Catalytic hydrosilation of organic esters using manganesecarbonyl acetyl complexes, (L)(CO){sub 4}MnC(O)CH{sub 3} (L=CO,PPh{sub 3})
Journal Article
·
· Journal of the American Chemical Society
- Rensselaer Polytechnic Inst., Troy, NY (United States)
This paper reports that manganese acetyl complexes(L)(CO){sub 4} MnC(O)CH{sub 3} [L = PPh{sub 3}, (1); CO, (2)] catalyze the hydrosilation of esters RC(=O)OR` to give successively silyl acetal RCH(OSiR{sub 3})OR`, then ether RCH{sub 2}OR`{sup 4} or alkoxysilane products RCH{sub 2}OSiR{sub 3}and R`OSiR{sub 3}. 11 refs., 1 tab.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 136261
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 40 Vol. 117; ISSN JACSAT; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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