Element-resolved thermodynamics of magnetocaloric LaFe13–xSix

Gruner, Markus E.; Keune, Werner; Cuenya, B. Roldan; Weis, C.; Landers, Joachim A.; Makarov, S. I.; Klar, David; Hu, M. Y.; Alp, E. E.; Zhao, Jiyong; Krautz, M.; Gutfleisch, O.; Wende, Heiko

doi:10.1103/PhysRevLett.114.057202

Element-resolved thermodynamics of magnetocaloric ${LaFe}_{13 - x} {Si}_{x}$

Journal Article · Wed Feb 04 00:00:00 EST 2015 · Physical Review Letters

DOI:https://doi.org/10.1103/PhysRevLett.114.057202· OSTI ID:1362293

Gruner, Markus E. ^[1]; Keune, Werner ^[2]; Cuenya, B. Roldan ^[3]; Weis, C. ^[4]; Landers, Joachim A. ^[4]; Makarov, S. I. ^[2]; Klar, David ^[4]; Hu, M. Y. ^[5]; Alp, E. E. ^[5]; Zhao, Jiyong ^[5]; Krautz, M. ^[6]; Gutfleisch, O. ^[7]; Wende, Heiko ^[4]

Univ. of Duisburg-Essen, Duisburg (Germany); IFW Dresden, Dresden (Germany)
Univ. of Duisburg-Essen, Duisburg (Germany); Max Planck Institute of Microstructure Physics, Halle (Germany)
Ruhr-Univ. Bochum, Bochum (Germany)
Univ. of Duisburg-Essen, Duisburg (Germany)
Argonne National Lab. (ANL), Argonne, IL (United States)
IFW Dresden, Dresden (Germany)
TU Darmstadt, Darmstadt (Germany)

By combination of two independent approaches, nuclear resonant inelastic x-ray scattering and first-principles calculations in the framework of density functional theory, we demonstrate significant changes in the element-resolved vibrational density of states across the first-order transition from the ferromagnetic low temperature to the paramagnetic high temperature phase of LaFe_13-xSi_x. These changes originate from the itinerant electron metamagnetism associated with Fe and lead to a pronounced magneto-elastic softening despite the large volume decrease at the transition. As a result, the increase in lattice entropy associated with the Fe subsystem is significant and contributes cooperatively with the magnetic and electronic entropy changes to the excellent magneto- and barocaloric properties.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: Argonne National Laboratory - Advanced Photon Source; USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1362293

Alternate ID(s):: OSTI ID: 1180313

Journal Information:: Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 5 Vol. 114; ISSN 0031-9007; ISSN PRLTAO

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (82)

Caloric Effects in Ferroic Materials: New Concepts for Cooling Fähler, Sebastian; Rößler, Ulrich K.; Kastner, Oliver Advanced Engineering Materials, Vol. 14, Issue 1-2 https://doi.org/10.1002/adem.201100178	journal	November 2011
Caloric Effects in Ferroic Materials: New Concepts for Cooling Fähler, Sebastian; Rößler, Ulrich K.; Kastner, Oliver Advanced Engineering Materials, Vol. 14, Issue 1-2 https://doi.org/10.1002/adem.201290005	journal	February 2012
Novel Design of La(Fe,Si)13 Alloys Towards High Magnetic Refrigeration Performance Lyubina, Julia; Schäfer, Rudolf; Martin, Norbert Advanced Materials, Vol. 22, Issue 33 https://doi.org/10.1002/adma.201000177	journal	August 2010
Magnetic Materials and Devices for the 21st Century: Stronger, Lighter, and More Energy Efficient Gutfleisch, Oliver; Willard, Matthew A.; Brück, Ekkes Advanced Materials, Vol. 23, Issue 7 https://doi.org/10.1002/adma.201002180	journal	December 2010
Study of the critical behaviour of the magnetization and electrical resistivity in cubic La(Fe, Si)13 compounds Palstra, T. T. M.; Mydosh, J. A.; Nieuwenhuys, G. J. Journal of Magnetism and Magnetic Materials, Vol. 36, Issue 3 https://doi.org/10.1016/0304-8853(83)90128-2	journal	April 1983
Data analysis for inelastic nuclear resonant absorption experiments Hu, M. Y.; Sturhahn, W.; Toellner, T. S. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 428, Issue 2-3 https://doi.org/10.1016/S0168-9002(99)00134-5	journal	June 1999
Systematic study of the microstructure, entropy change and adiabatic temperature change in optimized La–Fe–Si alloys Liu, Jian; Krautz, Maria; Skokov, Konstantin Acta Materialia, Vol. 59, Issue 9 https://doi.org/10.1016/j.actamat.2011.02.033	journal	May 2011
PHON: A program to calculate phonons using the small displacement method Alfè, Dario Computer Physics Communications, Vol. 180, Issue 12 https://doi.org/10.1016/j.cpc.2009.03.010	journal	December 2009
Neutron diffraction study of LaFe11.31Si1.69 and LaFe11.31Si1.69H1.45 compounds Rosca, M.; Balli, M.; Fruchart, D. Journal of Alloys and Compounds, Vol. 490, Issue 1-2 https://doi.org/10.1016/j.jallcom.2009.10.093	journal	February 2010
Systematic investigation of Mn substituted La(Fe,Si)13 alloys and their hydrides for room-temperature magnetocaloric application Krautz, Maria; Skokov, Konstantin; Gottschall, Tino Journal of Alloys and Compounds, Vol. 598 https://doi.org/10.1016/j.jallcom.2014.02.015	journal	June 2014
Mössbauer spectroscopic evaluation of chemical and electronic distributions in La(Fe0.81Si0.19)13 Hamdeh, H. H.; Al-Ghanem, H.; Hikal, W. M. Journal of Magnetism and Magnetic Materials, Vol. 269, Issue 3 https://doi.org/10.1016/j.jmmm.2003.07.004	journal	March 2004
Hyperfine interactions and band structures of LaFe13−xSix intermetallic compounds with large magnetic entropy changes Wang, Guang-jun; Wang, Fang; Di, Nai-li Journal of Magnetism and Magnetic Materials, Vol. 303, Issue 1 https://doi.org/10.1016/j.jmmm.2005.10.231	journal	August 2006
Magnetic and electronic studies of LaFe13−xSix compounds with 1.3≤x≤1.69 Boutahar, A.; Hlil, E. K.; Lassri, H. Journal of Magnetism and Magnetic Materials, Vol. 347 https://doi.org/10.1016/j.jmmm.2013.07.040	journal	December 2013
Vibrational thermodynamics of materials Fultz, Brent Progress in Materials Science, Vol. 55, Issue 4 https://doi.org/10.1016/j.pmatsci.2009.05.002	journal	May 2010
Magnetocaloric materials: The search for new systems Sandeman, Karl G. Scripta Materialia, Vol. 67, Issue 6 https://doi.org/10.1016/j.scriptamat.2012.02.045	journal	September 2012
Stability of metallic, magnetic and electronic states in NaZn13-type La(FexSi1−x)13 magnetocaloric compounds Fujita, A.; Yako, H. Scripta Materialia, Vol. 67, Issue 6 https://doi.org/10.1016/j.scriptamat.2012.03.033	journal	September 2012
An Application of the “Coloring Problem”: Structure−Composition−Bonding Relationships in the Magnetocaloric Materials LaFe ₁₃ _- _x Si _x Han, Mi-Kyung; Miller, Gordon J. Inorganic Chemistry, Vol. 47, Issue 2 https://doi.org/10.1021/ic701311b	journal	January 2008
Giant Negative Thermal Expansion in NaZn ₁₃ -Type La(Fe, Si, Co) ₁₃ Compounds Huang, Rongjin; Liu, Yanying; Fan, Wei Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja405161z	journal	July 2013
Monochromatization of synchrotron radiation for nuclear resonant scattering experiments Toellner, T. S. Hyperfine Interactions, Vol. 125, Issue 1/4, p. 3-28 https://doi.org/10.1023/A:1012621317798	journal	January 2000
CONUSS and PHOENIX: Evaluation of nuclear resonant scattering data Sturhahn, W. Hyperfine Interactions, Vol. 125, Issue 1/4, p. 149-172 https://doi.org/10.1023/A:1012681503686	journal	March 2000
Experimental aspects of inelastic nuclear resonance scattering Chumakov, A. I.; Sturhahn, W. Hyperfine Interactions, Vol. 123/124, Issue 1/4, p. 781-808 https://doi.org/10.1023/A:1017052730094	journal	January 1999
Experimental results on the pressure dependence of the Grüneisen parameter: A review Boehler, R.; Ramakrishnan, J. Journal of Geophysical Research, Vol. 85, Issue B12 https://doi.org/10.1029/JB085iB12p06996	journal	January 1980
Inverse barocaloric effect in the giant magnetocaloric La–Fe–Si–Co compound Mañosa, Lluís; González-Alonso, David; Planes, Antoni Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1606	journal	September 2011
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets Chen, Ruyi; Cui, Qirui; Liao, Liyang Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23414-3	journal	May 2021
Influence of negative lattice expansion and metamagnetic transition on magnetic entropy change in the compound LaFe11.4Si1.6 Hu, Feng-xia; Shen, Bao-gen; Sun, Ji-rong Applied Physics Letters, Vol. 78, Issue 23 https://doi.org/10.1063/1.1375836	journal	June 2001
Large magnetocaloric effect in La(FexSi1−x)13 itinerant-electron metamagnetic compounds Fujieda, S.; Fujita, A.; Fukamichi, K. Applied Physics Letters, Vol. 81, Issue 7 https://doi.org/10.1063/1.1498148	journal	August 2002
Entropy changes associated with the first-order magnetic transition in LaFe13−xSix Jia, L.; Liu, G. J.; Sun, J. R. Journal of Applied Physics, Vol. 100, Issue 12 https://doi.org/10.1063/1.2404468	journal	December 2006
Phonon softening and metallization of a narrow-gap semiconductor by thermal disorder Delaire, O.; Marty, K.; Stone, M. B. Proceedings of the National Academy of Sciences, Vol. 108, Issue 12 https://doi.org/10.1073/pnas.1014869108	journal	March 2011
Thermal expansion coefficients of LaFe _11.7 Si _1.3 Chang, Hong; Liang, Jing-Kui; Shen, Bao-Gen Journal of Physics D: Applied Physics, Vol. 36, Issue 2 https://doi.org/10.1088/0022-3727/36/2/314	journal	December 2002
Recent developments in magnetocaloric materials Gschneidner, K. A.; Pecharsky, V. K.; Tsokol, A. O. Reports on Progress in Physics, Vol. 68, Issue 6, p. 1479-1539 https://doi.org/10.1088/0034-4885/68/6/R04	journal	May 2005
A calculation of elastic constants of ferromagnetic iron at finite temperatures Hasegawa, H.; Finnis, M. W.; Pettifor, D. G. Journal of Physics F: Metal Physics, Vol. 15, Issue 1 https://doi.org/10.1088/0305-4608/15/1/007	journal	January 1985
Strong interplay between structure and magnetism in the giant magnetocaloric intermetallic compound LaFe _11.4 Si _1.6 : a neutron diffraction study Wang, Fangwei; Wang, Guang-jun; Hu, Feng-xia Journal of Physics: Condensed Matter, Vol. 15, Issue 30 https://doi.org/10.1088/0953-8984/15/30/309	journal	July 2003
Structure and magnetic transition of LaFe _{13 x} Si _x compounds Bo, Liu Xu; Altounian, Z.; Ryan, D. H. Journal of Physics: Condensed Matter, Vol. 15, Issue 43 https://doi.org/10.1088/0953-8984/15/43/020	journal	October 2003
Simulating functional magnetic materials on supercomputers Gruner, Markus Ernst; Entel, Peter Journal of Physics: Condensed Matter, Vol. 21, Issue 29 https://doi.org/10.1088/0953-8984/21/29/293201	journal	June 2009
Large magnetic entropy change and magnetic properties in La (Fe _{1- x} Mn _x ) _11.7 Si _1.3 H _y compounds Fang, Wang; Yuan-Fu, Chen; Guang-Jun, Wang Chinese Physics, Vol. 12, Issue 8 https://doi.org/10.1088/1009-1963/12/8/317	journal	July 2003
Resonance Absorption of Nuclear Gamma Rays and the Dynamics of Atomic Motions Singwi, K. S.; Sjölander, A. Physical Review, Vol. 120, Issue 4 https://doi.org/10.1103/PhysRev.120.1093	journal	November 1960
Inhomogeneous Electron Gas Hohenberg, P.; Kohn, W. Physical Review, Vol. 136, Issue 3B, p. B864-B871 https://doi.org/10.1103/PhysRev.136.B864	journal	November 1964
Anharmonic lattice vibrations in simple metals Rosén, J.; Grimvall, G. Physical Review B, Vol. 27, Issue 12 https://doi.org/10.1103/PhysRevB.27.7199	journal	June 1983
Ferromagnetic phases of bcc and fcc Fe, Co, and Ni Moruzzi, V. L.; Marcus, P. M.; Schwarz, K. Physical Review B, Vol. 34, Issue 3 https://doi.org/10.1103/PhysRevB.34.1784	journal	August 1986
Homology of interatomic forces and Debye temperatures in transition metals Guillermet, A. Fernández; Grimvall, G. Physical Review B, Vol. 40, Issue 3 https://doi.org/10.1103/PhysRevB.40.1521	journal	July 1989
High-precision sampling for Brillouin-zone integration in metals Methfessel, M.; Paxton, A. T. Physical Review B, Vol. 40, Issue 6 https://doi.org/10.1103/PhysRevB.40.3616	journal	August 1989
Electronic, quasiharmonic, and anharmonic entropies of transition metals Eriksson, Olle; Wills, J. M.; Wallace, Duane Physical Review B, Vol. 46, Issue 9 https://doi.org/10.1103/PhysRevB.46.5221	journal	September 1992
First-principles calculations of the instability leading to the Invar effect Entel, P.; Hoffmann, E.; Mohn, P. Physical Review B, Vol. 47, Issue 14 https://doi.org/10.1103/PhysRevB.47.8706	journal	April 1993
Improved tetrahedron method for Brillouin-zone integrations Blöchl, Peter E.; Jepsen, O.; Andersen, O. K. Physical Review B, Vol. 49, Issue 23 https://doi.org/10.1103/PhysRevB.49.16223	journal	June 1994
First-principles theory of short-range order, electronic excitations, and spin polarization in Ni-V and Pd-V alloys Wolverton, C.; Zunger, Alex Physical Review B, Vol. 52, Issue 12 https://doi.org/10.1103/PhysRevB.52.8813	journal	September 1995
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Generalized gradient approximation for the exchange-correlation hole of a many-electron system Perdew, John P.; Burke, Kieron; Wang, Yue Physical Review B, Vol. 54, Issue 23 https://doi.org/10.1103/PhysRevB.54.16533	journal	December 1996
Dynamical matrices, Born effective charges, dielectric permittivity tensors, and interatomic force constants from density-functional perturbation theory Gonze, Xavier; Lee, Changyol Physical Review B, Vol. 55, Issue 16 https://doi.org/10.1103/PhysRevB.55.10355	journal	April 1997
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Itinerant-electron metamagnetic transition and large magnetovolume effects in La ( Fe x Si 1 − x ) 13 compounds Fujita, A.; Fujieda, S.; Fukamichi, K. Physical Review B, Vol. 65, Issue 1 https://doi.org/10.1103/PhysRevB.65.014410	journal	November 2001
Itinerant-electron metamagnetic transition and large magnetocaloric effects in La ( Fe x Si 1 − x ) 13 compounds and their hydrides Fujita, A.; Fujieda, S.; Hasegawa, Y. Physical Review B, Vol. 67, Issue 10 https://doi.org/10.1103/PhysRevB.67.104416	journal	March 2003
Large magnetovolume effects and band structure of itinerant-electron metamagnetic La ( Fe x Si 1 − x ) 13 compounds Fujita, A.; Fukamichi, K.; Wang, J. -T. Physical Review B, Vol. 68, Issue 10 https://doi.org/10.1103/PhysRevB.68.104431	journal	September 2003
Itinerant-electron metamagnetism and giant magnetocaloric effect Yamada, H.; Goto, T. Physical Review B, Vol. 68, Issue 18 https://doi.org/10.1103/PhysRevB.68.184417	journal	November 2003
Analytical model to understand the colossal magnetocaloric effect Ranke, P. J. von; de Oliveira, N. A.; Mello, C. Physical Review B, Vol. 71, Issue 5 https://doi.org/10.1103/PhysRevB.71.054410	journal	February 2005
Mechanism of the strong magnetic refrigerant performance of LaFe 13 − x Si x Kuz’min, Michael D.; Richter, Manuel Physical Review B, Vol. 76, Issue 9 https://doi.org/10.1103/PhysRevB.76.092401	journal	September 2007
Effects of composition, temperature, and magnetism on phonons in bcc Fe-V alloys Lucas, M. S.; Muñoz, J. A.; Delaire, O. Physical Review B, Vol. 82, Issue 14 https://doi.org/10.1103/PhysRevB.82.144306	journal	October 2010
Overcoming the spin-multiplicity limit of entropy by means of lattice degrees of freedom: A minimal model Mukherjee, T.; Michalski, S.; Skomski, R. Physical Review B, Vol. 83, Issue 21 https://doi.org/10.1103/PhysRevB.83.214413	journal	June 2011
Impact of local lattice distortions on the structural stability of Fe-Pd magnetic shape-memory alloys Gruner, Markus E.; Entel, Peter Physical Review B, Vol. 83, Issue 21 https://doi.org/10.1103/PhysRevB.83.214415	journal	June 2011
Effect of temperature and compositional changes on the phonon properties of Ni-Mn-Ga shape memory alloys Ener, Semih; Neuhaus, Jürgen; Petry, Winfried Physical Review B, Vol. 86, Issue 14 https://doi.org/10.1103/PhysRevB.86.144305	journal	October 2012
Moments in nuclear resonant inelastic x-ray scattering and their applications Hu, Michael Y.; Toellner, Thomas S.; Dauphas, Nicolas Physical Review B, Vol. 87, Issue 6 https://doi.org/10.1103/PhysRevB.87.064301	journal	February 2013
Role of vibrational entropy in the stabilization of the high-temperature phases of iron Neuhaus, Jürgen; Leitner, Michael; Nicolaus, Karl Physical Review B, Vol. 89, Issue 18 https://doi.org/10.1103/PhysRevB.89.184302	journal	May 2014
Metallic magnetism at finite temperatures studied by relativistic disordered moment description: Theory and applications Deák, A.; Simon, E.; Balogh, L. Physical Review B, Vol. 89, Issue 22 https://doi.org/10.1103/PhysRevB.89.224401	journal	June 2014
Vibrational Properties of Nanograins and Interfaces in Nanocrystalline Materials Stankov, S.; Yue, Y. Z.; Miglierini, M. Physical Review Letters, Vol. 100, Issue 23 https://doi.org/10.1103/PhysRevLett.100.235503	journal	June 2008
Adiabatic Electron-Phonon Interaction and High-Temperature Thermodynamics of A 15 Compounds Delaire, O.; Lucas, M. S.; Muñoz, J. A. Physical Review Letters, Vol. 101, Issue 10 https://doi.org/10.1103/PhysRevLett.101.105504	journal	September 2008
Understanding the Phase Transitions of the Ni 2 MnGa Magnetic Shape Memory System from First Principles Uijttewaal, M. A.; Hickel, T.; Neugebauer, J. Physical Review Letters, Vol. 102, Issue 3 https://doi.org/10.1103/PhysRevLett.102.035702	journal	January 2009
Positive Vibrational Entropy of Chemical Ordering in FeV Muñoz, J. A.; Lucas, M. S.; Delaire, O. Physical Review Letters, Vol. 107, Issue 11 https://doi.org/10.1103/PhysRevLett.107.115501	journal	September 2011
Observation of Nuclear Resonant Scattering Accompanied by Phonon Excitation Using Synchrotron Radiation Seto, M.; Yoda, Y.; Kikuta, S. Physical Review Letters, Vol. 74, Issue 19 https://doi.org/10.1103/PhysRevLett.74.3828	journal	May 1995
Phonon Density of States Measured by Inelastic Nuclear Resonant Scattering Sturhahn, W.; Toellner, T. S.; Alp, E. E. Physical Review Letters, Vol. 74, Issue 19 https://doi.org/10.1103/PhysRevLett.74.3832	journal	May 1995
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
First-Principles Determination of the Soft Mode in Cubic ZrO 2 Parlinski, K.; Li, Z. Q.; Kawazoe, Y. Physical Review Letters, Vol. 78, Issue 21 https://doi.org/10.1103/PhysRevLett.78.4063	journal	May 1997
Giant Magnetocaloric Effect in Gd5(Si2Ge2) Pecharsky, V. K.; Gschneidner, Jr., K. A. Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497 https://doi.org/10.1103/PhysRevLett.78.4494	journal	June 1997
Nuclear Inelastic X-Ray Scattering of FeO to 48 GPa Struzhkin, Viktor V.; Mao, Ho-kwang; Hu, Jingzhu Physical Review Letters, Vol. 87, Issue 25 https://doi.org/10.1103/PhysRevLett.87.255501	journal	November 2001
Inhomogeneous Electron Gas Rajagopal, A. K.; Callaway, J. Physical Review B, Vol. 7, Issue 5 https://doi.org/10.1103/physrevb.7.1912	journal	March 1973
Giant volume magnetostriction due to the itinerant electron metamagnetic transition in La(Fe-Si)/sub 13/ compounds Fujita, A.; Fukamichi, K. IEEE Transactions on Magnetics, Vol. 35, Issue 5 https://doi.org/10.1109/20.800668	journal	January 1999
Ferromagnetism Bozorth, Richard M. https://doi.org/10.1109/9780470544624	book	January 1978
Stability and Magnetocaloric Properties of Sintered La(Fe, Mn, Si)$_{13}$H$_{z}$ Alloys Barcza, A.; Katter, M.; Zellmann, V. IEEE Transactions on Magnetics, Vol. 47, Issue 10 https://doi.org/10.1109/TMAG.2011.2147774	journal	October 2011
Density of Phonon States in Iron at High Pressure Lübbers, R. Science, Vol. 287, Issue 5456 https://doi.org/10.1126/science.287.5456.1250	journal	February 2000
Accurate spin-dependent electron liquid correlation energies for local spin density calculations: a critical analysis Vosko, S. H.; Wilk, L.; Nusair, M. Canadian Journal of Physics, Vol. 58, Issue 8 https://doi.org/10.1139/p80-159	journal	August 1980
The Magnetocaloric Effect and its Applications Tishin, A. M.; Spichkin, Y. I. CRC Press https://doi.org/10.1201/9781420033373	reference-book	January 2016
Energy Dependence of Nuclear Recoil Measured with Incoherent Nuclear Scattering of Synchrotron Radiation Chumakov, A. I.; Rüffer, R.; Grünsteudel, H. Europhysics Letters (EPL), Vol. 30, Issue 7 https://doi.org/10.1209/0295-5075/30/7/009	journal	June 1995
Ab initio Force Constant Approach to Phonon Dispersion Relations of Diamond and Graphite Kresse, G.; Furthmüller, J.; Hafner, J. Europhysics Letters (EPL), Vol. 32, Issue 9 https://doi.org/10.1209/0295-5075/32/9/005	journal	December 1995
Metallic magnetism at finite temperatures studied by relativistic disordered moment description: Theory and applications Deák, A.; Simon, E.; Balogh, L. arXiv https://doi.org/10.48550/arxiv.1403.2904	text	January 2014

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Lattice dynamics across the magnetic transition in (Mn,Fe) 1.95 (P,Si) Bessas, D.; Maschek, M.; Yibole, H. Physical Review B, Vol. 97, Issue 9 https://doi.org/10.1103/physrevb.97.094303	journal	March 2018
Determining the vibrational entropy change in the giant magnetocaloric material LaFe 11.6 Si 1.4 by nuclear resonant inelastic x-ray scattering Landers, J.; Salamon, S.; Keune, W. Physical Review B, Vol. 98, Issue 2 https://doi.org/10.1103/physrevb.98.024417	journal	July 2018
Multisite Exchange-Enhanced Barocaloric Response in Mn 3 NiN Boldrin, David; Mendive-Tapia, Eduardo; Zemen, Jan Physical Review X, Vol. 8, Issue 4 https://doi.org/10.1103/physrevx.8.041035	journal	November 2018
Magnetocaloric materials for refrigeration near room temperature Waske, Anja; Gruner, Markus E.; Gottschall, Tino MRS Bulletin, Vol. 43, Issue 4 https://doi.org/10.1557/mrs.2018.69	journal	April 2018
Hysteresis Design of Magnetocaloric Materials-From Basic Mechanisms to Applications Scheibel, Franziska; Gottschall, Tino; Taubel, Andreas UNSPECIFIED https://doi.org/10.25534/tuprints-00013405	text	January 2018
Electronic structure, metamagnetism and thermopower of LaSiFe$_{12}$ and interstitially doped LaSiFe$_{12}$ Gercsi, Z.; Fuller, N.; Sandeman, K. G. arXiv https://doi.org/10.48550/arxiv.1407.7975	text	January 2014
Moment-volume coupling in La(Fe$_{1-x}$Si$_x$)$_{13}$ Gruner, M. E.; Keune, W.; Landers, J. arXiv https://doi.org/10.48550/arxiv.1708.08304	text	January 2017

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