083-6	journal	January 1995
Palladium-Based Nanomaterials: Synthesis and Electrochemical Applications Chen, Aicheng; Ostrom, Cassandra Chemical Reviews, Vol. 115, Issue 21 https://doi.org/10.1021/acs.chemrev.5b00324	journal	September 2015
Anode Catalysts for Direct Methanol Fuel Cells in Acidic Media: Do We Have Any Alternative for Pt or Pt–Ru? Kakati, Nitul; Maiti, Jatindranath; Lee, Seok Hee Chemical Reviews, Vol. 114, Issue 24 https://doi.org/10.1021/cr400389f	journal	November 2014
Electrochemical Fabrication of Porous Ni _0.5 Co _0.5 Alloy Film and Its Enhanced Electrocatalytic Activity towards Methanol Oxidation Cui, Xun; Yang, Yang; Li, Yanhong Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0401514jes	journal	January 2015
Carbon nanofibers doped by Ni x Co 1−x alloy nanoparticles as effective and stable non precious electrocatalyst for methanol oxidation in alkaline media Barakat, Nasser A. M.; Motlak, Moaaed; Kim, Byoung-Suhk Journal of Molecular Catalysis A: Chemical, Vol. 394 https://doi.org/10.1016/j.molcata.2014.07.011	journal	November 2014
Electro-oxidation of methanol on mesoporous nickel phosphate modified GCE Yang, Jinghe; Tan, Juan; Yang, Fei Electrochemistry Communications, Vol. 23 https://doi.org/10.1016/j.elecom.2012.06.006	journal	September 2012
Ni nanoparticle modified graphite electrode for methanol electrocatalytic oxidation in alkaline media Ferdowsi, Gh. S.; Seyedsadjadi, S. A.; Ghaffarinejad, A. Journal of Nanostructure in Chemistry, Vol. 5, Issue 1 https://doi.org/10.1007/s40097-014-0124-z	journal	September 2014
Ni–P and Ni–Cu–P modified carbon catalysts for methanol electro-oxidation in KOH solution Hameed, R. M. Abdel; El-Khatib, K. M. International Journal of Hydrogen Energy, Vol. 35, Issue 6 https://doi.org/10.1016/j.ijhydene.2009.12.145	journal	March 2010
One – Step synthesis of nitrogen doped reduced graphene oxide with NiCo nanoparticles for ethanol oxidation in alkaline media Kakaei, Karim; Marzang, Kamaran Journal of Colloid and Interface Science, Vol. 462 https://doi.org/10.1016/j.jcis.2015.09.072	journal	January 2016
ELECTROCHEMICAL OXIDATION OF ETHANOL USING Ni-Co-PVC COMPOSITE ELECTRODE Riyanto, Riyanto; Othman, Mohamed Rozali; Salimon, Jumat Indonesian Journal of Chemistry, Vol. 11, Issue 1 https://doi.org/10.22146/ijc.21424	journal	March 2011
Thermally Cross-Linked Anion Exchange Membranes from Solvent Processable Isoprene Containing Ionomers Tsai, Tsung-Han; Ertem, S. Piril; Maes, Ashley M. Macromolecules, Vol. 48, Issue 3 https://doi.org/10.1021/ma502362a	journal	January 2015
Development of stabilized zero valent iron nanoparticles Greenlee, Lauren F.; Hooker, Stephanie A. Desalination and Water Treatment, Vol. 37, Issue 1-3 https://doi.org/10.1080/19443994.2012.661262	journal	January 2012
Influence of synthesis parameters on iron nanoparticle size and zeta potential Goldstein, Nikki; Greenlee, Lauren F. Journal of Nanoparticle Research, Vol. 14, Issue 4 https://doi.org/10.1007/s11051-012-0760-5	journal	March 2012
ATMP-stabilized iron nanoparticles: chelator-controlled nanoparticle synthesis Greenlee, Lauren F.; Rentz, Nikki S. Journal of Nanoparticle Research, Vol. 16, Issue 11 https://doi.org/10.1007/s11051-014-2712-8	journal	November 2014
Kinetics of Zero Valent Iron Nanoparticle Oxidation in Oxygenated Water Greenlee, Lauren F.; Torrey, Jessica D.; Amaro, Robert L. Environmental Science & Technology, Vol. 46, Issue 23 https://doi.org/10.1021/es303037k	journal	November 2012
Kinetic Studies of Reaction between Sodium Borohydride and Methanol, Water, and Their Mixtures Lo, Chih-ting F.; Karan, Kunal; Davis, Boyd R. Industrial & Engineering Chemistry Research, Vol. 46, Issue 17 https://doi.org/10.1021/ie0608861	journal	July 2007
Stability and phase transfer of catalytically active platinum nanoparticle suspensions Sriram, Indira; Curtin, Alexandra E.; Chiaramonti, Ann N. Journal of Nanoparticle Research, Vol. 17, Issue 5 https://doi.org/10.1007/s11051-015-3034-1	journal	May 2015
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
RAD, a program for analysis of X-ray diffraction data from amorphous materials for personal computers Petkov, V. Journal of Applied Crystallography, Vol. 22, Issue 4, p. 387-389 https://doi.org/10.1107/S0021889889002104	journal	August 1989
Tolerance of glucose electrocatalytic oxidation on NiO x /MnO x /GC electrode to poisoning by halides El-Refaei, S. M.; Saleh, M. M.; Awad, M. I. Journal of Solid State Electrochemistry, Vol. 18, Issue 1 https://doi.org/10.1007/s10008-013-2205-1	journal	August 2013
Efficient Pt/carbon electrocatalysts for proton exchange membrane fuel cells: Avoid chloride-based Pt salts! Job, Nathalie; Chatenet, Marian; Berthon-Fabry, Sandrine Journal of Power Sources, Vol. 240 https://doi.org/10.1016/j.jpowsour.2013.03.188	journal	October 2013
Size-Dependent Sulfur Poisoning of Silica-Supported Monodisperse Pt Nanoparticle Hydrogenation Catalysts Baldyga, Lyndsey M.; Blavo, Selasi O.; Kuo, Chun-Hong ACS Catalysis, Vol. 2, Issue 12 https://doi.org/10.1021/cs300625m	journal	November 2012
Poison-Tolerant Fuel Cells Selman, J. R. Science, Vol. 326, Issue 5949 https://doi.org/10.1126/science.1180820	journal	October 2009
Highly stable Pt monolayer on PdAu nanoparticle electrocatalysts for the oxygen reduction reaction Sasaki, Kotaro; Naohara, Hideo; Choi, YongMan Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2124	journal	January 2012
Platinum-Alloy Cathode Catalyst Degradation in Proton Exchange Membrane Fuel Cells: Nanometer-Scale Compositional and Morphological Changes Chen, Shuo; Gasteiger, Hubert A.; Hayakawa, Katsuichiro Journal of The Electrochemical Society, Vol. 157, Issue 1 https://doi.org/10.1149/1.3258275	journal	January 2010
Compositional and Morphological Changes of Ordered Pt _x Fe _y /C Oxygen Electroreduction Catalysts Chen, Liang; Chan, Mickey C. Y.; Nan, Feihong ChemCatChem, Vol. 5, Issue 6 https://doi.org/10.1002/cctc.201200614	journal	March 2013
Nanostructured platinum-free electrocatalysts in alkaline direct alcohol fuel cells: catalyst design, principles and applications Ozoemena, Kenneth Ikechukwu RSC Advances, Vol. 6, Issue 92 https://doi.org/10.1039/C6RA15057H	journal	January 2016
Predicted Trends of Core−Shell Preferences for 132 Late Transition-Metal Binary-Alloy Nanoparticles Wang, Lin-Lin; Johnson, Duane D. Journal of the American Chemical Society, Vol. 131, Issue 39 https://doi.org/10.1021/ja903247x	journal	October 2009
Surface segregation in jellium binary solid solutions Yamauchi, H. Physical Review B, Vol. 31, Issue 12 https://doi.org/10.1103/PhysRevB.31.7688	journal	June 1985
Role of Catalyst Preparation on the Electrocatalytic Activity of Ni _{1– x} Fe _x OOH for the Oxygen Evolution Reaction Klaus, Shannon; Louie, Mary W.; Trotochaud, Lena The Journal of Physical Chemistry C, Vol. 119, Issue 32 https://doi.org/10.1021/acs.jpcc.5b04776	journal	August 2015
Oxidation of metal nanoparticles: Experiment and model Chernavskii, P. A.; Peskov, N. V.; Mugtasimov, A. V. Russian Journal of Physical Chemistry B, Vol. 1, Issue 4 https://doi.org/10.1134/S1990793107040082	journal	August 2007
Theory of the oxidation of metals Cabrera, N.; Mott, N. F. Reports on Progress in Physics, Vol. 12, Issue 1 https://doi.org/10.1088/0034-4885/12/1/308	journal	January 1949
Kinetics of Oxide Film Growth on Metal Crystals: Electron Tunneling and Ionic Diffusion Fromhold, A. T.; Cook, Earl L. Physical Review, Vol. 158, Issue 3 https://doi.org/10.1103/PhysRev.158.600	journal	June 1967
Use of XPS in the determination of chemical environment and oxidation state of iron and sulfur samples: constitution of a data basis in binding energies for Fe and S reference compounds and applications to the evidence of surface species of an oxidized pyrite in a carbonate medium Descostes, M.; Mercier, F.; Thromat, N. Applied Surface Science, Vol. 165, Issue 4 https://doi.org/10.1016/S0169-4332(00)00443-8	journal	October 2000
X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems Biesinger, Mark C.; Payne, Brad P.; Lau, Leo W. M. Surface and Interface Analysis, Vol. 41, Issue 4 https://doi.org/10.1002/sia.3026	journal	April 2009
New interpretations of XPS spectra of nickel metal and oxides Grosvenor, Andrew P.; Biesinger, Mark C.; Smart, Roger St. C. Surface Science, Vol. 600, Issue 9 https://doi.org/10.1016/j.susc.2006.01.041	journal	May 2006
Size-controlled synthesis and characterization of thiol-stabilized gold nanoparticles Frenkel, A. I.; Nemzer, S.; Pister, I. The Journal of Chemical Physics, Vol. 123, Issue 18 https://doi.org/10.1063/1.2126666	journal	November 2005
Identifying the Atomic-Level Effects of Metal Composition on the Structure and Catalytic Activity of Peptide-Templated Materials Merrill, Nicholas A.; McKee, Erik M.; Merino, Kyle C. ACS Nano, Vol. 9, Issue 12 https://doi.org/10.1021/acsnano.5b04665	journal	October 2015
The effect of gold particle size on AuAu bond length and reactivity toward oxygen in supported catalysts Miller, J. T.; Kropf, A. J.; Zha, Y. Journal of Catalysis, Vol. 240, Issue 2 https://doi.org/10.1016/j.jcat.2006.04.004	journal	June 2006
Nanostructure by high-energy X-ray diffraction Petkov, Valeri Materials Today, Vol. 11, Issue 11 https://doi.org/10.1016/S1369-7021(08)70236-0	journal	November 2008
Beyond crystallography: the study of disorder, nanocrystallinity and crystallographically challenged materials with pair distribution functions Billinge, Simon J. L.; Kanatzidis, M. G. Chemical Communications, Issue 7 https://doi.org/10.1039/b309577k	journal	January 2004
Structural Evolution of Iron Antimonides from Amorphous Precursors to Crystalline Products Studied by Total Scattering Techniques Bauers, Sage R.; Wood, Suzannah R.; Jensen, Kirsten M. Ø. Journal of the American Chemical Society, Vol. 137, Issue 30 https://doi.org/10.1021/jacs.5b04838	journal	July 2015
Three-dimensional structure of multicomponent (Na ₂ O) _0.35 [(P ₂ O ₅ ) _{1 − x} (B ₂ O ₃ ) _x ] _0.65 glasses by high-energy x-ray diffraction and constrained reverse Monte Carlo simulations Roux, Sébastien Le; Martin, Steve; Christensen, Randi Journal of Physics: Condensed Matter, Vol. 23, Issue 3 https://doi.org/10.1088/0953-8984/23/3/035403	journal	January 2011
Atomic pair distribution functions analysis of disordered low-Z materials Petkov, V.; Ren, Y.; Kabekkodu, S. Physical Chemistry Chemical Physics, Vol. 15, Issue 22 https://doi.org/10.1039/c2cp43378h	journal	January 2013
Benchmark oxygen-oxygen pair-distribution function of ambient water from x-ray diffraction measurements with a wide Q -range Skinner, Lawrie B.; Huang, Congcong; Schlesinger, Daniel The Journal of Chemical Physics, Vol. 138, Issue 7 https://doi.org/10.1063/1.4790861	journal	February 2013
Quantitative size-dependent structure and strain determination of CdSe nanoparticles using atomic pair distribution function analysis Masadeh, A. S.; Božin, E. S.; Farrow, C. L. Physical Review B, Vol. 76, Issue 11 https://doi.org/10.1103/PhysRevB.76.115413	journal	September 2007
Ab initio determination of solid-state nanostructure Juhás, P.; Cherba, D. M.; Duxbury, P. M. Nature, Vol. 440, Issue 7084 https://doi.org/10.1038/nature04556	journal	March 2006
Structure of Nanocrystalline ${Ti}_{3} C_{2}$ MXene Using Atomic Pair Distribution Function Shi, Chenyang; Beidaghi, Majid; Naguib, Michael Physical Review Letters, Vol. 112, Issue 12 https://doi.org/10.1103/PhysRevLett.112.125501	journal	March 2014
Elucidation of Peptide-Directed Palladium Surface Structure for Biologically Tunable Nanocatalysts Bedford, Nicholas M.; Ramezani-Dakhel, Hadi; Slocik, Joseph M. ACS Nano, Vol. 9, Issue 5 https://doi.org/10.1021/acsnano.5b00168	journal	May 2015
On the road to metallic nanoparticles by rational design: bridging the gap between atomic-level theoretical modeling and reality by total scattering experiments Prasai, Binay; Wilson, A. R.; Wiley, B. J. Nanoscale, Vol. 7, Issue 42 https://doi.org/10.1039/C5NR04678E	journal	January 2015
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes Liu, H.; Strobridge, F. C.; Borkiewicz, O. J. Science, Vol. 344, Issue 6191 https://doi.org/10.1126/science.1252817	journal	June 2014
Sequence-Dependent Structure/Function Relationships of Catalytic Peptide-Enabled Gold Nanoparticles Generated under Ambient Synthetic Conditions Bedford, Nicholas M.; Hughes, Zak E.; Tang, Zhenghua Journal of the American Chemical Society, Vol. 138, Issue 2 https://doi.org/10.1021/jacs.5b09529	journal	December 2015
Synthesis-atomic structure-properties relationships in metallic nanoparticles by total scattering experiments and 3D computer simulations: case of Pt–Ru nanoalloy catalysts Prasai, Binay; Ren, Yang; Shan, Shiyao Nanoscale, Vol. 7, Issue 17 https://doi.org/10.1039/C5NR00800J	journal	January 2015
Correlating Structure and Function of Metal Nanoparticles for Catalysis Zhang, Liang; Anderson, Rachel M.; Crooks, Richard M. Surface Science, Vol. 640 https://doi.org/10.1016/j.susc.2015.03.018	journal	October 2015
Surface- and Structure-Dependent Catalytic Activity of Au Nanoparticles for Oxygen Reduction Reaction ^† Lee, Youngmin; Loew, Aviva; Sun, Shouheng Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm9013046	journal	February 2010
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli Nature Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/nchem.623	journal	April 2010
Origin of Oxygen Reduction Reaction Activity on “Pt ₃ Co” Nanoparticles: Atomically Resolved Chemical Compositions and Structures Chen, Shuo; Sheng, Wenchao; Yabuuchi, Naoaki The Journal of Physical Chemistry C, Vol. 113, Issue 3 https://doi.org/10.1021/jp807143e	journal	December 2008
Characterization of iron oxides by x-ray absorption at the oxygen K edgeusing a full multiple-scattering approach Wu, Z. Y.; Gota, S.; Jollet, F. Physical Review B, Vol. 55, Issue 4 https://doi.org/10.1103/PhysRevB.55.2570	journal	January 1997
Nickel-Based Alloys as Electrocatalysts for Oxygen Evolution from Alkaline Solutions Lu, P. W. T. Journal of The Electrochemical Society, Vol. 125, Issue 2 https://doi.org/10.1149/1.2131426	journal	January 1978
Electrochemical Quartz Microbalance characterization of Ni(OH)2-based thin film electrodes Wehrens-Dijksma, M.; Notten, P. H. L. Electrochimica Acta, Vol. 51, Issue 18 https://doi.org/10.1016/j.electacta.2005.10.022	journal	May 2006
Enhanced oxygen evolution at hydrous nickel oxide electrodes via electrochemical ageing in alkaline solution Godwin, I. J.; Lyons, M. E. G. Electrochemistry Communications, Vol. 32 https://doi.org/10.1016/j.elecom.2013.03.040	journal	July 2013
Efficient Water Oxidation Using Nanostructured α-Nickel-Hydroxide as an Electrocatalyst Gao, Minrui; Sheng, Wenchao; Zhuang, Zhongbin Journal of the American Chemical Society, Vol. 136, Issue 19 https://doi.org/10.1021/ja502128j	journal	May 2014
Dual-sized NiFe layered double hydroxides in situ grown on oxygen-decorated self-dispersal nanocarbon as enhanced water oxidation catalysts Zhu, Xiaolin; Tang, Cheng; Wang, Hao-Fan Journal of Materials Chemistry A, Vol. 3, Issue 48 https://doi.org/10.1039/C5TA08019C	journal	January 2015
Hierarchical construction of an ultrathin layered double hydroxide nanoarray for highly-efficient oxygen evolution reaction Yang, Qiu; Li, Tian; Lu, Zhiyi Nanoscale, Vol. 6, Issue 20 https://doi.org/10.1039/C4NR03371J	journal	January 2014
Facile synthesis of thin NiFe-layered double hydroxides nanosheets efficient for oxygen evolution Yan, Kai; Lafleur, Todd; Chai, Jiajue Electrochemistry Communications, Vol. 62 https://doi.org/10.1016/j.elecom.2015.11.004	journal	January 2016
Facile synthesis of Fe/Ni bimetallic oxide solid-solution nanoparticles with superior electrocatalytic activity for oxygen evolution reaction Wang, Lingxiao; Geng, Jing; Wang, Wenhai Nano Research, Vol. 8, Issue 12 https://doi.org/10.1007/s12274-015-0881-0	journal	October 2015
Spatially Confined Hybridization of Nanometer-Sized NiFe Hydroxides into Nitrogen-Doped Graphene Frameworks Leading to Superior Oxygen Evolution Reactivity Tang, Cheng; Wang, Han-Sen; Wang, Hao-Fan Advanced Materials, Vol. 27, Issue 30 https://doi.org/10.1002/adma.201501901	journal	June 2015
Carbon Quantum Dot/NiFe Layered Double-Hydroxide Composite as a Highly Efficient Electrocatalyst for Water Oxidation Tang, Di; Liu, Juan; Wu, Xuanyu ACS Applied Materials & Interfaces, Vol. 6, Issue 10 https://doi.org/10.1021/am501256x	journal	April 2014
Pulse-Electrodeposited Ni–Fe (Oxy)hydroxide Oxygen Evolution Electrocatalysts with High Geometric and Intrinsic Activities at Large Mass Loadings Batchellor, Adam S.; Boettcher, Shannon W. ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01551	journal	October 2015
Electrooxidation of methanol on NiMn alloy modified graphite electrode Danaee, I.; Jafarian, M.; Mirzapoor, A. Electrochimica Acta, Vol. 55, Issue 6 https://doi.org/10.1016/j.electacta.2009.11.039	journal	February 2010
Methanol electrooxidation on a nickel electrode modified by nickel–dimethylglyoxime complex formed by electrochemical synthesis Golikand, Ahmad Nozad; Asgari, Mehdi; Maragheh, Mohammad Ghannadi Journal of Electroanalytical Chemistry, Vol. 588, Issue 1 https://doi.org/10.1016/j.jelechem.2005.11.033	journal	March 2006
Understanding the electro-catalytic oxidation mechanism of urea on nickel electrodes in alkaline medium Vedharathinam, Vedasri; Botte, Gerardine G. Electrochimica Acta, Vol. 81 https://doi.org/10.1016/j.electacta.2012.07.007	journal	October 2012

Cited By (21)

Controlling the 3-D morphology of Ni–Fe-based nanocatalysts for the oxygen evolution reaction Manso, Ryan H.; Acharya, Prashant; Deng, Shiqing Nanoscale, Vol. 11, Issue 17 https://doi.org/10.1039/c8nr10138h	journal	January 2019
Self-template synthesis of defect-rich NiO nanotubes as efficient electrocatalysts for methanol oxidation reaction Wang, Tian-Jiao; Huang, Hao; Wu, Xin-Ru Nanoscale, Vol. 11, Issue 42 https://doi.org/10.1039/c9nr06304h	journal	January 2019
Heteroatom (P, B, or S) incorporated NiFe-based nanocubes as efficient electrocatalysts for the oxygen evolution reaction Xuan, Cuijuan; Wang, Jie; Xia, Weiwei Journal of Materials Chemistry A, Vol. 6, Issue 16 https://doi.org/10.1039/c8ta00410b	journal	January 2018
Removal of Synthetic Azo Dye Using Bimetallic Nickel-Iron Nanoparticles Foster, Shelby L.; Estoque, Katie; Voecks, Michael Journal of Nanomaterials, Vol. 2019 https://doi.org/10.1155/2019/9807605	journal	March 2019
Selective Etching Induced Synthesis of Hollow Rh Nanospheres Electrocatalyst for Alcohol Oxidation Reactions Kang, Yong-Qiang; Xue, Qi; Zhao, Yue Small, Vol. 14, Issue 29 https://doi.org/10.1002/smll.201801239	journal	June 2018
Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction Kim, Ju Seong; Kim, Byunghoon; Kim, Hyunah Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702774	journal	January 2018
Ultralow Fe ^III Ion Doping Triggered Generation of Ni ₃ S ₂ Ultrathin Nanosheet for Enhanced Oxygen Evolution Reaction Wang, Liyuan; Li, Yibin; Sun, Qiangqiang ChemCatChem, Vol. 11, Issue 7 https://doi.org/10.1002/cctc.201801959	journal	March 2019
Hierarchical Nickel–Cobalt‐Based Transition Metal Oxide Catalysts for the Electrochemical Conversion of Biomass into Valuable Chemicals Gao, Lifang; Bao, Yu; Gan, Shiyu ChemSusChem, Vol. 11, Issue 15 https://doi.org/10.1002/cssc.201800695	journal	July 2018
Highly Active Ternary Nickel–Iron oxide as Bifunctional Catalyst for Electrochemical Water Splitting Dalai, Namita; Mohanty, Bishnupad; Mitra, Arijit ChemistrySelect, Vol. 4, Issue 27 https://doi.org/10.1002/slct.201901465	journal	July 2019
Facile fabrication of bimetallic Cu–Ag binary hybrid nanoparticles and their application in catalysis Meng, Yuxi; Gao, Hanyu; Li, Shuang New Journal of Chemistry, Vol. 43, Issue 17 https://doi.org/10.1039/c9nj00816k	journal	January 2019
Colloidal Ni–Co–Sn nanoparticles as efficient electrocatalysts for the methanol oxidation reaction Li, Junshan; Luo, Zhishan; He, Feng Journal of Materials Chemistry A, Vol. 6, Issue 45 https://doi.org/10.1039/c8ta08242a	journal	January 2018
Bifunctional CoNi/CoFe ₂ O ₄ /Ni foam electrodes for efficient overall water splitting at a high current density Li, Shasha; Sirisomboonchai, Suchada; Yoshida, Akihiro Journal of Materials Chemistry A, Vol. 6, Issue 39 https://doi.org/10.1039/c8ta08223e	journal	January 2018
Effects of Incorporated Iron or Cobalt on the Ethanol Oxidation Activity of Nickel (Oxy)Hydroxides in Alkaline Media Martín-Yerga, Daniel; Henriksson, Gunnar; Cornell, Ann Electrocatalysis, Vol. 10, Issue 5 https://doi.org/10.1007/s12678-019-00531-8	journal	April 2019
A facile, one-step electroless deposition of NiFeOOH nanosheets onto photoanodes for highly durable and efficient solar water oxidation Suryawanshi, Mahesh P.; Shin, Seung Wook; Ghorpade, Uma V. Journal of Materials Chemistry A, Vol. 6, Issue 42 https://doi.org/10.1039/c8ta07343k	journal	January 2018
Platinum Nanoparticle Inclusion into a Carbonized Polymer of Intrinsic Microporosity: Electrochemical Characteristics of a Catalyst for Electroless Hydrogen Peroxide Production Adamik, Robert; Hernández-Ibáñez, Naiara; Iniesta, Jesus Nanomaterials, Vol. 8, Issue 7 https://doi.org/10.3390/nano8070542	journal	July 2018
Ultrathin Two-Dimensional Nanostructured Materials for Highly Efficient Water Oxidation Zhang, Wang; Zhou, Kun Small, Vol. 13, Issue 32 https://doi.org/10.1002/smll.201700806	journal	June 2017
Ultrathin trimetallic metal–organic framework nanosheets for highly efficient oxygen evolution reaction Ding, Mengmeng; Chen, Jing; Jiang, Meiwen Journal of Materials Chemistry A, Vol. 7, Issue 23 https://doi.org/10.1039/c9ta00708c	journal	January 2019
Synergistic Supports Beyond Carbon Black for Polymer Electrolyte Fuel Cell Anodes Huang, Yiyin; Babu, Dickson D.; Wu, Maoxiang ChemCatChem, Vol. 10, Issue 20 https://doi.org/10.1002/cctc.201801094	journal	September 2018
Bifunctional oxygen evolution and supercapacitor electrode with integrated architecture of NiFe-layered double hydroxides and hierarchical carbon framework Chen, Fenggui; Zhang, Liyang; Wu, Huiqing Nanotechnology, Vol. 30, Issue 32 https://doi.org/10.1088/1361-6528/ab178c	journal	May 2019
Chemical Structure of Fe–Ni Nanoparticles for Efficient Oxygen Evolution Reaction Electrocatalysis Acharya, Prashant; Nelson, Zachary J.; Benamara, Mourad ACS Omega, Vol. 4, Issue 17 https://doi.org/10.1021/acsomega.9b01692	journal	October 2019
Rapid Synthesis and Correlative Measurements of Electrocatalytic Nickel/Iron Oxide Nanoparticles Jeerage, Kavita M.; Candelaria, Stephanie L.; Stavis, Samuel M. Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-22609-x	journal	March 2018

Similar Records

Chemical Structure of Fe–Ni Nanoparticles for Efficient Oxygen Evolution Reaction Electrocatalysis

Journal Article · Fri Oct 11 00:00:00 EDT 2019 · ACS Omega · OSTI ID:1363813

Acharya, Prashant; Nelson, Zachary J.; Benamara, Mourad; +7 more

Single-atom implanted two-dimensional MOFs as efficient electrocatalysts for the oxygen evolution reaction

Journal Article · Tue Sep 22 00:00:00 EDT 2020 · Inorganic Chemistry Frontiers (Online) · OSTI ID:1363813

Peng, Rui-Li; Li, Jia-Luo; Wang, Xiao-Ning; +4 more

Introducing Fe ²⁺ into Nickel–Iron Layered Double Hydroxide: Local Structure Modulated Water Oxidation Activity

Journal Article · Wed Jun 27 00:00:00 EDT 2018 · Angewandte Chemie · OSTI ID:1363813

Cai, Zhao; Zhou, Daojin; Wang, Maoyu; +14 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
alcohol oxidation
core-shell nanoparticles
electrocatalyst
fuel cell
non-precious metal
oxygen evolution reaction

Title: Multi-component Fe–Ni hydroxide nanocatalyst for oxygen evolution and methanol oxidation reactions under alkaline conditions

Citation Formats

References (107)

Cited By (21)

Similar Records

Related Subjects